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Journal of Mathematical Physics

An approach to the study of quantum systems

F. T. Hioe

Published Apr 1, 1974• 28 citations
Publisher

Abstract

A perturbation method for quantum mechanical problems is presented in which the successive terms are obtained by algebraic recurrence relations without the use of any diagrams. Two examples, one an anharmonic oscillator with quartic self-interaction, and one a spin with quadratic self-interaction, are given to illustrate the use of this recurrence relation perturbation method.

DOI
10.1063/1.1666666

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A perturbation method for quantum mechanical problems is presented in which the successive terms are obtained by algebraic recurrence relations without the use of any diagrams. Two examples, one an anharmonic oscillator with quartic self-interaction, and one a spin with quadratic self-interaction, are given to illustrate the use of this recurrence relation perturbation method.
A new approach to the eigenvalue problem in quantum mechanics is proposed. This approach is based on three propositions: 1) a perturbation theory which does not require knowledge of the entire eigenvalue spectrum of the unperturbed problem and which uses a nonlinearization procedure (leaving some latitude in the choice of a zeroth order approximation); 2) a relationship between the perturbation theory and a variational principle, namely that any variational calculation is none other than the first two terms of some nontrivial perturbation theory which, when developed further, can reveal the accuracy of the variational calculations and can refine them by an iterative procedure; 3) Dyson's argument, which serves as a criterion for the reasonableness of the choice of a zeroth order approximation (the unperturbed problem). The realization of this perturbation theory in a k-dimensional space is equivalent to the solution of a k-dimensional electrostatic problem with a variable dielectric permittivity. In the one-dimensional case and in cases which reduce to the one-dimensional case, all the corrections are written in quadratures. It is shown that the construction of an ordinary perturbation theory (in which the zeroth order approximation is an exactly solvable problem) within the framework of this perturbation theory is a purely algebraic procedure, which reduces to the solution of some simple recurrence relations. An approximation analogous to the leading logarithmic approximation of quantum field theory is constructed. Some standard problems of quantum mechanics—the anharmonic oscillator, the Zeeman effect, and the Stark effect—are treated as examples. It is shown that this new approach makes it possible to develop systematically a theory for strong coupling and large perturbations.
This report discusses two new ideas for using perturbation methods to solve the time-independent Schrödinger equation. The first concept begins with rewriting the perturbation equations in a form that is closely related to matrix diagonalization methods. That allows a simple, compact derivation of the standard (Rayleigh-Schrödinger) equations. But it also leads to a new iterative solution method that is not based on the usual power series expansion. The iterative method can also be used when the unperturbed system is two-fold degenerate. The second concept is quite different from the first but compatible with it. It is based on the fact that one can replace the true Hamiltonian with a synthetic Hamiltonian having the same eigenvalues. This approach allows one to cancel part of the perturbation and to reduce the size of the off-diagonal matrix elements, giving better convergence of the series. These methods are illustrated by application to three perturbed harmonic oscillator problems--a 1-D oscillator with a linear perturbation, a 1-D oscillator with a quartic perturbation, and a perturbed 2-D oscillator, which involves degenerate states. The iterative method and the synthetic Hamiltonian method are shown to give significantly better results than the standard method.
We present a new Lie algebraic method to study the eigenvalues and eigenfunctions of quantum anharmonic oscillators. We consider the Hamiltonians for the simple harmonic and anharmonic oscillator as the two generators of a Lie algebra, whose other generators may be found exactly or up to any order of the parameter involved. Speciflcally, the closed commutator algebra for the quartic anharmonic oscillator is established in a perturbation sense. An element of this Lie group, turning out to be the four-photon operator, transforms the quartic anharmonic oscillator Hamiltonian to the harmonic one in a perturbation sense; thus, facilitating the calculation of the eigenvalues and eigenfunctions of the former.