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Molecular Physics

Symmetry and invariance

D J Newman

Published Jun 10, 2004• 2 citations
Publisher

Abstract

The concept of invariance relates to both the intrinsic symmetries of physical systems and the symmetry of the set of equivalent reference frames used to observe them. Standard algebraic expressions for electrostatic potentials and crystal-field effective operators display both types of invariance. The concept of a reference frame is generalized to that of an ‘observing system’, which can, for example, be the basis states of a quantum system. This idea is related to Racah’s mathematical machinery for evaluating the matrix elements of many-electron 4f open-shell states in lanthanide ions. It is argued, on the basis of computational flexibility and ease of interpretation, that all equations that represent physical processes be expressible in terms of invariants of the set of observing systems. This ‘Principle of Invariance’ is then applied to special relativity, leading to a simple geometrical interpretation of Maxwell’s electromagnetic field equations. The close relationship between Dirac’s relativistic wave equation and Maxwell’s equations is then exposed. This leads to the concept of an inner structure of space-time and the reinterpretation of particle spin. Finally, it is shown that the use of invariants in relativity theory identifies a set of observing systems with a higher symmetry than that of Minkowski space-time.

DOI
10.1080/00268970410001728627

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The concept of invariance relates to both the intrinsic symmetries of physical systems and the symmetry of the set of equivalent reference frames used to observe them. Standard algebraic expressions for electrostatic potentials and crystal-field effective operators display both types of invariance. The concept of a reference frame is generalized to that of an ‘observing system’, which can, for example, be the basis states of a quantum system. This idea is related to Racah’s mathematical machinery for evaluating the matrix elements of many-electron 4f open-shell states in lanthanide ions. It is argued, on the basis of computational flexibility and ease of interpretation, that all equations that represent physical processes be expressible in terms of invariants of the set of observing systems. This ‘Principle of Invariance’ is then applied to special relativity, leading to a simple geometrical interpretation of Maxwell’s electromagnetic field equations. The close relationship between Dirac’s relativistic wave equation and Maxwell’s equations is then exposed. This leads to the concept of an inner structure of space-time and the reinterpretation of particle spin. Finally, it is shown that the use of invariants in relativity theory identifies a set of observing systems with a higher symmetry than that of Minkowski space-time.
General remarks As already mentioned in the Introduction, the exact solution of the main equation of quantum mechanics – the Schrödinger equation – lies beyond the potentialities of modern mathematics and computer technology. But a number of important inferences about the behaviour, structure and properties of a given quantum-mechanical many-particle system can be drawn without solving this equation, just by examining its symmetry properties. Symmetry concepts come about in physics in two ways. First, since any physical process occurs in a real space, we have to make use of one or another coordinate system. The isotropy and homogeneity of space make physically meaningful only those mathematical relationships that remain unchanged under rotations of the axes of the coordinate system, and that impose fairly rigorous constraints on the possible physical laws. Second, every physical object and process features a symmetry which should be taken into account by the physical theory. A common idea underlying particular forms of symmetry is the invariance of a system under a certain set (group) of transformations. The normally considered forms of symmetry are rotational symmetry, which is based on the equivalence of all directions in space, and permutation symmetry, which is caused by identical particles. The operations of the geometrical symmetry group are responsible for appropriate conservation laws. So, the rotational symmetry of a closed system gives rise to the law of conservation of angular momentum. The group of rotations of a three-dimensional space stands apart in atomic spectroscopy. This is mostly due to the high accuracy of the central field approximation, on which the entire modern theory of complex atoms and ions is based.
A hypothesis is put forward according to which the formulas of Relativity are a consequence of the laws of quantum physics and may be applied only to quantum objects. According to the wave - particle duality quantum bodies are simultaneously the waves and considered in the present research with a use of the wave equation and requirement of its Lorentz‘s invariance. The property of invariance with respect to the Lorentz’s transform is analysed in hyperbolic coordinates in an area of complex numbers. An examination showed that formulas of relativistic kinematics can be obtained based on the condition of equality of the amplitudes and phases of the wave, observed from different inertial frames. There is no need to introduce the concept of a unified entity of space-time, but the return to the idea of aether and matter waves de Broglie occurs. The physical model becomes borrowed partly from quantum field theory. It is assumed that the moving particle binds to a wave of the aether disturbance, and only this wave acts on the other particle like an electromagnetic field pushes an electrical charge. The model of colliding elastic balls becomes inapplicable, but equations of relativity mechanics remain the same, however, with a new interpretation. The mass of a particle in all coordinate systems is constant, in exchange the expressions of energy and momentum alter relative the classical case, include the property of aether – coefficient c of the wave equation, and acquire relativistic forms.
