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Physical Review A

Quantum electrodynamics in the presence of dielectrics and conductors. IV. General theory for spontaneous emission in finite geometries

G. S. Agarwal

Published Oct 1, 1975• 224 citations
Publisher

Abstract

A quantum-electrodynamic theory of spontaneous emission in presence of dielectrics and conductors is developed. The theory makes use of the master-equation techniques and the response-function formalism of part I of this series of papers. Various observable entities such as damping coefficients (lifetimes), Lamb shifts, and frequency shifts are related to the appropriate surface-dependent response functions. The results are valid for arbitrary geometries (involving linear dielectrics) and naturally contain, as a special case, the usual results of spontaneous emission in free space. As explicit examples we consider a two-level atom (also the multilevel atom) in presence of a plane dielectric interface and between two conducting plates. Formulas for the shifts and widths are given and their asymptotic behavior for large and short distances is discussed. The behavior when the atom is embedded inside the dielectric is different than when the atom is outside the dielectric. The origin of coherence in the present model is discussed and the coherence effects in this model are contrasted with those in Dicke's model. The results are also compared with those obtained by the image method. Exact expressions for the operator radiation-reaction fields are obtained in terms of the atomic polarization operators and response functions. Approximate results for such fields are also given. The far-zone behavior of the radiation fields is obtained in terms of response functions and the polarization operators. Some of the normally ordered correlation functions are also calculated. The connection of some of the theoretical results with a recent experimental work of Carniglia, Mandel, and Drexhage is discussed. The effect of anisotropy of the dielectric function on the lifetimes as well as on the far-field correlation functions is also considered. Finally the contribution to the shifts and widths due to the excitation of surface polariton modes is computed and the results are compared with those obtained by the quantization of surface polariton field. It is found that such surface modes contribute significantly to widths.

DOI
10.1103/physreva.12.1475

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A quantum-electrodynamic theory of spontaneous emission in presence of dielectrics and conductors is developed. The theory makes use of the master-equation techniques and the response-function formalism of part I of this series of papers. Various observable entities such as damping coefficients (lifetimes), Lamb shifts, and frequency shifts are related to the appropriate surface-dependent response functions. The results are valid for arbitrary geometries (involving linear dielectrics) and naturally contain, as a special case, the usual results of spontaneous emission in free space. As explicit examples we consider a two-level atom (also the multilevel atom) in presence of a plane dielectric interface and between two conducting plates. Formulas for the shifts and widths are given and their asymptotic behavior for large and short distances is discussed. The behavior when the atom is embedded inside the dielectric is different than when the atom is outside the dielectric. The origin of coherence in the present model is discussed and the coherence effects in this model are contrasted with those in Dicke's model. The results are also compared with those obtained by the image method. Exact expressions for the operator radiation-reaction fields are obtained in terms of the atomic polarization operators and response functions. Approximate results for such fields are also given. The far-zone behavior of the radiation fields is obtained in terms of response functions and the polarization operators. Some of the normally ordered correlation functions are also calculated. The connection of some of the theoretical results with a recent experimental work of Carniglia, Mandel, and Drexhage is discussed. The effect of anisotropy of the dielectric function on the lifetimes as well as on the far-field correlation functions is also considered. Finally the contribution to the shifts and widths due to the excitation of surface polariton modes is computed and the results are compared with those obtained by the quantization of surface polariton field. It is found that such surface modes contribute significantly to widths.
In this paper the physical entities such as transition probabilities and the density of states are related to appropriate electromagnetic-field correlation functions and to appropriate response functions. Such response functions have already been computed in a previous paper and therefore these can be used to obtain surface-dependent corrections. It is shown how the density of states and hence Planck's law depends on the presence of surfaces. I explicitly calculate the correction terms for the case of a small blackbody bounded by two plane conducting surfaces. An appreciable correction occurs if the linear dimensions of the blackbody are of the order of a wavelength. Next electric-dipole-type transitions in atomic systems are considered and a straightforward perturbation theory is used to obtain one-photon transition probabilities in terms of the surface-dependent response functions. As an illustration of the surface-dependent terms, the transitions in presence of a conducting surface are considered. The transition probabilities show a marked increase or decrease depending on whether the dipole transition is parallel or perpendicular to the surface. Both stationary and nonstationary fields are considered. As a special case of nonstationary fields, the transitions in a coherent field are considered in detail. It is also shown how the coherent radiation field in presence of dielectrics can be realized. It is found that if the radiation field, in arbitrary geometries, is initially in vacuum state then at later times it would be found in a coherent state if perturbed by an external (ccc-number) electromagnetic field.
A quantum-theoretic treatment of Lippmann fringes is given using the response-function formalism of part I of this series of papers. It is shown that the field emitted by the excited atom in the presence of a dielectric mirror possesses first-order coherence, and the absorption of such a field by the unexcited atom leads to the interference fringes. The nature of the emitted field is also examined from the point of view of excitation of surface modes. The causal character of the absorption process is also briefly commented upon.
We consider the spontaneous emission in an absorbing medium by calculating the quantum flow of energy from an emitting atom. For this purpose, we extend the analysis by Power and Thirunamachandran of quantized Maxwell fields in the vicinity of an atom in the free space to a situation where the emitter is in a dielectric medium. We represent the quantum flow in terms of the non-equal time commutators involving electric and magnetic fields, as well as the local displacement field. The commutators are calculated applying a previously developed microscopic theory of quantization of radiation in dielectrics. Consequently, we derive from first principles the rate of spontaneous emission in an absorbing medium containing local field factors and other refractive contributions. The results support the previous introduction of the (virtual cavity) local field correction by Barnett et al on a phenomenological basis, as well as our previous approach in which the spontaneous emission is considered as a resonance energy transfer to the far-zone atoms. A distinctive feature of the present formalism is that it deals with the spontaneous emission directly by calculating the quantum flow from the emitting atom. Therefore, the method is free from divergences appearing in other approaches analysing the spontaneous decay in absorbing media.
Abstract Analytic expressions of a previous paper, for the width of the excited state of an atom in presence of a dielectric interface are integrated numerically for two different types of material medium viz. a metal and the one involving phonorus such as GaP. In each case there is a very large transition probability that the atom decays with the emission of an appropriate surface polariton. It is also found that the diffuse contribution to the width closely related to the irradiated power is much smaller than the surface polariton contribution. The influence of the damping of the dielectric function on the width of the atomic states as well as the surface plasmon‐polariton contribution to frequency shifts for a metal are studied.