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Journal of Physics B Atomic Molecular and Optical Physics

Wavefunction localisation for the hydrogen atom in parallel electric and magnetic fields

Saverio Bivona, Wolfgang Schweizer, Patrick F. O’Mahony, K T Taylor

Published Oct 28, 1988• 11 citations

Abstract

A quantum mechanical study of a simple two-dimensional problem identifies lines in coordinate space about which the probability densities are localised. These lines in general do not correspond to extrema in the system's static potential energy surface. The subject of this study has been the hydrogen atom in externally applied parallel electric and magnetic and magnetic fields. Probability density plots of eigenstates, in which the electron experiences comparable influences from all three fields: Coulomb, electric and magnetic, are each found to display a localisation at a polar angle related to an invariant previously obtained in a classical study of the problem. The line about which localisation occurs is found to vary with energy and is in coincidence with a periodic trajectory found within a classical framework.

DOI: 10.1088/0953-4075/21/20/001

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A quantum mechanical study of a simple two-dimensional problem identifies lines in coordinate space about which the probability densities are localised. These lines in general do not correspond to extrema in the system's static potential energy surface. The subject of this study has been the hydrogen atom in externally applied parallel electric and magnetic and magnetic fields. Probability density plots of eigenstates, in which the electron experiences comparable influences from all three fields: Coulomb, electric and magnetic, are each found to display a localisation at a polar angle related to an invariant previously obtained in a classical study of the problem. The line about which localisation occurs is found to vary with energy and is in coincidence with a periodic trajectory found within a classical framework.

The hydrogen atom is the simplest of all atoms consisting of proton of charge e and the electron of charge −e. It is a two particle system. A two-body problem can always be reduced to a one-body problem by choosing the center of mass coordinate and the relative coordinates. In the hydrogen atom the attractive force exerted by the proton on electron prevents it from escape. The potential energy V of the system is −e2/r where r is the distance between the electron and the proton. Suppose the nucleus is held fixed at the origin of coordinates. V (r) is independent of θ and φ, that is, insensitive to the direction of r and depends only on the scalar magnitude r. The potential energy remains invariant under rotation and is said to be spherically symmetric. Figure 12.1 shows V (r) as a function of r. In this chapter the hydrogen atom problem in threedimension is solved and momentum eigenfunction is obtained. The problem in D-dimension where D may be noninteger is analysed. The magnetic field produced by a hydrogen atom is worked out. Finally, the system in parabolic coordinates is discussed.

Statistics of tunneling rates in the presence of chaotic classical dynamics is discussed on a realistic example: a hydrogen atom placed in parallel, uniform, static electric, and magnetic fields, where tunneling is followed by ionization along the fields direction. Depending on the magnetic quantum number, one may observe either a standard Porter-Thomas distribution of tunneling rates or, for strong scarring by a periodic orbit parallel to the external fields, strong deviations from it. For the latter case, a simple model based on random matrix theory gives the correct distribution.

The polarization properties of a beam of radiation interacting with a hydrogen atom subject to simultaneous stationary electric and magnetic fields are investigated, assuming no constraints on the direction of the two fields. The problem of determining the energy eigenstates is solved within the theory of Rayleigh-Schrodinger for the stationary perturbations (the contributions of the fine and hyperfine structure of the energy spectrum are also accounted for). Then the polarized transition rates (for absorption, spontaneous emission and stimulated emission) are evaluated according to the methods of non-relativistic quantum electrodynamics, adopting the density matrix formalism which allows one to deal with partially polarized states of the atomic and the radiation field systems

The motion of a multi-electronic atom in an external electro-magnetic field is reconsidered. We prove that according to classical mechanics and electrodynamics, the assumption that the interaction with the magnetic field is described by means of a potential energy is no valid, and the trajectory of the center of mass can be deflected by a magnetic field, even if the internal angular momentum is zero. The characteristic equation of the corresponding hamiltonian is not separable in three degrees of freedom for the hydrogen atom.