Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Physical review. D. Particles, fields, gravitation, and cosmology/Physical review. D. Particles and fields

Hamiltonians, path integrals, and a new renormalization group

Marvin Weinstein

Published Jun 15, 1993• 11 citations
Publisher

Abstract

New nonperturbative methods for dealing with Hamiltonian systems are introduced. The derivation of these methods requires identities for rewriting exponentials of sums of operators which are different from the usual Campbell-Hausdorff formula. These identities allow one to derive approximations to ${e}^{\ensuremath{-}\ensuremath{\delta}H}$ which are correct to higher order in $\ensuremath{\delta}$ and which contain fewer terms than the Campbell-Hausdorff formula. This allows one to generate path-integral actions which are more accurate for finite-size steps in time and which can be exploited to improve the rate of convergence of Monte Carlo calculations. To show that these methods allow one to include effects which show up in the stationary-phase approximation to the path integral, e.g., instantons, solitons, etc., I not only derive the connection between the Hamiltonian and path-integral formalism but the relationship between a specific stationary-phase approximation and the corresponding Hamiltonian calculation. My focus, however, is the direct application of these new identities to the study of nonperturbative Hamiltonian dynamics. I show that these methods are easier to apply and give better results than those based upon the naive $t$-expansion, block mean-field, or real-space renormalization ideas. Comparison of these older methods with the computational tools introduced in this paper are discussed in the context of simple examples. It is shown that the new methods allow one to extrapolate answers to finite $t$ without the use of Pad\'e approximants.

DOI
10.1103/physrevd.47.5499

Related papers

Series expansions and their summation

R. J. Rivers

Let us recapitulate. Although the form (4.32) for the path integral was motivated by analogy with finite-dimensional integrals, in no way is it a definition. Rather, as we have stressed repeatedly, it is an algorithm for handling the Feynman perturbation series. Strong coupling apart, all the manipulations of the path integral that we have performed (integration by parts, the introduction of auxiliary fields, the inclusion of background fields) stand in one-to-one correspondence to rearrangements of the perturbation series. In fact, path integrals are unnecessary in the derivation of expressions like (4.50). See Fried (1972), for example. The path integrals are as rigorous – or non-rigorous – as the series, irrespective of whether they can be given proper mathematical definition or not. At the same time, the analogy with finite-dimensional integrals suggests approaches that go beyond this purely operational stance. In particular, because of the dominant role played by the classical action in the path integral formalism we would like to use it to establish the relation of quantum dynamics to classical dynamics. This is the most compelling reason for introducing the path integral formalism, requiring a distinct relaxation in our treatment of it. By formal analogy with finite-dimensional saddle-point and stationary-phase methods, elevating the classical action to the phase of the integrand promotes series expansions in ħ as the natural way to proceed.

Cambridge University Press eBooks•Nov 12, 1987•0 citations

Variational Methods for Path Integral Scattering

Julien Carron

In this master thesis, a new approximation scheme to non-relativistic potential scattering is developed and discussed. The starting points are two exact path integral representations of the T-matrix, which permit the application of the Feynman-Jensen variational method. A simple Ansatz for the trial action is made, and, in both cases, the variational procedure singles out a particular one-particle classical equation of motion, given in integral form. While the first is real, in the second representation this trajectory is complex and evolves according to an effective, time dependent potential. Using a cumulant expansion, the first correction to the variational approximation is also evaluated. The high energy behavior of the approximation is investigated, and is shown to contain exactly the leading and next-to-leading order of the eikonal expansion, and parts of higher terms. Our results are then numerically tested in two particular situations where others approximations turned out to be unsatisfactory. Substantial improvements are found.

arXiv:0903.0273•Mar 2, 2009•5 citations

Quantum Mechanics on Lie Groups: II. Path Integrals

Mathieu Beauvillain, Blagoje Oblak, Marios Petropoulos

We continue our study of quantum dynamics on a Lie group $G$, initiated in arXiv:2512.19840, by building the path integral that governs transition amplitudes in the Hilbert space $L^2(G)$. This relies on the proper handling of both a noncommutative momentum space and the presence of compact directions in $G$. We show that compactness can be handled through a sum over winding numbers in maximal tori of $G$, generalizing the similar sum commonly encountered for path integrals on a circle. As applications, we compute semiclassical approximations of propagators and partition functions of Euler-Arnold systems, up to (and including) two-loop order.

