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Progress of Theoretical Physics

On Collective and Internal Motions in a Bose System

Toshiyuki Nishiyama

Published May 1, 1957• 3 citations
Publisher

Abstract

By introducing a number of auxiliary variables, quantum-mechanical collective and internal motions in a Bose system are described. In a collective representation obtained here, the wave functions are expressed as functions of the auxiliary variables and the internal coordinates. The energy for the ground state and the excitation energies of collective motion and internal motion are obtained for the case of a long-range interaction potential. The lowest energy obtained proves to be smaller than that afforded by the Hartree-Fock approximation. The excitations of the collective motion with smaller wave numbers than a cut-off wave number kc correspond to Landau's phonons. The excitations of the internal motion resemble Landau's rotons; but they are forbidden for the smaller wave numbers K ≦ kc. When one applies this method to the problem of liquid helium, it becomes necessary to take account of the two-body correlation of individual particles. It is pointed out that the phonon energy depends upon the zero-point motion of the individual particles.

DOI
10.1143/ptp.17.711

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By introducing a number of auxiliary variables, quantum-mechanical collective and internal motions in a Bose system are described. In a collective representation obtained here, the wave functions are expressed as functions of the auxiliary variables and the internal coordinates. The energy for the ground state and the excitation energies of collective motion and internal motion are obtained for the case of a long-range interaction potential. The lowest energy obtained proves to be smaller than that afforded by the Hartree-Fock approximation. The excitations of the collective motion with smaller wave numbers than a cut-off wave number kc correspond to Landau's phonons. The excitations of the internal motion resemble Landau's rotons; but they are forbidden for the smaller wave numbers K ≦ kc. When one applies this method to the problem of liquid helium, it becomes necessary to take account of the two-body correlation of individual particles. It is pointed out that the phonon energy depends upon the zero-point motion of the individual particles.
The method of “auxiliary variables” (collective coordinates) used by Bogolyubov and Zubarev is formulated in a somewhat different manner. Improvements are made in two points: 1) The Hamiltonian is given in an Hermitian form and 2) the number of the auxiliary variables can be limited, if necessary. We calculate the ground state energy and the excitation energy spectrum of the spinless bosons taking account of phonon-phonon interactions. The expression for the ground state energy is shown to be equivalent to the one derived by Bogolyubov and Zubarev.
In this paper we suggest a new ground-state wave function and low-temperature density matrix for a strongly interacting system of bosons. Our basic assumption is that the system can support long-wavelength phonons and that these can propagate independently of any other mode of motion. We therefore write the ground-state function as the product of two factors. One factor arises from the zero-point motion of the phonons, and we show that it has the form ${\ensuremath{\Pi}}_{i<j}f({r}_{\mathrm{ij}})$, where lnf(r)\mathrm{ln}f(r)lnf(r) has an infinite range. The other factor is assumed to have this same form but with lnf(r)\mathrm{ln}f(r)lnf(r) of finite range; it takes into account the short-range correlations arising from the strong repulsive part of the interparticle potential. The function we have chosen to represent the short-range correlations is not new; functions of this kind were first introduced by Bijl and later by Jastrow. At finite temperatures we use a density matrix for an ensemble of excited phonon states. We find that for small wave vectors kkk, the structure factor S(k)S(k)S(k) is equal to $\frac{\ensuremath{\hbar}k}{2mc}$, a result that was first derived by Feynman. At a finite temperature TTT, S(k)S(k)S(k) tends to the constant value kBTmc2\frac{{k}_{B}T}{m{c}^{2}}mc2kB​T​, where mmm is the mass of the particles and ccc the velocity of propagation of the phonons. The momentum distribution nk{n}_{k}nk​ has a ${k}^{\ensuremath{-}1}$ singularity at absolute zero and a stronger, ${k}^{\ensuremath{-}2}$ singularity at finite temperatures. The small-kkk behavior of both S(k)S(k)S(k) and nk{n}_{k}nk​ is completely controlled by the correlations introduced by the phonons. Both the ground-state function and the density matrix imply that there is a finite fraction of particles in the zero-momentum state in three dimensions; this fraction does not seem to be appreciably affected by the infinite-range correlations introduced by the phonons. We find, however, that these correlations imply that a one-dimensional Bose system does not exhibit Bose-Einstein condensation at any temperature, while a two-dimensional system exhibits Bose-Einstein condensation only at absolute zero.
The method of auxiliary variables is generalized so as to be applicable to the systems having strong interparticle interactions or obeying Fermi-Dirac statistics. The ground state energy and the excitation energy specrum are calculated to the zeroth approximation. It is shown that Feynman's relation for liquid helium and Tomonaga's expression for a one-dimensional Fermi gas can be derived as the special cases of the present theory. The theory is applied also to the classical statistical mechanics.
With the aid of the displacement method, the wave function of interacting bosons is represented as a product of the ground state function and the function describing the excitations in the system. The equations for these functions are solved in the collective variables representation by means of a special perturbation method free of divergences. The expressions obtained for the wave functions, the energy of the ground state, the energy spectrum and the damping of collective excitations are investigated. (auth)
An alternative approach to the quantum statistics of interacting particles is proposed. It consists of calculating the equilibrium thermodynamical quantities of the many-body system via the pair distribution function with the assumption that the particles interact with each other only through pair central forces. The proposed approach has some advantage over the usual treatment via the partition function in that the pair distribution function is easier to deal with than the partition function in certain circumstances particularly when the collective motion description of the system is desirable. This is because only the pair distribution function can be expressed directly in terms of the collective interaction which is closely connected with collective elementary excitation, such as a plasmon in the electron gas and a phonon in the hard-sphere Boson gas. The equation of state as well as the internal energy are obtained in the form of integrals of the pair distribution function. The close analogy between the pair distribution function and the two-body propagator, which appears in the quantum field theory, makes it possible to analyze the former by the use of Feynman diagrams identical with those usually introduced for the latter. The collective interaction, which is defined by the sum of the direct and the indirect interactions, is introduced as a particular partial sum of the perturbation series of the pair distribution function. This is used in rewriting the pair distribution function in terms of the collective interaction.It is shown that, while the simple chain approximation to the collective interaction in the electron gas is responsible for the transfer of a plasmon, the same approximation to the collective pseudo-interaction in the hard-sphere Boson system has a relation similar to that of transfer of a phonon, both cases occuring at low temperatures. The explicit calculation of the pair distribution functions for these systems at the absolute zero temperature is carried out up to the first order in the collective interaction (simple chain approximation.) These results are used to calculate the ground-state energies. For the electron gas the energy thus obtained confirms Gell-Mann-Bruckner's calculation of the correlation energy. For the hard-sphere Bosons the calculated energy reproduces the result of Lee, Huang, and Yang. The extension of the calculation to the finite temperature case is also indicated. In particular the classical Debye-Huckel equation of state for the electron gas is briefly discussed.