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Physical Review A

Heating rates in collisionally opaque alkali-metal atom traps: Role of secondary collisions

Herman C. W. Beijerinck

Published Nov 15, 2000• 23 citations
Publisher

Abstract

Grazing collisions with background gas are the major cause of trap loss and trap heating in atom traps. To first order, these effects do not depend on the trap density. In collisionally opaque trapped atom clouds, however, scattered atoms with an energy E larger than the effective trap depth ${\mathcal{E}}_{\mathrm{eff}},$ which are destined to escape from the atom cloud, will have a finite probability for a secondary collision. This results in a contribution to the heating rate that depends on the column density $〈\mathrm{nl}〉$ of the trapped atoms, i.e., the product of density and characteristic size of the trap. For alkali-metal atom traps, secondary collisions are quite important due to the strong long-range interaction with like atoms. We derive a simple analytical expression for the secondary heating rate, showing a dependency proportional to $〈\mathrm{nl}〉 {\mathcal{E}}_{\mathrm{eff}}^{1/2}.$ When extrapolating to a vanishing column density, only primary collisions with the background gas will contribute to the heating rate. This contribution is rather small, due to the weak long-range interaction of the usual background gas species in an ultrahigh-vacuum system---He, Ne, or Ar---with the trapped alkali-metal atoms. We conclude that the transition between trap-loss collisions and heating collisions is determined by a cutoff energy $200 \ensuremath{\mu}\mathrm{K}<~{\mathcal{E}}_{\mathrm{eff}}<~400 \ensuremath{\mu}\mathrm{K},$ much smaller than the actual trap depth $\mathcal{E}$ in most magnetic traps. Atoms with an energy ${\mathcal{E}}_{\mathrm{eff}}<E<\mathcal{E}$ escape into the Oort cloud: a mechanism of effective traploss in the microkelvin range of trap temperatures. We present results of secondary heating rates for the alkali-metal atoms Li through Cs as a function of the effective trap depth, the column density of the trap, and the species in the background gas. The predictions of our model are in good agreement with the experimental data of Myatt for heating rates in high-density ${}^{87}\mathrm{Rb}$-atom magnetic traps at JILA, including the effect of the rf shield and the composition of the background gas. It is shown that collisions with atoms from the Oort cloud also contribute to the heating rate. For ${}^{85}\mathrm{Rb}$ the calculated heating rate is below the experimentally observed value at JILA, supporting the idea that inelastic collisions in the trap are the major source of heating.

DOI
10.1103/physreva.62.063614

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Measurements of the temperature dependence of trap loss collisions of laser-cooled rubidium atoms are presented. A significant suppression of the rate of collisions between ground- and excited-state atoms is observed for temperatures below $\\sim$70 $\\mu$K. In such inelastic collisions, the atomic excitation takes place at long range and must survive against spontaneous decay to short range. Our results are consistent with recent predictions for the low temperature suppression of these collisions due to reduced survival of atomic excitation at low collision velocities.^ We report on measurements of trap loss collisions between ultracold Rb atoms which are confined in a magneto-optical trap. Both isotopes $\\sp{85}$Rb and $\\sp{87}$Rb have been studied over wide range of trap laser intensities and detunings. The trap loss collision rates exhibit variations over 3 orders of magnitude. We observe significant differences between the isotopes. At large detunings the ability of the trap to recapture products of the hyperfine-changing collisions is significantly diminished. This finding is supported by our numerical simulations of the recapture process. The trap loss rates due to collisions with room temperature background gas have also been measured.^ Using laser light tuned to a repulsive molecular potential, we have been able to suppress inelastic ground-state hyperfine changing collisions between ultracold $\\sp{87}$Rb atoms. Adiabatic excitation to the repulsive curve alters the atomic trajectories and prevents the atoms from approaching close enough for the hyperfine change to occur. Experimental results show suppressions up to $\\sim$50% and are in reasonable agreement with a simple Landau-Zener model.^ Finally, we have observed a significant cooperative effect in ultracold trap loss collisions induced by two separate lasers. One laser, tuned close to the atomic resonance, excites the atom pair to an attractive potential at long range. The resulting acceleration and deflection give rise to an enhancement in the collisional flux of ground-state atoms reaching short range, as probed by a second laser. Enhancements up to a factor of $\\sim$3 have been observed. ^

