The scattering of a wave packet by a finite range potential may be described by a wave function in which the initial state is specified at time t = 0 , and the time dependence appears in functions M(r, k, t), first obtained by Moshinsky.
A one-dimensional scattering problem off a delta-shaped potential is solved analytically and the time development of a wave packet is derived from the time-dependent Schrödinger equation. The exact and explicit expression of the scattered wave packet supplies us with interesting information about the "time delay" by potential scattering in the asymptotic region. It is demonstrated that a wave packet scattered by a spin-flipping potential can give us quite a different value for the delay times from that obtained without spin-degrees of freedom.
A wave-packet formalism is presented for obtaining the differential cross section for the elastic scattering of a single particle by a potential. The method avoids difficulties inherent in the more common formulations such as interference between incident and scattered waves, box normalization, and density of final states. The time sequence of events in the scattering process is pictured in an intuitively appealing manner. The initial form of the wave packet is specified explicitly, and the time development of the wave packet is determined from the time-translation operator. The asymptotic form of the wave packet is investigated after a sufficiently long time lapse, and the cross section is obtained from a calculation of particle flux densities.
Two-body scattering is analyzed using a time-dependent formalism and wave packets of arbitrary shape as the initial wavefunctions. In particular, the case of single-channel resonant scattering is discussed in some detail. In addition to the usual amplitudes resulting from the potential term and the resonant term, a third amplitude is found which interferes with the other two. Another interesting result is that in this formalism the final state is not necessarily represented by spherical outgoing waves, but can be interpreted instead as two separate outgoing wave packets whose shape is different from the initial packets. The Wigner time delay is obtained as a natural consequence of the analysis, and the resonant cross sections are expressed as density matrices constructed from the wave packets.
We derive and explain the key ideas behind a time-dependent formulation of quantum scattering theory, applicable generally to systems with a finite-range scattering potential. The scattering is initiated and probed by plane wave packets, which are localized just outside the range of the potential. The asymptotic limits of conventional scattering theory (initiation in the remote past; detection in the remote future) are not taken. Instead, the differential cross section (DCS) is obtained by projecting the scattered wave packet onto the probe plane wave packets. The projection also yields a time-dependent version of the DCS. Cuts through the wave packet, just as it exits the scattering potential, yield time-dependent and time-independent angular distributions that give a close-up picture of the scattering which complements the DCS. We have previously applied the theory to interpret experimental cross sections of chemical reactions [e.g., S. C. Althorpe, F. Fern\'andez-Alonso, B. D. Bean, J. D. Ayers, A. E. Pomerantz, R. N. Zare, and E. Wrede, Nature (London) 416, 67 (2002)]. This paper gives the derivation of the theory, and explains its relation to conventional scattering theory. For clarity, the derivation is restricted to spherical-particle scattering, though it may readily be extended to general multichannel systems. We illustrate the theory using a simple application to hard-sphere scattering.