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American Journal of Physics

The role of continuum states in perturbation theory

Viktor Urumov, Gjorgji Ivanovski

Published Oct 1, 1983• 2 citations
Publisher

Abstract

An example of a three-dimensional Schrödinger equation is solved exactly and it is shown that the potential can sustain an arbitrary number of bound states. Nevertheless, in the second-order perturbation theory all the contributions for all bound states come from the continuum states if the perturbation is spherically symmetric. This is also true for any central potential that does not show accidental degeneracy and has both bound and unbound states, when the perturbation is another central potential.

DOI
10.1119/1.13393

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An example of a three-dimensional Schrödinger equation is solved exactly and it is shown that the potential can sustain an arbitrary number of bound states. Nevertheless, in the second-order perturbation theory all the contributions for all bound states come from the continuum states if the perturbation is spherically symmetric. This is also true for any central potential that does not show accidental degeneracy and has both bound and unbound states, when the perturbation is another central potential.
In nonrelativistic quantum mechanics, we require that the free and interacting Hamiltonians be related by a unitary transformation, as has been done by other authors. We then derive a stationary perturbation theory for the radial Schrödinger equation for scattering from a spherically symmetric potential. A resulting advantage over the more commonly used Green function method is that the expression for the interacting state vector is normalized to each order in the coupling constant, unlike, in general, the result of the Green function method. Other authors have applied the unitary transformation concept to time-dependent perturbation theory to give unitarity of the time evolution operator to each order in perturbation theory, with results that show improvement over the standard perturbation theory. In this paper, general formulas are obtained for the phase shifts at the first and second order in the coupling constant. We test the method on a simple system with a known exact solution and find complete agreement between our first- and second-order contributions to the s-wave phase shifts and the corresponding expansion to the second order of the exact solution.
The bound states of a weak attractive potential never come out of doing perturbation theory on free particle states. This is a quite general rule: if the perturbation commutes with a constant of the motion, A, of the unperturbed Hamiltonian, then matrix elements of the perturbation between eigenstates of A with different eigenvalues must vanish. This rule, an example of a selection rule, often simplifies the problem of selecting the correct linear combination of degenerate states with which to do the perturbation expansion. The Rayleigh-Schrodinger perturbation theory – yields rather complicated expressions for the change in the states in second order and beyond. There is a somewhat different form of the perturbation theory, due to Brillouin and Wigner that enables to see more clearly the structure of the perturbed states.
We show that the δ-function potential can be exploited along with perturbation theory to yield the result of certain infinite series. The idea is that any exactly soluble potential, if coupled with a δ function potential, remains exactly soluble. We use the strength of the δ function as an expansion parameter and express the second-order energy shift as an infinite sum in perturbation theory. The analytical solution is used to determine the second-order energy shift and hence the sum of an infinite series. By an appropriate choice of the unperturbed system, we can show the importance of the continuum in the energy shift of bound states.
We consider the quantum-mechanical problem of a particle bound to a configuration of spherical potentials, each of finite range. If the Schr\"odinger equation can be solved for each potential by itself, then it is shown how to solve it for the configuration, provided the potentials do not overlap. The energy levels are the zeros of a determinant of formally infinite order, but in practice this is always well approximated by a finite determinant and often by one of small order. As illustrative examples we consider some states of a particle bound to three square wells with the configuration of an equilateral triangle, and to two truncated Coulomb potentials. The possibility of extending an approximate version of the method to overlapping potentials is pointed out.