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Lettere al nuovo cimento della societa italiana di fisica/Lettere al nuovo cimento

The modified Euler equation for the correlation function in the case of a many-fermion system and study of its asymptotic behaviour

M. E. Grypeos, Eirene Mavrommatis

Published Sep 1, 1974• 5 citations
Publisher
DOI
10.1007/bf02752730

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arXiv:hep-th/0512088•Journal of Physics A Mathematical and General•Jan 11, 2006•5 citations
By means of a suitably chosen variational principle, Euler equations are derived which generalize the Hartree-Fock equations in such a way as to include two-particle correlations. For a system of NNN fermions these equations involve NNN single-particle functions and $\frac{1}{2}N(N\ensuremath{-}1)$ pair correlation functions. The Euler equations are optimal in the sense that a more accurate estimation of the total energy would require the introduction of three-particle correlation functions and the retention of terms nonlinear in the two-particle functions. Although intended primarily for use in the calculation of atomic and molecular electronic structure, the Euler equations are here used to determine the Coulomb correlation energy in the case of the high-density electron gas. The result obtained is shown to have the same leading logarithmic divergence with density as that found previously by Gell-Mann and Brueckner.