quant-pharXiv:2607.16029•Jul 20, 2026•0 citations

Effects of dynamical paths on the energy gap and the corrections to the free energy in path integrals of mean-field quantum spin systems

Yang Wei Koh

In current studies of mean-field quantum spin systems, much attention is placed on the calculation of the ground-state energy and the excitation gap, especially the latter, which plays an important role in quantum annealing. In pure systems, the finite gap can be obtained by various existing methods such as the Holstein-Primakoff transform, while the tunneling splitting at first-order phase transitions has also been studied in detail using instantons in many previous works. In disordered systems, however, it remains challenging to compute the gap of large-size systems with specific realization of disorder. Hitherto, only quantum Monte Carlo techniques are practical for such studies. Recently, Knysh [Nature Comm. 7, 12370 (2016)] proposed a method where the exponentially large dimensionality of such systems is condensed onto a random potential of much lower dimension, enabling efficient study of such systems. Here we propose a slightly different approach, building upon the method of static approximation of the partition function widely used for analyzing mean-field models. Quantum effects giving rise to the excitation gap and nonextensive corrections to the free energy are accounted for by incorporating dynamical paths into the path integral. The time-dependence of the trace of the time-ordered exponential of the effective Hamiltonian is calculated by solving a differential equation perturbatively, yielding a finite-size series expansion of the path integral. Formulae for the first excited-state energy are proposed to aid in computing the gap. We illustrate our approach using the infinite-range ferromagnetic Ising model and the Hopfield model, both in the presence of a transverse field.

arXiv:1803.08632•Physical review. B./Physical review. B•Mar 16, 2018•1 citation

Path integral methods for quantum dynamics in condensed phases

Tuseeta Banerjee

Quantum mechanical effects play an important role in dynamics of condensed phases. It is also well known that the difficulty of solving the full Schrödinger equation grows exponentially with time. One approach to cope up with this difficulty is to restrict quantum treatment to a few particles (system) and treat the dynamics of the rest of particles (bath) using classical trajectories. Path integral methods due to their trajectory like nature provide excellent tool to develop quantum-classical methods, but to capture long time dynamics, the number of classical trajectories grow exponentially. A part of this work focuses on improving Quantum-Classical Path Integral (QCPI) treatments that allow for larger path integral time step by building “smarter” propagators. These improved solvent-driven reference propagators is developed by incorporating physically motivated approximations to the solvent. When used in QCPI expression they allow convergence with larger time steps leading to an exponential reduction of the number of trajectories required. Further advantages of these propagators include improvements in path filtering techniques, smaller number of path integral steps for achieving the memory decoherence time, and smoothing of the integrand which leads to convergence with fewer Monte Carlo sample points. These ideas have been validated on the spin boson model - a prototypical model to study condensed phase dynamics, which consists of a two-level system coupled to a harmonic bath. The new approach of building the reference propagators combined with their iterative evaluation and filtering is validated using parameters that mimic the first electron transfer in wild-type photosynthetic reaction centres. A real-world dynamical simulation contains various anharmonic effects, Ferrocene (donor) - Ferrocenium (acceptor) system in liquid Benzene was studied where the anharmonic effects of the bath of liquid Benzene on the dynamics of the system were treated using Ensemble Averaged Classical Path. The process of electron or proton transfer occurs between two species having different charges and fluctuations in the solvent plays a key role in determining the rates of such reaction dynamics. To correctly account for the effects of initial distribution of the solvent on the dynamics of the quantum system, the concept of equilibrating the bath to the donor state of the system is used. Two different approaches have been used within the influence functional framework.

•Dec 2, 2015•0 citations

Weak-Field Expansion: A Time-Closed Solution of Quantum Three-Wave Mixing

Hanzhong Zhang, Avi Pe'er

We present a systematic derivation of the Heisenberg evolution of a trilinear bosonic Hamiltonian system in presence of a strong drive beyond the standard approximation of a classical, undepleted driving field. We employ a perturbative expansion of the Hamiltonian propagator in orders of the input field amplitudes, as opposed to the standard Baker-Campbell-Hausdorff (BCH) expansion of the propagator in orders of time. Our method automatically provides time-closed expressions; and converges considerably faster than BCH, especially in the regime of high parametric gain because the small parameter it uses is natural to the problem. We obtain the well-known quantum solution for optical parametric amplification of down-conversion simply as the first order of the expansion, and present the rigorous procedure to derive higher order corrections one by one. To demonstrate the utility of higher corrections, we discuss the 2nd order correction to the pump field as an ideal detector of time-energy entanglement in parametric down-conversion. We also use the 3rd order correction to calculate the limits on the achievable squeezing with parametric amplification and on the fidelity of quantum state-transfer from one optical mode to another with sum/difference frequency generation, due to the quantum properties of the strong driving field.

