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Journal of Experimental and Theoretical Physics

Nonexponential decay of spin polarization in rubidium vapor

T. L. Andreeva, P. L. Rubin, В. Н. Сорокин

Published Jun 1, 2002• 0 citations
Publisher

Abstract

Experimental data on the decay of spin polarization in rubidium vapor are compared with inferences of the theory developed by the authors for spin-polarized Boltzmann gases. It is demonstrated that the nonexponential pattern of polarization decay points to the anisotropy of the indicatrix of inelastic scattering of rubidium atoms at high temperatures. Estimates are obtained of the degree of anisotropy of such inelastic scattering, i.e., scattering with variation of total spin. Under the experimental conditions, the indicatrix of inelastic scattering turns out to be highly extended forward, with the degree of anisotropy of the order of 1000.

DOI
10.1134/1.1493159

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Experimental data on the decay of spin polarization in rubidium vapor are compared with inferences of the theory developed by the authors for spin-polarized Boltzmann gases. It is demonstrated that the nonexponential pattern of polarization decay points to the anisotropy of the indicatrix of inelastic scattering of rubidium atoms at high temperatures. Estimates are obtained of the degree of anisotropy of such inelastic scattering, i.e., scattering with variation of total spin. Under the experimental conditions, the indicatrix of inelastic scattering turns out to be highly extended forward, with the degree of anisotropy of the order of 1000.
An equation is derived for the dynamics of the spin magnetic moment in a polarized Boltzmann gas allowing for spin loss processes. The general form of the T matrix for collisions between two spin 1/2 particles allowing for inelastic processes is used. It is shown that the rate of spin loss depends on the degree of polarization of the gas. As a result, the damping of deviations of the magnetic moment from the average becomes anisotropic where the degree of anisotropy depends on the amplitude of the zero-angle scattering of atoms.
The spin relaxation of optically pumped rubidium vapor induced by rubidium-rare-gas atomic collisions has been investigated in an ultraclean environment. The experiment was performed under conditions such that the partial pressure of nonrare-gas impurities was less than 1\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}8}$ Torr, and that the time between Rb-Rb spin exchange collisions was short compared to the spin relaxation time. The cross sections (in cm2{\mathrm{cm}}^{2}cm2) for disorientation of rubidium were found to be: He, 3.3\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}25}$; Ne, 3.3\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}24}$; Ar, 1.1\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}22}$; Kr, 7.3\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}21}$; Xe, 1.3\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}19}$. The fact that these cross sections are considerably smaller than previously reported values is attributed primarily to the low degree of impurity contamination in the present work. When compared with already existing values for cesium and sodium, the disorientation cross sections of these three alkali metals are seen to have a remarkably similar dependence on buffer-gas atomic number. The new experimental values are also compared with recent theoretical calculations.
The rates of elastic and inelastic scattering processes of spin-polarized atomic tritium are vital inputs for the design and operation of experiments using cold, magnetically trapped tritium atoms. Elastic scattering dominates the total cross section and dictates the thermophysical properties of the vapor, determining the efficiency of magnetic evaporative cooling and the fluid dynamical properties of the trapped atom cloud. Spin-changing cross sections in both exchange and dipolar channels determine the trap lifetime of the various hyperfine states, imposing constraints on the required atomic tritium supply rate to maintain a given trap density. Motivated by the needs of next-generation spectrometers that will study the tritium beta end point to infer the mass of the neutrino, we present new calculations of the elastic, spin-exchange, and dipolar cross sections for spin-polarized atomic tritium. Cross sections and rate constants are reported for magnetic field strengths of 0--10 T and temperatures from 0 to 100 K in all relevant Zeeman-hyperfine channels for both tritium and hydrogen. Results are benchmarked against past calculations for atomic hydrogen and the limited available results for tritium, and extend far into the regimes where past calculations have not been available.
A new optical method for studying the spin relaxation of optically aligned rubidium vapor is described. In this method, the pumping radiation, consisting of circularly polarized D1{D}_{1}D1​ resonance radiation, is suddenly shut off and then turned on again after a known time interval. The relaxation which takes place during the interval of darkness causes the vapor to become more opaque to the pumping radiation at a rate which is determined by the relaxation time. A large degree of alignment, as well as a relaxation time of about 80 milliseconds, were observed in a closed-off evacuated cylindrical glass cell completely lined, except for 1200\frac{1}{200}2001​ of the wall area, with a thin film of tetracontane (C40{\mathrm{C}}_{40}C40​H82{\mathrm{H}}_{82}H82​). The variation of relaxation time with buffer gas pressure was studied in this cell and in an unlined glass cell. From the observations with the unlined cell, diffusion coefficients for rubidium in neon and argon of 0.31 cm2{\mathrm{cm}}^{2}cm2/sec and 0.24 cm2{\mathrm{cm}}^{2}cm2/sec, respectively, can be deduced. Observed cross sections for disorientation collisions between aligned ground-state rubidium atoms and neon, argon, krypton, and xenon atoms are 5.2\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}23}$ cm2{\mathrm{cm}}^{2}cm2, 3.7\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}22}$ cm2{\mathrm{cm}}^{2}cm2, 5.9\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}21}$ cm2{\mathrm{cm}}^{2}cm2, and 1.3\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}20}$ cm2{\mathrm{cm}}^{2}cm2, respectively. In the evacuated tetracontane-lined cell, the relaxation time decreased by 30% for a tenfold increase in rubidium vapor pressure. An explanation for this relatively weak dependence is suggested. The longest observed relaxation time was approximately 0.4 seconds in a tetracontanelined cell filled with neon to a pressure of 3 cm Hg.
We derive a kinetic equation for a polarized paramagnetic gas that is exact in the Boltzmann (binary) approximation. The equation is written in a compact form and applies to both Fermi and Bose gases in a wide temperature range as long as the Boltzmann approximation remains applicable. The derived equation is used to analyze the conditions for the propagation of spin waves in polarized Fermi and Bose gases. We deduce a universal criterion for the propagation of weakly damped spin waves in a wide temperature range. The criterion is reduced to the condition that the real parts of the particle zero-angle scattering amplitudes (or T matrices) be much larger than their imaginary parts. We derive dispersion equations for spin waves at high and low gas temperatures and show that spin waves can propagate in both these limiting cases.