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Communications in Mathematical Physics

A new method for the thermomodynamics of the BCS model

Nick G. Duffield, J. V. Pul�

Published Sep 1, 1988• 16 citations
Publisher
DOI
10.1007/bf01466728

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A new stochastic number projection method is proposed. The component of the BCS wave function corresponding to the right number of particles is obtained by means of a Metropolis algorithm in which the weight functions are constructed from the single-particle occupation probability. Either standard BCS or Lipkin-Nogami probability distributions can be used, thus the method is applicable for any pairing strength. The accuracy of the method is tested in the computation of pairing energies of model and real systems.
The solvable two-level pairing model is used to test two new number-conserving approximations. These approximations are compared with the exact results, with perturbation theory, with the BCS method, and with the projected BCS method of Kerman, Lawson, and Macfarlane. It is found that second-order perturbation theory and one of the tested approximations work rather well for not too high values of the pairing-force strength, while for higher values the other approximation turns out to be quite good.
The canonical operator exp [−β(H − μN)] associated with the Bardeen-Cooper-Schrieffer (BCS) model Hamiltonian of superconductivity is represented as a functional integral by the use of Feynman's ordering parameter. General properties of the partition function in this representation are discussed. Taking the inverse volume of the system as an expansion parameter, it is possible to calculate the thermodynamic potential including terms independent of the volume. This yields a new proof that the BCS variational value is asymptotically exact. The behavior of the canonical operator for large volume is described and related to the state of free quasiparticles. A study of the terms of the thermodynamic potential which are of smaller order in the volume in the low-temperature limit, shows that the ground state energy is nondegenerate and belongs to a number eigenstate.