quant-pharXiv:2603.29869•Apr 1, 2026•0 citations
New nonperturbative methods for dealing with Hamiltonian systems are introduced. The derivation of these methods requires identities for rewriting exponentials of sums of operators which are different from the usual Campbell-Hausdorff formula. These identities allow one to derive approximations to e\ensuremath−\ensuremathδH{e}^{\ensuremath{-}\ensuremath{\delta}H}e\ensuremath−\ensuremathδH which are correct to higher order in \ensuremathδ\ensuremath{\delta}\ensuremathδ and which contain fewer terms than the Campbell-Hausdorff formula. This allows one to generate path-integral actions which are more accurate for finite-size steps in time and which can be exploited to improve the rate of convergence of Monte Carlo calculations. To show that these methods allow one to include effects which show up in the stationary-phase approximation to the path integral, e.g., instantons, solitons, etc., I not only derive the connection between the Hamiltonian and path-integral formalism but the relationship between a specific stationary-phase approximation and the corresponding Hamiltonian calculation. My focus, however, is the direct application of these new identities to the study of nonperturbative Hamiltonian dynamics. I show that these methods are easier to apply and give better results than those based upon the naive ttt-expansion, block mean-field, or real-space renormalization ideas. Comparison of these older methods with the computational tools introduced in this paper are discussed in the context of simple examples. It is shown that the new methods allow one to extrapolate answers to finite ttt without the use of Pad'e approximants.
Let us recapitulate. Although the form (4.32) for the path integral was motivated by analogy with finite-dimensional integrals, in no way is it a definition. Rather, as we have stressed repeatedly, it is an algorithm for handling the Feynman perturbation series. Strong coupling apart, all the manipulations of the path integral that we have performed (integration by parts, the introduction of auxiliary fields, the inclusion of background fields) stand in one-to-one correspondence to rearrangements of the perturbation series. In fact, path integrals are unnecessary in the derivation of expressions like (4.50). See Fried (1972), for example. The path integrals are as rigorous – or non-rigorous – as the series, irrespective of whether they can be given proper mathematical definition or not. At the same time, the analogy with finite-dimensional integrals suggests approaches that go beyond this purely operational stance. In particular, because of the dominant role played by the classical action in the path integral formalism we would like to use it to establish the relation of quantum dynamics to classical dynamics. This is the most compelling reason for introducing the path integral formalism, requiring a distinct relaxation in our treatment of it. By formal analogy with finite-dimensional saddle-point and stationary-phase methods, elevating the classical action to the phase of the integrand promotes series expansions in ħ as the natural way to proceed.
In this master thesis, a new approximation scheme to non-relativistic potential scattering is developed and discussed. The starting points are two exact path integral representations of the T-matrix, which permit the application of the Feynman-Jensen variational method. A simple Ansatz for the trial action is made, and, in both cases, the variational procedure singles out a particular one-particle classical equation of motion, given in integral form. While the first is real, in the second representation this trajectory is complex and evolves according to an effective, time dependent potential. Using a cumulant expansion, the first correction to the variational approximation is also evaluated. The high energy behavior of the approximation is investigated, and is shown to contain exactly the leading and next-to-leading order of the eikonal expansion, and parts of higher terms. Our results are then numerically tested in two particular situations where others approximations turned out to be unsatisfactory. Substantial improvements are found.
We continue our study of quantum dynamics on a Lie group GGG, initiated in arXiv:2512.19840, by building the path integral that governs transition amplitudes in the Hilbert space L2(G)L^2(G)L2(G). This relies on the proper handling of both a noncommutative momentum space and the presence of compact directions in GGG. We show that compactness can be handled through a sum over winding numbers in maximal tori of GGG, generalizing the similar sum commonly encountered for path integrals on a circle. As applications, we compute semiclassical approximations of propagators and partition functions of Euler-Arnold systems, up to (and including) two-loop order.
