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Physical review. B, Condensed matter

Anisotropic sine-Gordon model and infinite-order phase transitions in three dimensions

G. Grinstein

Published May 1, 1981• 56 citations
Publisher

Abstract

A three-dimensional anisotropic sine-Gordon model, derived as the spin-wave approximation to the biaxial ($m=2$) Lifshitz point problem in a uniform magnetic field, is shown to possess [in close analogy to the isotropic two-dimensional (2D) sine-Gordon theory which is well known to describe the critical behavior of the 2D $\mathrm{XY}$ model], a surface of infinite-order phase transitions. This critical surface separates a phase characterized by infinite correlation length $\ensuremath{\xi}$ and power-law decay of correlations, and controlled by a stable fixed line, from one with finite $\ensuremath{\xi}$ and exponential decay. As the critical surface is approached from the latter phase, $\ensuremath{\xi}$ diverges as exp ($\ensuremath{\sigma}{t}^{\ensuremath{-}\ensuremath{\nu}}$) where $\ensuremath{\nu}=1$ is a universal number, $t$ measures the distance from the critical surface, and $\ensuremath{\sigma}$ is nonuniversal. On the critical surface correlations decay like ${r}^{\ensuremath{-}\ensuremath{\eta}}{(\mathrm{ln}r)}^{\ensuremath{-}\stackrel{\ifmmode \tilde{}\else \~{}\fi{}}{\ensuremath{\eta}}}$, where $\ensuremath{\eta}=4$ and $\stackrel{\ifmmode \tilde{}\else \~{}\fi{}}{\ensuremath{\eta}}=0.88\ensuremath{\cdots}$. Speculations on the occurrence of an infinite-order transition in liquid-crystal mixtures exhibiting nematic, smectic-$A$, and smectic-$C$ phases are advanced.