We consider a quantum particle as a wave packet in the coordinate space. When the conjugate wave packet in the momentum space is considered, we find that the group velocities of these two wave packets, which describe the particle dynamics, are in agreement with the Hamilton equations only if in the time dependent phases one considers the Lagrangian instead of the Hamiltonian which leads to the conventional Schrodinger equation. We define a relativistic quantum principle asserting that a quantum particle has a finite frequency spectrum, with a cutoff propagation velocity c as a universal constant not depending on the coordinate system, and that any time dependent phase variation is the same in any system of coordinates. From the time dependent phase invariance, the relativistic kinematics is obtained. We consider two types of possible interactions: 1) An interaction with an external field, by a modification of the time dependent phase differential with the terms proportional to the differentials of the space-time coordinates multiplied with the components of this field four-potential, and 2) an interaction by a deformation of the space-time coordinates, due to a gravitational field. From the invariance of the time dependent phase with field components, we obtain a mechanical force of the form of Lorentz’s force, and three Maxwell equations: The Gauss-Maxwell equations for the electric and magnetic fluxes, and the Faraday-Maxwell equation for the electromagnetic induction. When the fourth equation, Ampere-Maxwell, is considered, the interaction field takes the form of the electromagnetic field. For a low propagation velocity of the particle waves, we get a packet of waves with the time dependent phases proportional to the relativistic Hamiltonian, as in Dirac’s famous theory of spin, and a slowly-varying amplitude with a phase proportional to the momentum and this velocity. In the framework of our theory, the spin is obtained as an all quantum effect, without any additional assumption to the quantum theory. When a space-time deformation is considered in the time dependent phase of a quantum particle, from the group velocity we get the particle dynamics according to the general theory of relativity. In this way, the relativistic dynamics, the electromagnetic field, and the spin of a quantum particle are obtained only from the invariance of the time dependent phases of the particle wave functions.
If a system in atomic physics contains a number of particles of the same kind, e.g. a number of electrons, the particles are absolutely indistinguishable one from another. No observable change is made when two of them are interchanged … A satisfactory theory ought, of course, to count any two observationally indistinguishable states as the same state and to deny that any transition does occur when two similar particles exchange places. ( Dirac, 1958, p. 207 ) Introduction In our contribution to this volume we deal with discrete symmetries: these are symmetries based upon groups with a discrete set of elements (generally a set of elements that can be enumerated by the positive integers). In physics we find that discrete symmetries frequently arise as ‘internal’, non-spacetime symmetries. Permutation symmetry is such a discrete symmetry, arising as the mathematical basis underlying the statistical behaviour of ensembles of certain types of indistinguishable quantum particle (e.g. fermions and bosons). Roughly speaking, if such an ensemble is invariant under a permutation of its constituent particles (i.e. permutation symmetric) then one doesn't ‘count’ those permutations which merely ‘exchange’ indistinguishable particles; rather, the exchanged state is identified with the original state. This principle of invariance is generally called the ‘indistinguishability postulate’ (IP), but we prefer to use the term ‘permutation invariance’ (PI).
In order to preserve the nature of physical laws in different reference frames there are four dimensions: three of space and one of time. These are combined into a single entity called space–time. Many of the mathematical techniques used in the first part of this book now need to be extended into a four-dimensional space–time. We will see that that actual mathematical concepts are not so difficult, and it largely becomes an exercise in notation. Once the mathematical tools are available, Schrödinger’s equation can be re-visited and a new form of quantum physics discovered which allows for the intrinsic property of electron spin and the existence of anti-matter. Finally, the “action principle” can be introduced. We will see that the action principle pervades all of the equations of motion in physics and ultimately accounts for the quantum behaviour of particles, whether they be sub-atomic particles or large-scale particles. Not only does the action principle apply to particles but also to fields. Applied to the electromagnetic field, we find that Maxwell’s equations arise as a consequence of the action principle. The action principle is perhaps of even more fundamental significance than the law of conservation of energy.
The description of relativistic effects requires a preliminary definition of events localised in space-time while the clocks used for time definition and the fields used in synchronisation or localisation procedures are necessarily quantum systems. We outline an algebraic framework where basic requirements of quantum theory and relativity are consistently dealt with. This approach which may be termed as a `quantum relativity' is built on the algebra of symmetries. It contains the definition of quantum observables associated with Einstein localisation in space-time as well as the evaluation of their commutation relations including the energy-time relation. These commutators also describe the relativistic shifts undergone under frame transformations, not only for inertial frames but also for uniformly accelerated frames. The quantum redshift laws differ from their classical counterparts while still obeying universal metric properties. The paper presents this approach in terms closely connected to the seminal Einstein conception of localisation in space-time and refers to already published papers for more technical developments.