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Modern Physics Letters A

TEMPORAL DESCRIPTION OF THERMAL QUANTUM FIELDS

Hiroomi Umezawa, Y. Yamanaka

Published Dec 7, 1992• 16 citations
Publisher

Abstract

By making use of time-dependent Bogoliubov transformations, we develop a calculation technique for time-dependent non-equilibrium systems of quantum fields in a time-representation (t-representation). The corrected one-body propagator in the t-representation turns out to have the form B−1 (diagonal matrix) B (B being a thermal Bogoliubov matrix). Applying the usual on-shell concept to the diagonal matrix part of the self-energy, we formulate a self-consistent renormalization scheme. This renormalization determines the vacuum and leads to a kinetic equation for the number density parameter, which reduces to the Boltzmann equation in the lowest approximation. This gives us the increasing entropy in time (the second law of thermodynamics).

DOI
10.1142/s0217732392002925

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Modern Physics Letters A•Dec 14, 1992•12 citations
By making use of time-dependent Bogoliubov transformations, we develop a calculation technique for time-dependent non-equilibrium systems of quantum fields in a time-representation (t-representation). The corrected one-body propagator in the t-representation turns out to have the form B−1 (diagonal matrix) B (B being a thermal Bogoliubov matrix). Applying the usual on-shell concept to the diagonal matrix part of the self-energy, we formulate a self-consistent renormalization scheme. This renormalization determines the vacuum and leads to a kinetic equation for the number density parameter, which reduces to the Boltzmann equation in the lowest approximation. This gives us the increasing entropy in time (the second law of thermodynamics).
Making use of the thermo field dynamics (TFD) we formulate a calculable method for time-dependent nonequilibrium systems in a time representation (t-representation) rather than in the k0-Fourier representation. The corrected one-body propagator in the t-representation has the form of B−1 (diagonal matrix) B (B being a thermal Bogoliubov matrix). The number parameter in B here is the observed number (the Heisenberg number) with a fluctuation. With the usual definition of the on-shell self-energy a self-consistent renormalization condition leads to a kinetic equation for the number parameter. This equation turns out to be the Boltzmann equation, from which the entropy law follows.
The renormalization scheme in nonequilibrium thermal quantum field theories is reexamined. Instead of the self-energy diagonalization scheme, we propose to diagonalize Green’s function at equal time. This eliminates the problem of on-shell definition related to time-dependent energies and spatially inhomogeneous situations, and yields a Boltzmann equation that contains memory effect. The new diagonalization scheme and the derivation of the Boltzmann equation from it can be applied to any thermal situation. It allows the treatment of a nonequilibrium problem beyond perturbational calculations in a self-consistent manner. The results are applicable to both thermo field dynamics and the closed time path formalism.
It is well known that physical particles are thermally dissipative at finite temperature. In this paper we reformulate both the equilibrium and nonequilibrium thermal field theories in terms of stable quasiparticles. We will redefine the thermal doublets, the double tilde conjugation rules and the thermal Bogoliubov transformations so that our theory can be consistent for most general situations. All operators, including the dissipative physical particle operators, are realized in a Fock space defined by the stable quasiparticles. The propagators of the physical particles are expressed in terms of the operators of such stable quasiparticles, which is a simple diagonal matrix with the diagonal elements being the temporal step functions, same as the propagators in the usual quantum field theory without thermal degrees of freedom. The proper self-energies are also expressed in terms of these stable quasiparticle propagators. This formalism inherits the definition of on-shell self-energy in the usual quantum field theory. With this definition, a self-consistent renormalization is formulated which leads to quantum Boltzmann equation and the entropy law. With the aid of a doublet vector algebra we have an extremely simple recipe for computing Feynman diagrams. We apply this recipe to several examples of equilibrium and nonequilibrium two-point functions, and to the kinetic equation for the particle numbers.
The way to determine the renormalized energy of inhomogeneous systems of a quantum field under an external potential is established for both equilibrium and nonequilibrium scenarios based on thermo field dynamics. The key step is to find an extension of the on-shell concept valid in homogeneous case. In the nonequilibrium case, we expand the field operator by time-dependent wavefunctions that are solutions of the appropriately chosen differential equation, synchronizing with temporal change of thermal situation, and the quantum transport equation is derived from the renormalization procedure. Through numerical calculations of a triple-well model with a reservoir, we show that the number distribution and the time-dependent wavefunctions are relaxed consistently to the correct equilibrium forms at the long-term limit.
We consider the temporal evolution of the entropy S of an isolated system from an initial non-equilibrium state 2· of entropy S = S i to the equilibrium state of maximum entropy S = S max > S i. The application of usual density matrix theory of quantum mechanics leads us to the surprising result P = dS/dt = 0. The entropy does not change in time. This result is valid in case of the equilibrium state. However it is wrong for a non-equilibrium state, because the entropy of the isolated system could not spontaneously increase from S i to S max by entropy production P > 0. This contradicts the second law of thermodynamics. We avoid this discrepancy by changing from quantum mechanics to quantum thermodynamics. Now the entropy production P = dS/dt and the time t are the relevant observables. In order to treat the temporal development of S and P, we at first prepare an initial state i of entropy production P i at time t < 0. Subsequently at ϑ t ≥ 0 the initial state i interacts with a continuum of final states f, which transfers the entropy production from i to f. The temporal evolution of the entropy production P(t) of our system is treated by means of the time-dependent perturbation theory. For that reason we split the operator of entropy production P = P 0 + W into two parts. The operator P 0 describes the unperturbed basic vectors of entropy production | i > and | f >, while the perturbation operator W determines the interaction between | i > and | f >. We expand the time-dependent state function < t | ψ > of the isolated system into the complete set of stationary eigenvectors | i > and | f > and calculate the time-dependent expansion coefficients c i(t) and c(f, t) by means of the dynamic equation of quantum thermodynamics − i k (d/dt) < t | ψ > = < t | P | ψ >. Here k means the Boltzmann constant, which is characteristic of quantum thermodynamics and represents the atomic entropy unit. The expansion coefficients are given by a system of coupled differential equations, from which we deduce an integral-differential equation for the coefficient c i(t) of the initial state i. Unfortunately it has been impossible to obtain an analytic solution of the complicated equation. However approximations are available. Accordingly, in the vicinity of the equilibrium state, the probability of still finding the initial state i of entropy production P i at time t is given by ω i(t) = | c i(t) |2 = exp (−Lt). The rate constant L ≥ σ depends on the density ρ(P f) of final states f of entropy production P f near by P i, and on the squared modulus of the perturbation matrix elements W if = < i | W | f >, which determines the interaction between | i > and | f >. The entropy production P(t) = P i ω i(t) = P i exp (−ϑLt) of the isolated system decreases exponentially and irreversibly with proceeding time t. Its rate-determining step is the transfer of entropy production from i to f. The integral over the entropy production of the final states f vanishes. Therefore the continuum states f do not contribute to the total entropy production P(t). The temporal evolution of the entropy S(t) can easily be calculated by integration of P(t). In conclusion, the entropy production of a non-equilibrium state is finite P(t) > 0 and only vanishes in the case of the equilibrium state P(∞) = 0. Thus, quantum thermodynamics agrees with the second law of thermodynamics.