•Jan 1, 1996•0 citations
Grazing collisions with background gas are the major cause of trap loss and trap heating in atom traps. To first order, these effects do not depend on the trap density. In collisionally opaque trapped atom clouds, however, scattered atoms with an energy E larger than the effective trap depth Eeff,{\mathcal{E}}_{\mathrm{eff}},Eeff​, which are destined to escape from the atom cloud, will have a finite probability for a secondary collision. This results in a contribution to the heating rate that depends on the column density 〈nl〉〈\mathrm{nl}〉〈nl〉 of the trapped atoms, i.e., the product of density and characteristic size of the trap. For alkali-metal atom traps, secondary collisions are quite important due to the strong long-range interaction with like atoms. We derive a simple analytical expression for the secondary heating rate, showing a dependency proportional to 〈nl〉Eeff1/2.〈\mathrm{nl}〉 {\mathcal{E}}_{\mathrm{eff}}^{1/2}.〈nl〉Eeff1/2​. When extrapolating to a vanishing column density, only primary collisions with the background gas will contribute to the heating rate. This contribution is rather small, due to the weak long-range interaction of the usual background gas species in an ultrahigh-vacuum system---He, Ne, or Ar---with the trapped alkali-metal atoms. We conclude that the transition between trap-loss collisions and heating collisions is determined by a cutoff energy 200\ensuremathμK< Eeff< 400\ensuremathμK,200 \ensuremath{\mu}\mathrm{K}<~{\mathcal{E}}_{\mathrm{eff}}<~400 \ensuremath{\mu}\mathrm{K},200\ensuremathμK< Eeff​< 400\ensuremathμK, much smaller than the actual trap depth E\mathcal{E}E in most magnetic traps. Atoms with an energy Eeff<E<E{\mathcal{E}}_{\mathrm{eff}}<E<\mathcal{E}Eeff​<E<E escape into the Oort cloud: a mechanism of effective traploss in the microkelvin range of trap temperatures. We present results of secondary heating rates for the alkali-metal atoms Li through Cs as a function of the effective trap depth, the column density of the trap, and the species in the background gas. The predictions of our model are in good agreement with the experimental data of Myatt for heating rates in high-density 87Rb{}^{87}\mathrm{Rb}87Rb-atom magnetic traps at JILA, including the effect of the rf shield and the composition of the background gas. It is shown that collisions with atoms from the Oort cloud also contribute to the heating rate. For 85Rb{}^{85}\mathrm{Rb}85Rb the calculated heating rate is below the experimentally observed value at JILA, supporting the idea that inelastic collisions in the trap are the major source of heating.
The finite depth E\mathcal{E}E of an atom trap results in an upper bound for the energy transfer in collisions with the background gas that will result in heating but not in loss of an atom. The energy transfer rate is accurately predicted as function of the well depth by applying a versatile semiempirical model function for the small-angle differential cross section, covering the full range from pure diffractive scattering to classical scattering. Simple scaling laws for the energy transfer rate are presented that can be readily applied. For the diffraction dominated regime we find an energy transfer rate proportional to (E/Eref)2(\mathcal{E}/{\mathcal{E}}_{\mathrm{ref}}{)}^{2}(E/Eref​)2 with ${\mathcal{E}}_{\mathrm{ref}}{=(k}_{B}{T}_{b} {\ensuremath{\theta}}_{0}^{2}/4),$ a system-dependent energy determined by the ambient temperature Tb{T}_{b}Tb​ and the diffraction angle ${\ensuremath{\theta}}_{0}.$ In the classical regime we find the usual result of an energy transfer rate proportional to (E/Eref)5/6.(\mathcal{E}/{\mathcal{E}}_{\mathrm{ref}}{)}^{5/6}.(E/Eref​)5/6.
