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Physical Review Letters

Equation of State of an Interacting Bose Gas Confined by a Harmonic Trap: The Role of the “Harmonic” Pressure

Vı́ctor Romero-Rochı́n

Published Apr 6, 2005• 68 citations
Publisher

Abstract

A gas of interacting atoms confined by a three dimensional anisotropic harmonic potential is studied. It is shown that there appear "new" thermodynamic variables instead of the usual pressure and volume: the latter is replaced by (the inverse of) the cube of the geometric average of the oscillator frequencies of the trap, and the former by the harmonic pressure responsible for the mechanical equilibrium of the fluid in the trap. We discuss the origin and physical meaning of these quantities and show that the equation of state of the gas is given in terms of these variables. The equation of state of a cold gas of interacting Bose atoms in the Hartree-Fock approximation is presented. We indicate how the harmonic pressure can be measured in current experiments.

DOI
10.1103/physrevlett.94.130601

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•Jan 1, 2016•0 citations
A gas of interacting atoms confined by a three dimensional anisotropic harmonic potential is studied. It is shown that there appear "new" thermodynamic variables instead of the usual pressure and volume: the latter is replaced by (the inverse of) the cube of the geometric average of the oscillator frequencies of the trap, and the former by the harmonic pressure responsible for the mechanical equilibrium of the fluid in the trap. We discuss the origin and physical meaning of these quantities and show that the equation of state of the gas is given in terms of these variables. The equation of state of a cold gas of interacting Bose atoms in the Hartree-Fock approximation is presented. We indicate how the harmonic pressure can be measured in current experiments.
We present theoretical aspects concerning the thermodynamics of an ideal bosonic gas trapped by a harmonic potential. Working in the Grand Canonical ensemble we are able to properly identify the extensive thermodynamic variable equivalent to the volume and the intensive thermodynamic variable equivalent to the pressure. These are called the "harmonic volume" and the "harmonic pressure" and their physical meaning is discussed. With these variables, the problem of Bose-Einstein condensation is studied in terms of the behavior of the corresponding equation of state and in terms of measurable susceptibilities such as the heat capacities, the isothermal compressibility and the coefficient of thermal expansion. From the analysis, an interesting analogy with Black-Body radiation emerges, showing that at and below the critical temperature, the non-condensate fraction of atoms behaves thermodynamically like a gas of massless particles.
We study a fluid of interacting atoms confined by a three-dimensional anisotropic harmonic potential, similar to those produced by the magnetic traps used to confine cold atoms. We show that instead of the usual thermodynamic variables pressure and volume, no longer existing in this case, there appear "new" variables: the volume is replaced by (the inverse cube of) the geometric average of the oscillator frequencies of the trap, and the hydrostatic pressure is replaced by an intensive variable, conjugate to the previous one, and responsible for the mechanical equilibrium of the fluid in the trap. We discuss the origin and physical meaning of these new variables. With the aid of molecular dynamics simulations we show the emergence of novel liquid, vapor and solid-like phases in a classical fluid. In particular, we calculate the liquid-vapor-like coexistence curve and show evidence for the appearance of a critical point. These phase transitions should be observable in fluids of not-so-cold alkaline atoms.
Abstract The critical properties of the phase transition from a normal gas to a Bose–Einstein condensate (superfluid) of a harmonically confined Bose gas are addressed with the knowledge of an equation of state of the underlying homogeneous Bose fluid. It is shown that while the presence of the confinement trap arrests the usual divergences of the isothermal compressibility and heat capacities, the critical behavior manifests itself now in the divergence of derivatives of the mentioned susceptibilities. This result is illustrated with a mean-field like model of an equation of state for the homogeneous particle density as a function of the chemical potential and temperature of the gas. The model assumes the form of an ideal Bose gas in the normal fluid while in the superfluid state a function is proposed such that, both, asymptotically reaches the Thomas–Fermi solution of a weakly interacting Bose gas at large densities and low temperatures and, at the transition, matches the critical properties of the ideal Bose gas. With this model we obtain the global thermodynamics of the harmonically confined gas, from which we analyze its critical properties. We discuss how these properties can be experimentally tested.
Abstract By using the one-dimensional canonical partition function, we modelled an ideal gas-like form of a set of Bose-Einstein condensates confined by a three-dimensional anisotropic parabolic trap. The model itself was constructed by taking the eigenenergies of the one-dimensional Gross-Pitaevskii equation in the longitudinal direction and enabling the harmonic volume as the inverse cube of average geometric trapping frequency to substitute the real volume. In this paper, we showed that the condensates form an ideal gas represented by its equation of state and have similar mature to Einstein’s solid-like model with the corrections in both the low and high temperatures in the internal energy formulations.
We present the full thermodynamics of an interacting fluid confined by an arbitrary external potential. We show that for each confining potential, there emerge "generalized" volume and pressure variables V and P , that replace the usual volume and hydrostatic pressure of a uniform system. This scheme is validated with the derivation of the virial expansion of the grand potential. We discuss how this approach yields experimentally amenable procedures to find the equation of state of the fluid, P=P(VN,T) with N the number of atoms, as well as its heat capacity at constant generalized volume C_{V}=C_{V}(V,N,T) . With these two functions, all the thermodynamics properties of the system may be found. As specific examples we study weakly interacting Bose gases trapped by harmonic and by linear quadrupolar potentials within the Hartree-Fock approximation. We claim that this route provides an additional and useful tool to analyze both the thermodynamic variables of an ultracold trapped gas as well as its elementary excitations.
Abstract This chapter describes the main properties of the ideal Bose gas confined by a harmonic potential. It calculates the temperature dependence of the condensate density and identify the value of the critical temperature in terms of the oscillator frequency and the number of atoms. This identification provides an important temperature scale for experiments with ultracold atomic gases. The chapter also discusses the behaviour of the expanding cloud after the release of the trap and how the anisotropy of the gas evolves in time, reflecting the initial anisotropy of the momentum distribution. It finally discusses the possibility of getting Bose–Einstein condensation through adiabatic transformations, working with non-harmonic trapping potentials or with mixtures of two atomic species trapped by different harmonic potentials.