Physical Review A
Quadratic fluctuation-dissipation theorem: The quantum domain
Gabor J. Kalman, Xiao-Yue Gu
Abstract
A derivation of a general relationship between the frequency- and wave-number-dependent longitudinal quadratic response functions and the three-point dynamical structure function (the Fourier transform of the equilibrium three-point density-density correlations) is presented. This relationship is the full quadratic equivalent, valid for quantum systems of arbitrary degeneracy, of the customary (linear) fluctuation-dissipation theorem. The high-temperature limit reproduces earlier classical results, while its zero-temperature limit is characterized by a piecewise analytic behavior in the (${\ensuremath{\omega}}_{1}$${\ensuremath{\omega}}_{2}$) plane, generated by the respective dominance of the differently ordered triplets of density operators. There are two main versions of the theorem. In the first the completely symmetrized combination of the three-point functions is expressed in terms on a ``triangle-symmetrized'' [in the (k\ensuremath{\omega}) space] combination of the response functions. In the second ``inverted'' form, each of the six differently ordered three-point functions is expressed in terms of combinations of response functions, where the triangle symmetry is broken.