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European Journal of Physics

Variational principles in quantum statistical mechanics

João da Providência, Carlos Fiolhais

Published Jan 1, 1987• 2 citations
Publisher

Abstract

The principle of least information is used to derive the inequality between the arithmetic and the geometric mean. Some important variational results in quantum statistical mechanics (Peierls and Bogolyubov inequalities) are pedagogically reviewed. Emphasis is put on the distinction between mixed states describing metastable and stable equilibrium.

DOI
10.1088/0143-0807/8/1/004

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The principle of least information is used to derive the inequality between the arithmetic and the geometric mean. Some important variational results in quantum statistical mechanics (Peierls and Bogolyubov inequalities) are pedagogically reviewed. Emphasis is put on the distinction between mixed states describing metastable and stable equilibrium.
The approach to the theory of many-particle interacting systems from a unified standpoint, based on the variational principle for free energy is reviewed. A systematic discussion is given of the approximate free energies of complex statistical systems. The analysis is centered around the variational principle of Bogoliubov for free energy in the context of its applications to various problems of statistical mechanics. The review presents a terse discussion of selected works carried out over the past few decades on the theory of many-particle interacting systems in terms of the variational inequalities. It is the purpose of this paper to discuss some of the general principles which form the mathematical background to this approach and to establish a connection of the variational technique with other methods, such as the method of the mean (or self-consistent) field in the many-body problem. The method is illustrated by applying it to various systems of many-particle interacting systems, such as Ising, Heisenberg and Hubbard models, superconducting (SC) and superfluid systems, etc. This work proposes a new, general and pedagogical presentation, intended both for those who are interested in basic aspects and for those who are interested in concrete applications.
Geometrical methods in quantum information are very promising for both providing technical tools and intuition into difficult control or optimization problems. Moreover, they are of fundamental importance in connecting pure geometrical theories, like GR, to quantum mechanics, like in the AdS/CFT correspondence. In this paper, we first make a survey of the most important settings in which geometrical methods have proven useful to quantum information theory. Then we lay down a geometric theory of entanglement by a principle of action, discussing a simple example with two qubits and consequences for a quantum theory of space-time.
The first steps in the application of methods for integrating functions defined on abstract sets were taken by Wiener. Most widely, the ideas of functional integration were developed in Feynman's works. The Feynman continual integral is well known to a wide community of physicists. Along with this, there is another approach to the construction of a functional integral in quantum physics. This approach was proposed by Bogolyubov. Bogolyubov's methods are relevant in quantum statistical physics, and have natural ties with probability theory. We review some mathematical results of integration with respect to a special Gaussian measure that arises in the statistical theory for quantum systems. It is shown that the Gibbs equilibrium averages of the chronological products of Bose operators can be represented as functional integrals with respect to this measure (the Bogolyubov measure). Some properties of this measure are studied. We rewrite partition function of many particle Bose systems in terms of Bogolyubov functional integral.