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Physica A Statistical Mechanics and its Applications

Violation of the second law of thermodynamics in the quantum microworld

Vladislav Čápek, Jiří Bok

Published Feb 1, 2001• 22 citations
Publisher
DOI
10.1016/s0378-4371(00)00345-9

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Several models of quantum open systems are known at present to violate, according to principles of the standard quantum theory of open systems, the second law of thermodynamics. Here, a new and rather trivial model of another type is suggested describing mechanism that violates, according to the same principles, the zeroth and the second laws of thermodynamics simultaneously. Up to a technically minor modification, the model resembles some models already known, solved by standard means, and properly understood. Universal validity of two basic principles of thermodynamics in strictly quantum situations is thus simultaneously called in question.
Abstract Thermodynamics was developed when it was still unclear whether the microworld had an atomic substructure. The objective here is to investigate the relationship between the process of a quantum measurement and the second law of thermodynamics. It is necessary to make the ideas of heat and work explicit in this approach. It is possible to study the correspondence between information entropy and thermodynamic entropy. Finally, a model is proposed in such a way as to resemble an experimental example for the discussion.