Physical Review Letters
Measurement and Cancellation of the Cold Collision Frequency Shift in an 87Rb Fountain Clock
Chad Fertig, Kurt Gibble
Abstract
We measure a cold collision frequency shift in an ${}^{87}\mathrm{Rb}$ fountain clock that is fractionally 30 times smaller than that for Cs. The shift is $\ensuremath{-}0.38(8)\mathrm{mHz}$ for a density of $1.0(6)\ifmmode\times\else\texttimes\fi{}{10}^{9}{\mathrm{cm}}^{\ensuremath{-}3}$. We study the cavity pulling of the atomic transition and use it to cancel the cold collision shift. We also measure the partial frequency shifts of each clock state finding $2({\ensuremath{\lambda}}_{10}\ensuremath{-}{\ensuremath{\lambda}}_{20})/({\ensuremath{\lambda}}_{10}+{\ensuremath{\lambda}}_{20})\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}0.1(6)$.