The difficulty near the critical point encountered by the Landau theory or the classical theory of the second order phase transition is removed with the least modification of the original framework. The essential point of our idea is to note that the temperature region in which the Landau theory valids depends sensitively on the way of defining the local order parameter. It is shown that the relations among the singularities of various thermodynamic quantities predicted by this modified form of the Landau theory are in good agreement with those obtained by nonclassical theories such as the static scaling theory.
If the zero-field transition in high-temperature superconductors such as ${\mathrm{YBa}}_{2}{\mathrm{Cu}}_{3}{\mathrm{O}}_{7\ensuremath{-}\ensuremath{\delta}}$ is a critical point in the universality class of the three-dimensional
XY model, then the general theory of critical phenomena predicts the existence of a critical region in which thermodynamic functions have a characteristic scaling form. We report an attempt to calculate the universal scaling function associated with the specific heat, for which experimental data have become available in recent years. Scaling behavior is extracted from a renormalization-group analysis, and the
1/N expansion is adopted as a means of approximation. The estimated scaling function is qualitatively similar to that observed experimentally, and also to the lowest-Landau-level scaling function used by some authors to provide an alternative interpretation of the same data. Unfortunately, the
1/N expansion is not sufficiently reliable at small values of N for a quantitative fit to be feasible.
The critical phenomenon of the second order phase transition is considered for temperatures above the critical point. A general phenomenological approach is developed. The generalized free energy F[{η q }: T ] is introduced. It is a functional of the Fourier component η q of the local order parameter η( r ). A general property of the correlation function <η q η - q > is established rigorously. The equilibrium free energy and the wave-number dependent susceptibility χ q are expressed in terms of the linked clusters, large clusters corresponding to highr order fluctuation of the order parameter. The general rule for calculating the contribution of each cluster is given. The rule is shown to be very simple. It is found that the specific heat is expressed as a sum of the temperature derivatives of χ q 's. As an example of the application of the linked cluster method, the susceptibility is calculated in the vicinity of the critical point by summing up the clusters that are most divergent when approaching the criticat point. The linked cluster expansion developed here could be a clue to the whole mystery of the singularity at the critical point.
Using the Landau Hamiltonian for the description of second-order phase transitions, we give a proof of scaling for any continuous number of dimensions below four. The proof is based on a summation of diagrams having a power-law divergence and standard renormalization-group methods. The proof is constructive in that it leads to an unambiguous calculation for the critical exponents $\ensuremath{\eta}$ and $\ensuremath{\gamma}$. We present in this paper a detailed discussion of the proof; we also compare our method with the $\ensuremath{\epsilon}$ expansion leading to an interesting aspect of that theory: We find that the contribution to the critical exponents of order $\ensuremath{\epsilon}$ can be gotten without any calculation of diagrams. In this paper we have only made a lowest-order calculation in three dimensions. To this order we are of course unable to locate the relevant fixed point, but it leads to a relation between $\ensuremath{\eta}$ and $\ensuremath{\gamma}$---also to lowest order---which is such that if $\ensuremath{\gamma}$ is fixed to be 1.25, then $\ensuremath{\eta}$ turns out to be 0.12.
Abstract In this work, we define and calculate critical exponents associated with higher order thermodynamic phase transitions. Such phase transitions can be classified into two classes: with or without a local order parameter. For phase transitions involving a local order parameter, we write down the Landau theory and calculate critical exponents using the saddle point approximation. Further, we investigate fluctuations about the saddle point and demarcate when such fluctuations dominate over saddle point calculations by introducing the generalized Ginzburg criteria. We use Wilsonian renormalization group (RG) to derive scaling forms for observables near criticality and obtain scaling relations between the critical exponents. Afterwards, we find out fixed points of the RG flow using the one-loop beta function and calculate critical exponents about the fixed points for third and fourth order phase transitions.
Using the functional-integral method applied to the BCS Hamiltonian we have calculated the partition function, off-diagonal correlation function, specific heat, and conductivity of a super-conductor in the transition region. The partition function is obtained in the form $\ensuremath{\int}D\ensuremath{\psi}{e}^{\ensuremath{-}\ensuremath{\beta}F[\ensuremath{\psi}]}$, where
F is of the Ginzburg-Landau form but with a time-dependent order parameter. An examination of the coefficient
b of the fourth-order term in
F, however, shows that
b is sharply peaked at zero frequency, thus justifying the use of a time-independent order parameter. We then apply a self-consistent mean-field approximation similar to that of Mar\ifmmode \check{c}\else \v{c}\fi{}elja to the fourth-order term. The self-consistency condition determines the mean-square fluctuation in the order parameter and a renormalized temperature shift in terms of which the nature of the phase transition (or lack of it) can be understood. We find that only in three dimensions does a phase transition strictly occur, at a slightly lowered transition temperature with critical indices $\ensuremath{\gamma}=2$, $\ensuremath{\nu}=1$. In two, one, and zero dimensions the mean-square fluctuation in the order parameter is bounded for
T>0 and the mean value of the order parameter vanishes, indicating that the transition is completely suppressed in samples of reduced dimensionality. This behavior is reflected in the off-diagonal correlation function which manifests off-diagonal long-range order only in three dimensions. The specific heat in three dimensions is found to be finite at
Tc, with critical index $\ensuremath{\alpha}=\ensuremath{-}1$. In two, one, and zero dimensions the specific-heat transition is rounded relative to the BCS result. We find an anomalous factor of 2 in the specific-heat calculation deriving from our treatment of the fourth-order term in
F. As a result we conjecture that the Hartree approximation of Mar\ifmmode \check{c}\else \v{c}\fi{}elja may be better than the Hartree-Fock approximation of Tucker and Halperin. The equations for the conductivity are identical to those of Mar\ifmmode \check{c}\else \v{c}\fi{}elja.