DOI
10.1103/physrevb.23.4615

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A three-dimensional anisotropic sine-Gordon model, derived as the spin-wave approximation to the biaxial (m=2m=2m=2) Lifshitz point problem in a uniform magnetic field, is shown to possess [in close analogy to the isotropic two-dimensional (2D) sine-Gordon theory which is well known to describe the critical behavior of the 2D XY\mathrm{XY}XY model], a surface of infinite-order phase transitions. This critical surface separates a phase characterized by infinite correlation length \ensuremathξ\ensuremath{\xi}\ensuremathξ and power-law decay of correlations, and controlled by a stable fixed line, from one with finite \ensuremathξ\ensuremath{\xi}\ensuremathξ and exponential decay. As the critical surface is approached from the latter phase, \ensuremathξ\ensuremath{\xi}\ensuremathξ diverges as exp (\ensuremathσt\ensuremath−\ensuremathν\ensuremath{\sigma}{t}^{\ensuremath{-}\ensuremath{\nu}}\ensuremathσt\ensuremath−\ensuremathν) where \ensuremathν=1\ensuremath{\nu}=1\ensuremathν=1 is a universal number, ttt measures the distance from the critical surface, and \ensuremathσ\ensuremath{\sigma}\ensuremathσ is nonuniversal. On the critical surface correlations decay like r\ensuremath−\ensuremathη(lnr)\ensuremath−\ensuremathη\ifmmode~\else˜\fi{r}^{\ensuremath{-}\ensuremath{\eta}}{(\mathrm{ln}r)}^{\ensuremath{-}\stackrel{\ifmmode \tilde{}\else \~{}\fi{}}{\ensuremath{\eta}}}r\ensuremath−\ensuremathη(lnr)\ensuremath−\ensuremathη\ifmmode~\else˜\fi​, where \ensuremathη=4\ensuremath{\eta}=4\ensuremathη=4 and \ensuremathη\ifmmode~\else˜\fi=0.88\ensuremath⋯\stackrel{\ifmmode \tilde{}\else \~{}\fi{}}{\ensuremath{\eta}}=0.88\ensuremath{\cdots}\ensuremathη\ifmmode~\else˜\fi​=0.88\ensuremath⋯. Speculations on the occurrence of an infinite-order transition in liquid-crystal mixtures exhibiting nematic, smectic-AAA, and smectic-CCC phases are advanced.
This article outlines a tutorial review of some recent progress in the theory of phase transitions and criticality. Topics mentioned are: |φ|6 field theories in (d=3)-dimensional space which correspond to the limits of tricriticality in spherical models; the desirability of finding real systems displaying critical endpoints, etc., in a magnetic field; scaling theories for first-order magnetic transitions in block and cylinder geometries, including spin-wave contributions, ϵ=4 - d expansions for finite-size effects at and near criticality; the universal correlation length amplitude for critical-point correlations in a finite cylinder and its evaluation in d = 2 dimensions on the basis of conformal covariance; the predictions of conformal covariance for other finite-size and surface critical-point properties; the implications, stemming from field theory, of conformal covariance and unitarity for general criticality in two dimensions, including infinitely many sets of exact critical exponents for Ising-like, three-state Potts-like, … systems; the discovery of new, exactly soluble two-dimensional, “restricted solid-on-solid” models which display all the predicted conformally covariant multicritical points and a second infinite set as well!
The critical behaviour of semi-infinite d -dimensional systems with short-range interactions and an O( n ) invariant Hamiltonian is investigated at an m -axial Lifshitz point with an isotropic wave-vector instability in an m -dimensional subspace of d parallel to the surface. Continuum |ϕ| 4 models representing the associated universality classes of surface critical behaviour are constructed. In the boundary parts of their Hamiltonians quadratic derivative terms (involving a dimensionless coupling constant λ) must be included in addition to the familiar ones ∝ϕ 2 . Beyond one-loop order the infrared-stable fixed points describing the ordinary, special and extraordinary transitions in d = 4 + m /2 − dimensions (with > 0) are located at λ = λ* = O( ). At second order in , the surface critical exponents of both the ordinary and the special transitions start to deviate from their m = 0 analogues. Results to order 2 are presented for the surface critical exponent β ord 1 of the ordinary transition. The scaling dimension of the surface energy density is shown to be given exactly by d + m (θ − 1), where θ = ν l 4 /ν l 2 is the bulk anisotropy exponent.
Phase diagrams of uniaxial two-dimensional systems with commensurate, incommensurate, and liquid phases are derived by combining exact results for the quantum sine-Gordon model with the Kosterlitz-Thouless theory of melting. The phase diagram depends on the order of commensurability, ppp. In particular, for p=3p=3p=3 (the "chiral Potts" case), we conjecture that the phase diagram contains no Lifshitz point, in contrast to previous authors; for p=1p=1p=1, dislocations remove the original CI\mathrm{CI}CI transition completely.
The renormalization group equations for the sine-Gordon system with a short wave-length cutoff in two dimensions are derived by means of a momentum-shell recursion method. In a special limit they agree with the Kosterlitz renormalization group equations which describe the critical properties of the phase transitions of the two-dimensional (2-D) neutral Coulomb gas with single charges ±1 and of the 2-D isotropic X-Y model in the absence of an external field. The results, therefore, give rise to a possibility that certain classes of phase transitions in low dimensions can be described in a unified way with the sine-Gordon Hamiltonian.
The critical behavior of a semi-infinite nnn-vector model with anisotropic ferromagnetic pair interactions on the surface and isotropic interactions everywhere else is studied with the use of renormalization-group methods for dimension $d=4\ensuremath{-}\ensuremath{\epsilon}$. The effects of surface anisotropies are analyzed near the isotropic ordinary transition (where they produce corrections to scaling), near the isotropic special transition (where they are relevant perturbations), and near a new class of "anisotropic special" transitions. The latter occur if the surface exchange constants associated with me{m}_{e}me​ (easy-magnetization) components take a critical value above which me{m}_{e}me​-component surface order is possible while the interaction constants of the remaining ${m}_{h}=n\ensuremath{-}{m}_{e}$ (hard-magnetization) components are weaker. Of particular interest is the anisotropic special transition with an easy axis (me=1{m}_{e}=1me​=1) because it occurs also in three dimensions, in contrast to the isotropic special one. The associated critical, crossover, and correction-to-scaling exponents are given to second order in $\ensuremath{\epsilon}$.
The ferromagnetic-modulated transition in the biaxial (m=2m=2m=2) XY\mathrm{XY}XY Lifshitz-point model with ppp-fold anisotropy in spin space is studied via renormalization-group techniques in three dimensions. For sufficiently large ppp the transition is, respectively, first and second order at low and high temperatures; an infinite-order critical point separates the two regimes.