In current studies of mean-field quantum spin systems, much attention is placed on the calculation of the ground-state energy and the excitation gap, especially the latter, which plays an important role in quantum annealing. In pure systems, the finite gap can be obtained by various existing methods such as the Holstein-Primakoff transform, while the tunneling splitting at first-order phase transitions has also been studied in detail using instantons in many previous works. In disordered systems, however, it remains challenging to compute the gap of large-size systems with specific realization of disorder. Hitherto, only quantum Monte Carlo techniques are practical for such studies. Recently, Knysh [Nature Comm. 7, 12370 (2016)] proposed a method where the exponentially large dimensionality of such systems is condensed onto a random potential of much lower dimension, enabling efficient study of such systems. Here we propose a slightly different approach, building upon the method of static approximation of the partition function widely used for analyzing mean-field models. Quantum effects giving rise to the excitation gap and nonextensive corrections to the free energy are accounted for by incorporating dynamical paths into the path integral. The time-dependence of the trace of the time-ordered exponential of the effective Hamiltonian is calculated by solving a differential equation perturbatively, yielding a finite-size series expansion of the path integral. Formulae for the first excited-state energy are proposed to aid in computing the gap. We illustrate our approach using the infinite-range ferromagnetic Ising model and the Hopfield model, both in the presence of a transverse field.
Quantum mechanical effects play an important role in dynamics of condensed phases. It is also well known that the difficulty of solving the full Schrödinger equation grows exponentially with time. One approach to cope up with this difficulty is to restrict quantum treatment to a few particles (system) and treat the dynamics of the rest of particles (bath) using classical trajectories. Path integral methods due to their trajectory like nature provide excellent tool to develop quantum-classical methods, but to capture long time dynamics, the number of classical trajectories grow exponentially. A part of this work focuses on improving Quantum-Classical Path Integral (QCPI) treatments that allow for larger path integral time step by building “smarter” propagators. These improved solvent-driven reference propagators is developed by incorporating physically motivated approximations to the solvent. When used in QCPI expression they allow convergence with larger time steps leading to an exponential reduction of the number of trajectories required. Further advantages of these propagators include improvements in path filtering techniques, smaller number of path integral steps for achieving the memory decoherence time, and smoothing of the integrand which leads to convergence with fewer Monte Carlo sample points. These ideas have been validated on the spin boson model - a prototypical model to study condensed phase dynamics, which consists of a two-level system coupled to a harmonic bath. The new approach of building the reference propagators combined with their iterative evaluation and filtering is validated using parameters that mimic the first electron transfer in wild-type photosynthetic reaction centres. A real-world dynamical simulation contains various anharmonic effects, Ferrocene (donor) - Ferrocenium (acceptor) system in liquid Benzene was studied where the anharmonic effects of the bath of liquid Benzene on the dynamics of the system were treated using Ensemble Averaged Classical Path. The process of electron or proton transfer occurs between two species having different charges and fluctuations in the solvent plays a key role in determining the rates of such reaction dynamics. To correctly account for the effects of initial distribution of the solvent on the dynamics of the quantum system, the concept of equilibrating the bath to the donor state of the system is used. Two different approaches have been used within the influence functional framework.
We present a systematic derivation of the Heisenberg evolution of a trilinear bosonic Hamiltonian system in presence of a strong drive beyond the standard approximation of a classical, undepleted driving field. We employ a perturbative expansion of the Hamiltonian propagator in orders of the input field amplitudes, as opposed to the standard Baker-Campbell-Hausdorff (BCH) expansion of the propagator in orders of time. Our method automatically provides time-closed expressions; and converges considerably faster than BCH, especially in the regime of high parametric gain because the small parameter it uses is natural to the problem. We obtain the well-known quantum solution for optical parametric amplification of down-conversion simply as the first order of the expansion, and present the rigorous procedure to derive higher order corrections one by one. To demonstrate the utility of higher corrections, we discuss the 2nd order correction to the pump field as an ideal detector of time-energy entanglement in parametric down-conversion. We also use the 3rd order correction to calculate the limits on the achievable squeezing with parametric amplification and on the fidelity of quantum state-transfer from one optical mode to another with sum/difference frequency generation, due to the quantum properties of the strong driving field.