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Physica

On the rotation operators in quantum mechanics

M. -C. Bouten

Published Jun 1, 1969• 35 citations
Publisher
DOI
10.1016/0031-8914(69)90162-1

Related papers

Rotations in Quantum Mechanics

K. Heyde

Springer eBooks•Jan 1, 1994•0 citations

Rotations et Moments Angulaires en Mecanique Quantique - Rotations and angular moments in quantum mechanics

Jacques Van de Wiele

As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.

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Explicit expressions of quantum mechanical rotation operators for spins 1 to 2

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Quantum mechanical rotation operators are the subject of quantum mechanics, mathematics and pulsed magnetic resonance spectroscopies, namely NMR, EPR and ENDOR. They are also necessary for spin based quantum information systems. The rotation operators of spin 1/2 are well known and can be found in related textbooks. But rotation operators of other spins greater than 1/2 can be found numerically by evaluating the series expansions of exponential operator obtained from Schrödinger equation, or by evaluating Wigner-d formula or by evaluating recently established expressions in polynomial forms discussed in the text. In this work, explicit symbolic expressions of x, y and z components of rotation operators for spins 1 to 2 are worked out by evaluating series expansion of exponential operator for each element of operators and utilizing linear curve fitting process. The procedures gave out exact expressions of each element of the rotation operators. The operators of spins greater than 2 are under study and will be published in a separate paper.

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Rotations in Quantum Mechanics

K. Heyde

Springer series in nuclear and particle physics•Jan 1, 1990•2 citations
As in classical mechanics, rotation in quantum mechanics is a transformation which deals with angular momentum. The difference with classical mechanics comes from the fact that angular momentum is a vector operator and not a usual vector and its components do not commute. As for any transformation in quantum mechanics, to each rotation we can associate an operator which acts in state space. The expression of this operator depends on whether the rotation is passive, that is we do a rotation of the coordinate axes and the physical system is left unchanged, or active, in which case the coordinate axes are unchanged and the rotation is performed on the physical system. In the first part (Chaps. 1 and 2) of this book, details concerning both aspects are given. Following the definition of the geometrical transformation associated with the most general rotation, we give the expression of the rotation operator for specific cases. Transformation laws for scalar fields, vector fields and spinor fields are given as well as transformation laws for scalar operators, vector operators and more generally, for operators of any rank. The second part (Chaps. 3 and 4) deals with angular momentum algebra. We define the coupling coefficients of 2, 3 and 4 angular momenta as well as the recoupling coefficients. The definition of the irreductible tensor operator, which is a generalisation of scalar and vector operators, is given as well as the Wigner-Eckart theorem. The application of this theorem to more complex cases is studied.
Quantum mechanical rotation operators are the subject of quantum mechanics, mathematics and pulsed magnetic resonance spectroscopies, namely NMR, EPR and ENDOR. They are also necessary for spin based quantum information systems. The rotation operators of spin 1/2 are well known and can be found in related textbooks. But rotation operators of other spins greater than 1/2 can be found numerically by evaluating the series expansions of exponential operator obtained from Schrödinger equation, or by evaluating Wigner-d formula or by evaluating recently established expressions in polynomial forms discussed in the text. In this work, explicit symbolic expressions of x, y and z components of rotation operators for spins 1 to 2 are worked out by evaluating series expansion of exponential operator for each element of operators and utilizing linear curve fitting process. The procedures gave out exact expressions of each element of the rotation operators. The operators of spins greater than 2 are under study and will be published in a separate paper.