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Elsevier eBooks

Superfluidity in Helium Clusters

M. V. Rama Krishna, K. Birgitta Whaley

Published Jan 1, 1993• 1 citation
Publisher
DOI
10.1016/b978-0-444-89022-1.50028-6

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In this paper, quantum fluctuations of a carbonyl sulfide molecule in helium-4 clusters are studied as a function of cluster size N in a small-to-large size regime (2<or=N<or=64). The molecular rotation of the dopant shows nonmonotonic size dependence in the range of 10<or=N<or=20, reflecting the density distribution of the helium atoms around the molecule. The size dependence on the rotational constant shows a plateau for N>or=20, which is larger than the experimental nanodroplet value. Superfluid response of the doped cluster is found to show remarkable anisotropy especially for N<or=20. The superfluid fraction regarding the axis perpendicular to the molecular axis shows a steep increase at N=10, giving the significant enhancement of the rotational fluctuation of the molecule. On the other hand, the superfluid fraction regarding the axis parallel to the molecular axis reaches 0.9 at N=5, arising from the bosonic exchange cycles of the helium atoms around the molecular axis. The anisotropy in the superfluid response is found to be the direct consequence of the configurations of the bosonic exchange cycles.

The Journal of Chemical Physics•Mar 20, 2007•28 citations
Many microscopic properties of the only natural superfluid element helium have become available within the last 18 years through a number of novel experiments. The diffraction of matter-waves of small helium clusters has established the unusually large bond distance (5.2 nm) and extremely weak binding energy (10−7 eV) of the dimer and other exotic properties of small helium clusters. The high-resolution spectroscopy of closed-shell chromophore molecules attached to small clusters or embedded inside large superfluid droplets have revealed that as a result of superfluidity, molecules rotate virtually without friction and that only a handful of He atoms are required for microscopic superfluidity. The frictionless translational motion of atoms and molecules inside the droplets has also been observed. These and a number of other experiments demonstrate that helium droplets are the most gentle and coldest of all cryomatrices with enormous potential for a wide range of future applications.
In this paper, quantum fluctuations of a carbonyl sulfide molecule in helium-4 clusters are studied as a function of cluster size N in a small-to-large size regime (2<or=N<or=64). The molecular rotation of the dopant shows nonmonotonic size dependence in the range of 10<or=N<or=20, reflecting the density distribution of the helium atoms around the molecule. The size dependence on the rotational constant shows a plateau for N>or=20, which is larger than the experimental nanodroplet value. Superfluid response of the doped cluster is found to show remarkable anisotropy especially for N<or=20. The superfluid fraction regarding the axis perpendicular to the molecular axis shows a steep increase at N=10, giving the significant enhancement of the rotational fluctuation of the molecule. On the other hand, the superfluid fraction regarding the axis parallel to the molecular axis reaches 0.9 at N=5, arising from the bosonic exchange cycles of the helium atoms around the molecular axis. The anisotropy in the superfluid response is found to be the direct consequence of the configurations of the bosonic exchange cycles.