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Journal of the Physical Society of Japan

The Coherence Theory of the Bose-Einstein Condensation

Yutaka Kano

Published Mar 1, 1974• 4 citations
Publisher

Abstract

The coherent-state representation of the density operator for an ideal Bose gas in a thermal equilibrium is introduced. It is shown that a pure coherent state can be an eigenstate of the Hamiltonian of the non-interacting boson system when the symmetry breaking term is added to it. However, at the limit of the vanishing “classical field” only zero-energy states can be a coherent state. It is also proved that the pure coherent state is the lowest energy state among all the zero-momentum states. The temperature dependence of the coherent state is then discussed. The diminution of the coherent state can clearly be seen as the temperature rises from zero to the critical temperature.

DOI
10.1143/jpsj.36.649

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The coherent-state representation of the density operator for an ideal Bose gas in a thermal equilibrium is introduced. It is shown that a pure coherent state can be an eigenstate of the Hamiltonian of the non-interacting boson system when the symmetry breaking term is added to it. However, at the limit of the vanishing “classical field” only zero-energy states can be a coherent state. It is also proved that the pure coherent state is the lowest energy state among all the zero-momentum states. The temperature dependence of the coherent state is then discussed. The diminution of the coherent state can clearly be seen as the temperature rises from zero to the critical temperature.
The nature of the Einstein-Bose condensation in an imperfect boson gas is discussed. It is argued that no matter how low the temperature, provided it is not zero, macroscopic second-sound waves should be weakly excited as thermal fluctuations about equilibrium. This implies that the single-particle momentum distribution must be smeared so that the state of zero momentum cannot contain a finite fraction of the particles. A microscopic mechanism which independently leads to a momentum spread is discussed. It is suggested that the actual Einstein-Bose condensation of an imperfect gas takes place in energy rather than momentum but that even in terms of this variable it becomes perfectly sharp only at zero temperature. This hypothesis is formulated analytically in terms of correlation functions of the second-quantized boson field.
The theory of non-interacting Bose gases is supplemented by a numerical quantum field description with a two-dimensional non-local order parameter that allows the modeling of wave-like atomic correlations and interference effects in the limit of low atomic densities. From the present model, it is possible to explain symmetry aspects of non-interacting and very weakly interacting Bose gases in the limit of fluctuating particle numbers, like the forward propagation of time and the relation to the breaking and preservation of phase gauge symmetry in solids. In the present formalism, the propagation of one-directional time arises from the pre-defined and equivalent convergence of independent quantum fields towards the Boltzmann equilibrium, and it is shown that Glauber coherent states are related to the definition of the quantized field. Coherently coupling condensate and non-condensate parts as a direct consequence of the increasing quantum coherence time between the different quantum field components in the Bose gas from cooling to below the critical temperature, the present model describes symmetry breaking, which is originally known from the definition of a specific gauge field from Elitzur's theorem for local gauge fields, as a global physical rather than a purely formal mathematical process.
The topic of Bose–Einstein condensation in a uniform, non-interacting gas of bosons is treated in most textbooks on statistical mechanics. In the present chapter we discuss the properties of a non-interacting Bose gas in a trap. We shall calculate equilibrium properties of systems in a semi-classical approximation, in which the energy spectrum is treated as a continuum. For this approach to be valid the temperature must be large compared with Δ∊/ k , where Δ∊ denotes the separation between neighbouring energy levels. As is well known, at temperatures below the Bose–Einstein condensation temperature, the lowest-energy state is not properly accounted for if one simply replaces sums by integrals, and it must be included explicitly. The statistical distribution function is discussed in Sec. 2.1, as is the single-particle density of states, which is a key ingredient in the calculations of thermodynamic properties. Calculations of the transition temperature and the fraction of particles in the condensate are described in Sec. 2.2. In Sec. 2.3 the semi-classical distribution function is introduced. From this we obtain the density profile and the velocity distribution of particles, and use these to determine the shape of an anisotropic cloud after free expansion. Thermodynamic properties of Bose gases are calculated as functions of the temperature in Sec. 2.4. Finally, Sec. 2.5 treats corrections to the transition temperature due to a finite particle number.
The topic of Bose–Einstein condensation in a uniform, non-interacting gas of bosons is treated in most textbooks on statistical mechanics. In the present chapter we discuss the properties of a non-interacting Bose gas in a trap. We shall calculate equilibrium properties of systems in a semi-classical approximation, in which the energy spectrum is treated as a continuum. For this approach to be valid the temperature must be large compared with Δ∈/ k , where Δ∈ denotes the separation between neighbouring energy levels. As is well known, at temperatures below the Bose–Einstein condensation temperature, the lowest energy state is not properly accounted for if one simply replaces sums by integrals, and it must be included explicitly. The statistical distribution function is discussed in Sec. 2.1, as is the single-particle density of states, which is a key ingredient in the calculations of thermo dynamic properties. Calculations of the transition temperature and the fraction of particles in the condensate are described in Sec. 2.2. In Sec. 2.3 the semi-classical distribution function is introduced, and from this we determine the density profile and the velocity distribution of particles. Thermodynamic properties of Bose gases are calculated as functions of the temperature in Sec. 2.4. The final two sections are devoted to effects not captured by the simplest version of the semi-classical approximation: corrections to the transition temperature due to a finite particle number (Sec. 2.5), and thermodynamic properties of gases in lower dimensions (Sec. 2.6).
Bose–Einstein condensation is a phenomenon, first proved by Einstein, in which a gas of bosons condenses into the lowest quantum state below a certain critical temperature. It occurs due to the symmetry, under particle exchange, of the boson wave function. The chapter discusses temperature, the Kelvin scale, the concept of absolute zero, and how laser cooling can reach ultralow temperatures. The property of bosons in which they often prefer to be in the same state is seen to apply to lasers, superfluid liquid helium, and to dilute nearly ideal gases. The latter are trapped in magnetic or optical potential wells where the condensation can be observed directly. These large condensate matter waves show quantum interference in a variety of possible experiments.