Thermodynamic origin of the contact
Vı́ctor Romero-Rochı́n
As can be inferred from present experiments in ultracold gases, the scattering length is a quantity that determines the thermodynamic state of the gas. As such, a conjugate thermodynamic variable to it exists. Here, we show that the recently introduced contact is the conjugate of the inverse of the scattering length. We find that this identification, in addition to well-known approximations, allows for a derivation of three of the most relevant results concerning the contact, namely its relation to the adiabatic change of the energy, the general form of the energy and the generalized virial theorem. We find that the current identification of the contact variable depends on the use of the contact approximation for the intermolecular potential but it is independent of whether the gas is made out of fermions or bosons and of the strength of the interaction.
Journal of Physics B Atomic Molecular and Optical Physics•Apr 21, 2011•4 citations