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Physical Review A

Universal and nonuniversal statistical properties of levels and intensities for chaotic Rydberg molecules

M. Lombardi, T. H. Seligman

Published May 1, 1993• 63 citations
Publisher

Abstract

We study Rydberg molecules taking into account the interaction between the rotational motion of the nuclei and the radial motion of the electron. This situation can be treated to a good approximation in quantum mechanics by the multichannel quantum-defect method which in turn has a well-defined classical limit. We are able to calculate very long sequences of levels and the corresponding amplitudes of wave packets. This allows us to study the statistical properties of both in detail. Our interest focuses on aspects of ``quantum chaos'' that can be particularly well understood in this case. Our main result is that, in a completely chaotic classical situation, where statistics of quantum-level spacings follow the expected universal Gaussian-orthogonal-ensemble behavior, and statistics of line intensities display the expected universal Porter-Thomas behavior, nonuniversal properties are explicitly contained in correlations between intensities and spacings, determined by the time needed for the classical system to mix on a length scale given by the quantum wavelength.

DOI
10.1103/physreva.47.3571

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We study Rydberg molecules taking into account the interaction between the rotational motion of the nuclei and the radial motion of the electron. This situation can be treated to a good approximation in quantum mechanics by the multichannel quantum-defect method which in turn has a well-defined classical limit. We are able to calculate very long sequences of levels and the corresponding amplitudes of wave packets. This allows us to study the statistical properties of both in detail. Our interest focuses on aspects of ``quantum chaos'' that can be particularly well understood in this case. Our main result is that, in a completely chaotic classical situation, where statistics of quantum-level spacings follow the expected universal Gaussian-orthogonal-ensemble behavior, and statistics of line intensities display the expected universal Porter-Thomas behavior, nonuniversal properties are explicitly contained in correlations between intensities and spacings, determined by the time needed for the classical system to mix on a length scale given by the quantum wavelength.
Random matrix theory (RMT) and semi-classical methods are both used to study the spectra of chaotic quantum systems. The former is usually applied to small distances within the spectrum residing on scales of the mean level spacing where the phenomenon of universality emerges. Through the quantum-classical correspondence provided by semi-classics this regime is, conversely, described by long time dynamical properties of the classical system. In the first half of this thesis we explore such a connection for the study of spectral properties of quantum graphs with dynamically broken time reversal invariance. In physical systems this invariance is often not fully broken and to emulate this we include a rank-1 perturbation on the quantum level resulting in a RMT model outside of the usual universality classes. As we further show, the outcome can depend on graph specific properties and the rank of the perturbation. For the second half of the thesis we consider an opposite limit: instead of long times we study short times, on which universality can not be expected, in a chain-like spin system. In these systems the number of spins takes on a similar role as time, therefore the short time behavior in long chains has remarkable similarities to long time dynamics in few-body system. For instance, the formulation of an evolution operator in spatial direction is possible. Exploring this spatial-time duality we address long range spectral statistic in many-body systems and, for the first time, resolve periodic orbits in a genuine many-body system from the traces of its quantum evolution.
For Hamiltonian systems, level statistics provide a faithful diagnostic of quantum chaos. By analogy, the statistics of the Lindbladian spectrum are often used in open quantum systems, and the Grobe-Haake-Sommers conjecture proposes that systems with chaotic classical counterparts should exhibit level repulsion in the Lindbladian spectrum. Here we point out an important flaw in this analogy: Hamiltonian and Lindbladian spectra behave differently and have distinct physical interpretations, and one should therefore not expect the latter to provide a reliable diagnostic. For Lindbladians, the late-time dynamics are not determined by the bulk of the eigenvalues but only by those eigenvalues -- and their corresponding eigenvectors -- with small real parts. Combined with the strong non-normality typical of Lindbladians, this allows situations in which the level statistics can be tuned almost arbitrarily without affecting the dynamics on either short or long time scales. We explicitly demonstrate this phenomenon and provide examples in which Ginibre level repulsion arises while the system dynamics at no time show signatures of chaos. We further relate this mechanism to the emergence of a non-Hermitian skin effect in Liouville space, linking boundary-induced eigenvector localization to the observed spectral instability. Our results show that level statistics cannot universally serve as a reliable diagnostic of quantum chaos in open quantum systems and highlight the need for alternative diagnostics that remain robust in strongly non-normal regimes.
We study the level statistics of an interacting multiqubit system, namely the kicked Ising spin chain, in the regime of quantum chaos. Long range quasienergy level statistics show effects analogous to the ones observed in semiclassical systems due to the presence of short classical periodic orbits, while short range level statistics display perfect statistical agreement with random matrix theory. Even though our system possesses no classical limit, our results suggest existence of an important nonuniversal system specific behavior at short time scale, which clearly goes beyond finite size effects in random matrix theory.
Understanding the emergence of chaos in many-body quantum systems away from semi-classical limits, particularly in spatially local interacting spin Hamiltonians, has been a long-standing problem. In these intrinsically quantum regimes, quantum chaos has been primarily understood through the correspondence between the eigensystem statistics of midspectrum eigenstates and the universal statistics described by random matrix theory (RMT). However, this correspondence no longer holds for finite-temperature eigenstates. Here we show that the statistical properties of finite-temperature eigenstates of quantum chaotic Hamiltonians can be accurately described by pure random states constrained by a local charge, with the average charge density of the constrained random state ensemble playing the same role as the average energy density of the eigenstates. By properly normalizing the energy density using a single Hamiltonian-dependent parameter that quantifies the typical energy per degree of freedom, we find excellent agreement between the entanglement entropy statistics of eigenstates and that of constrained random states. Interestingly, in small pockets of Hamiltonian parameter phase space which we previously identified as `maximally chaotic' [PRX 14, 031014 (2024)], we find excellent agreement not only at the level of the first moment, including O(1) corrections, but also at the level of statistical fluctuations. These results show that notions of maximal chaos -- in terms of how much randomness eigenstates contain -- can still be defined at finite temperature in physical Hamiltonian models away from semi-classical and large-NNN limits.
The dynamics of Rydberg states of a hydrogen atom subjected simultaneously to uniform static electric field and two microwave fields with commensurate frequencies is considered in the range of small field amplitudes. In the certain range of the parameters of the system the classical secular motion of the electronic ellipse reveals chaotic behavior. Quantum mechanically, when the fine structure of the atom is taken into account, the energy level statistics obey predictions appropriate for the symplectic Gaussian random matrix ensemble.
Motivated by the surge of interest in statistics of non-Hermitian random matrices as a framework for description of universal characteristics of dissipative chaotic quantum many-body systems, we address the problem of characterizing the parametric correlations of spectral densities. Considering parameter-dependent ensemble of complex Ginibre matrices we derive an explicit, closed-form expression for the parametric number covariance in the systems of symmetry class A\mathbf{A}A for eigenvalues in a circular domain containing on average a finite number of eigenvalues in the spectral bulk. This behavior is expected to be universal, as further supported by numerical evidence for the real Ginibre ensemble, non-Hermitian Bernoulli Wigner matrices and bi-unitarily invariant ensembles. We also discuss a relation between parametric correlations of spectral densities and the distribution of the so-called eigenvector non-orthogonality factor, which attracted considerable interest in recent years.