Using a fully coupled oscillator model for the quantum mechanical description of a harmonically bound electron in a radiation field, exact results about the dissipative properties of the system in thermal equilibrium are derived. In particular one gets, without any additional assumption, the classical equation of motion of an oscillating electron damped by radiation and the scattering cross section of the system for incident light.
Using a fully coupled oscillator model for the quantum mechanical description of a harmonically bound electron in a radiation field, exact results about the dissipative properties of the system in thermal equilibrium are derived. In particular one gets, without any additional assumption, the classical equation of motion of an oscillating electron damped by radiation and the scattering cross section of the system for incident light.
The need for a quantum-mechanical formalism for systems with dissipation which is applicable to the radiation field of a cavity is discussed. Two methods that have been used in this connection are described. The first, which starts with the classical Newtonian equation of motion for a damped oscillator and applies the conventional formal quantization techniques, leads to an exact solution; but subsequent discussion shows that this method is invalid, the results being unacceptable from a quantum-mechanical viewpoint. The second method, which considers the interaction of two systems, the lossless oscillator and the loss mechanism, is adopted in the present article. No special model is used for the loss mechanism, but this mechanism is assumed to have a large number of densely-spaced energy states.The approximations with respect to the loss mechanism that underlie the concept of dissipation are discussed. These approximations are then applied to the analysis, and a differential equation for a coordinate operator of the harmonic oscillator is obtained which has the formal appearance of the Newtonian equation of motion for a driven damped harmonic oscillator, the driving term being an operator referring to the loss mechanism. The presence of the driving term is responsible for the difference between the present theory and that of the first method mentioned above. A solution of the differential equation for the coordinate operator is given explicitly. An examination of the physical significance of the solution shows that the driving term is responsible not only for the thermal fluctuations which are due to the loss mechanism, but also for the proper commutation relationship of the conjugate coordinates of the oscillator and for its zero-point fluctuations.A generalization of the solution to provide for a classical driving force and coupled atomic systems is given. The results are then restated in a form that refers to the loss mechanism only through the two parameters by which it is usually described---the dissipation constant and the temperature.
The quantum theory of a damped harmonic oscillator is developed by considering an exactly solvable model, previously discussed by Unruh and Zurek [Phys. Rev. D 40, 1071 (1989)]. A one-dimensional harmonic oscillator is coupled to a scalar field. The field is assumed to be initially in thermal equilibrium. The Heisenberg equations of motion are solved without approximation, and the first and second moments, 〈q(t)〉, 〈p(t)〉, 〈q2(t)〉, 〈p2(t)〉, and 〈q(t)p(t)+p(t)q(t)〉 of the coordinate and momentum of the oscillator are calculated. The high-temperature, zero-temperature, free-particle, and weak-damping limits are discussed. A Wigner function of Gaussian form is constructed. The density-matrix equation derived by Louisell $[---Quantum Statistical Properties of Radiation (Wiley, New York, 1973)] is examined and shown to have a solution in agreement with our weak-damping limit.
The development of a quantum-mechanical formalism for systems with dissipation that was presented in an earlier article, and intended mainly for application to the electromagnetic field in a cavity, is extended. The problem of the harmonic oscillator with dissipation is shown to be the same as that of a harmonic oscillator coupled to a thermal reservoir, and the need of the formalism to contain the appropriate statistical mechanics is discussed. The derivation of relationships which permit the calculation of all moments of the oscillator coordinate and momentum provides the necessary extension of the theory. The formal resemblance of the completed theory to that of classical Brownian motion, some differences due to quantum mechanics, and the fact that certain fundamental relationships which are assumed in the latter are derived in the present analysis, are pointed out. The application of the theory is illustrated by the consideration of three problems: the proof of Ott's formula, and the derivation of both the probability density and energy distribution of the oscillator in equilibrium with a thermal reservoir.
A brief review of the classical and quantum description of the interaction of electromagnetic radiation with matter based on the model of a harmonic oscillator is presented. This review includes the generalized Bohr correspondence principle, the excitation of a quantum oscillator by electromagnetic pulses including saturation effect, the harmonic limit of the Bloch equations, and a phenomenological account of the damping of the quantum oscillator. In all cases, at the mathematical level, the relationship between the classical and quantum descriptions of the electromagnetic interaction is established and the conditions for such compliance are identified.
Atoms and ions containing residual bound electrons do not quite resemble the simple harmonic oscillator model used so successfully in the classical theory of radiation. However, replacing the atoms or ions with sets of harmonic oscillators of a great number of discrete resonance frequencies and having various amplitudes, together with the results of classical radiation theory, go a long way toward a quantitative description of emission or absorption spectra. The set of resonance frequencies is obtained from measured or calculated energy levels using Ritz's combination principle. The amplitudes are associated with matrix elements of appropriate quantum mechanical operators between wave functions of the two energy eigenstates involved at a given frequency. In other words, quantities of the emitters, absorbers, or scatterers are described quantum-mechanically, whereas the electromagnetic field is treated classically. Such semi-classical description of matter-electromagnetic field interactions became unnecessary very early in the development of quantum theory. It will therefore not be discussed in any detail. Instead, we will begin immediately with the combined theory of matter and radiation (Heitler 1954, Dirac 1958, Loudon 1983). Quantum theory of particles and fields There are various ways to also quantize the electromagnetic fields (Cohen-Tannoudji, DuPont-Roc and Grynberg 1989), of which that performed on the combined Hamiltonian equations of motion for the field-matter system is followed here.
The damped harmonic oscillator is a workhorse for the study of dissipation in quantum mechanics. However, despite its simplicity, this system has given rise to some approximations whose validity and relation to more refined descriptions deserve a thorough investigation. In this work, we apply a method that allows us to diagonalize exactly the dissipative Hamiltonians that are frequently adopted in the literature. Using this method, we derive the conditions of validity of the rotating-wave approximation (RWA) and show how this approximate description relates to more general ones. We also show that the existence of dissipative coherent states is intimately related to the RWA. Finally, through the evaluation of the dynamics of the damped oscillator, we notice an important property of the dissipative model that has not been properly accounted for in previous works, namely the necessity of new constraints to the application of the factorizable initial conditions.