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Canadian Journal of Physics

Wave equation for dissipative motion

Mohsen Razavy

Published Oct 1, 1991• 1 citation
Publisher

Abstract

From a quantized many-body system a wave equation for the motion of a particle linearly coupled to a heat bath is derived. The effective Hamiltonian describing the motion of the single particle is explicitly time dependent, and for a quadratic potential, has a simple dependence on the initial position and momentum of the particle. For the case of dissipative harmonic motion, a time-dependent wave equation is derived and the ground-state wave function is determined. It is also shown that if the equations of motion for the many-body system is Galilean invariant, the reduced form of equation of motion for the single particle is not. However a generalized form of transformation for the position and momentum operators, to a coordinate system moving with constant velocity, is obtained, which reduces to the Galilean transformation when the coupling to the dissipative system is turned off.

DOI
10.1139/p91-184

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From a quantized many-body system a wave equation for the motion of a particle linearly coupled to a heat bath is derived. The effective Hamiltonian describing the motion of the single particle is explicitly time dependent, and for a quadratic potential, has a simple dependence on the initial position and momentum of the particle. For the case of dissipative harmonic motion, a time-dependent wave equation is derived and the ground-state wave function is determined. It is also shown that if the equations of motion for the many-body system is Galilean invariant, the reduced form of equation of motion for the single particle is not. However a generalized form of transformation for the position and momentum operators, to a coordinate system moving with constant velocity, is obtained, which reduces to the Galilean transformation when the coupling to the dissipative system is turned off.
The motion of a particle subject to an external force and coupled to a large number of harmonic oscillators is reducible to a nonlinear integro-differential equation for the position operator. This is achieved by eliminating the degrees of freedom corresponding to the motion of the oscillators. Upon this elimination the commutator of the position and the mechanical momentum of the particle becomes time dependent and a c number for a quadratic potential, but in general a q number for other fields of force. For a harmonically bound particle interacting with the heat bath the time evolution of the position and momentum operators are given in terms of the solutions of an integro-differential equation. Certain forms of the coupling of the motion of the particle to the heat bath allow for further reduction of these equations to quartic differential equations with constant coefficients. For these cases the time dependence of the position-momentum commutator, the energy of the particle as well as the heat bath are studied.
A classical many-body problem composed of an infinite number of mass points coupled together by springs is quantized. The masses and the spring constants in this system are chosen in such a way that the motion of each particle is exponentially damped. Because of the quadratic form of the Hamiltonian, the many-body wave function of the system can be written as a product of two terms: a time-dependent phase factor which contains correlations between the classical motions of the particles, and a stationary state solution of the Schrödinger equation. By assuming a Hartree type wave function for the many-particle Schrödinger equation, the contribution of the time-dependent part to the single particle wave function is determined, and it is shown that the time-dependent wave function of each mass point satisfies the nonlinear Schrödinger–Langevin equation. The characteristic decay time of any part of the subsystem, in this model, is related to the stiffness of the springs, and is the same for all particles.
Phenomenological Equations of Motion for Dissipative Systems Lagrangian Hamiltonian and Hamilton-Jacobi Formulation of the Classical Dissipative Systems Noether's Theorem and Non-Noether Conservation Laws Dissipative Forces Derived from Many-Body Problems A Particle Coupled to a Field and the Damped Motion of a Central Particle Coupled to a Heat Bath Quantization of Dissipative Systems in General and of Explicitly Time-Dependent Hamiltonians in Particular Density Matrix and the Wigner Distribution Function for Damped Systems Path Integral Formulation of a Damped Harmonic Oscillator Quantization of the Motion of an Infinite Chain Heisenberg's Equations of Motion for a Particle Coupled to a Heat Bath Quantum Mechanical Models of Dissipative Systems and the Concept of Optical Potential.
The Brownian motion of a particle coupled to a heat bath can be derived from an exactly solvable many-body system. This motion is governed by the Langevin equation in Newtonian mechanics, and by an operator equation formally identical to the Langevin equation when the system composed of the particle plus the heat bath is quantized. To get this formal similarity between the classical and the quantal equations of motion of the particle, the classical dissipative system is formulated in terms of a modified Hamilton–Jacobi equation and is then quantized using the Schrödinger method. The result is identical with the Schrödinger–Langevin equation that has been obtained by quantizing the entire system and then isolating the motion of the particle. The non-linear wave equation describing the motion of a particle subject to conservative and time-dependent forces as well as frictional forces has been applied to the problems of motion of a wave-packet, and of the scattering and trapping of heavy-ions.
A wave equation formulation of the problem of quantum tunneling in a dissipative medium is developed by considering a many-body system in which the central particle is subject to an arbitrary force law, and at the same time is coupled to a bath of noninteracting harmonic oscillators. For the motion of the central particle it is possible to obtain an effective Lagrangian and Hamiltonian by eliminating the degrees of freedom of the oscillators. However both of these operators are nonlocal, and it is difficult to derive a wave equation for this motion. As an alternative method one can write a many-body Schrödinger equation for the whole system, and then eliminate the wave functions of all of the oscillators. This result is a many-channel Schrödinger equation for the motion of the central particle. By truncating this set of coupled equations, one can solve the problem for different force laws. In particular, in this work, the cases of dissipative tunneling, hopping, and quantum coherence are studied in detail. It is also shown how this approach can be generalized to multidimensional dissipative systems.
We study the quantum dynamics of the simplest dissipative system, a particle moving in a constant external field and interacting with a bath of harmonic oscillators with Ohmic spectral density. Applying the main idea and methods developed in our recent work [L. H. Yu and C. P. Sun, Phys. Rev. A 49, 592 (1994)] to this system, we obtain the simple and exact solutions for the coordinate operator of the system in the Heisenberg picture and the wave function of the composite system of the system and the bath in the Schr\"odinger picture. An effective Hamiltonian for the dissipative system is explicitly derived from these solutions. The meaning of the wave function described by this effective Hamiltonian is clarified by analyzing the effect of the Brownian motion. In particular, the general effective Hamiltonian for an arbitrary potential is directly derived with this method for the case when the Brownian motion can be ignored. Using this effective Hamiltonian, we show an interesting result that the dissipation suppresses the wave-packet spreading.