This paper examines two collisional mechanisms by which cold alkali-metal atoms can escape from a neutral-atom trap, due to collison of excited- and ground-state atoms. One is fine-structure-changing collisions, by which the atoms are heated by the amount of the fine-structure splitting. The other produces hot ground-state atoms following emission of a red-shifted photon during the course of a collision. A rate expression is obtained that applies to both normal and ultracold temperatures (1 mK). This expression assumes a canonical distribution of initial states, low-intensity excitation, and a semiclassical treatment of the survival probability relative to excited-state decay during the long time of the ultracold collision, and uses fine-structure-changing probabilities found by quantum scattering calculations. The known properties of the attractive molecular states of the alkaline-metal dimers are used to identify and calculate the probabilities for the specific mechanisms. We conclude that the earlier semiclassical analysis by Dashevskaya [Opt. Spectrosk. 46, 423 (1979)] of the fine-structure-changing mechanisms for the various alkali-metal species is qualitatively correct. We present quantum-mechanical calculations of the rate coefficient for fine-structure-changing collisions between ground- and excited-state Cs atoms from 1000 K to 100 \ensuremath{\mu}K. Collision-rate coefficients for the trap-loss processes are calculated for pairs of Li, Na, K, Rb, and Cs atoms at low temperature. There is a wide variation of predicted loss rate among alkali-metal species from the fastest for K and the slowest for Li. Retardation corrections to molecular lifetimes must be taken into account to predict the correct rate coefficients for Na, K, and Rb. Good agreement is obtained with the observed trap loss rate in a Cs trap.
The collision cross sections for alkali-metal--rare-gas spin orbit mixing between the ${n}^{2}{P}_{3/2}\ensuremath{\rightarrow}{n}^{2}{P}_{1/2}$ levels trend strongly with the Massey parameter, or adiabaticity of the collisions. The strength of the interaction, as characterized by the C6{C}_{6}C6​ dispersion coefficient, is a secondary influence on the rates. An analytic expression for the probability of energy transfer in alkali-metal--rare-gas collisions is derived using time-dependent perturbation theory. The model agrees well with a broad literature survey of the observed temperature-dependent cross sections. A simple interaction potential successfully organizes the alkali-metal--rare-gas database. The rates become very large for high-lying states, as the collisions are quite sudden and the radius of the valence electron is large. In contrast, the highly adiabatic cesium 62P{6}^{2}P62P mixing rates are six to eight orders of magnitude smaller. The mixing rate for the Rb-He diode pumped alkali laser system varies from $0.20--1.53\phantom{\rule{4pt}{0ex}}\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}11}\mathrm{cm}{}^{3}/\mathrm{at}.\phantom{\rule{0.16em}{0ex}}\mathrm{s}$ for T=279−−893KT=279--893\phantom{\rule{0.222222em}{0ex}}\mathrm{K}T=279−−893K.
We derive a simple formula for the heating rate that arises from quantum-diffractive background gas collisions in atom traps. This result appears to explain the residual heating rates reported for recent experiments with a Cs vapor-loaded, far-detuned optical trap at $\ensuremath{\simeq}{10}^{\ensuremath{-}9}$ Torr [Phys. Rev. Lett. 81, 5768 (1998)]. Diffractive collisions may determine the minimum heating rates achievable in shallow all-optical or magnetic atom traps operating at low temperature and high density.
The calculated upper limit ${\mathcal{K}}_{i}^{\mathrm{pol}}<~{10}^{\ensuremath{-}14}{\mathrm{cm}}^{3}/\mathrm{s}$ of the rate constant for suppressed ionization in a gas of metastable Ne(3P2)\mathrm{Ne}{(}^{3}{\mathrm{P}}_{2})Ne(3P2​) atoms in the fully aligned ∣J=2,mJ=2〉|{J=2,m}_{J}=2〉∣J=2,mJ​=2〉 state is used as input to investigate the prospects for achieving Bose-Einstein condensation (BEC). The heating rate of the trap population by secondary collisions of the hot products of the process of ionization---i.e., ground-state atoms, ions, and dimer-ions---with cold trapped metastable atoms is discussed in terms of a semiclassical model. An important step lies in limiting the depth of the magnetic trap to a value of a few millikelvin, to limit the range of small-angle scattering that contributes to heating. Also, a tight radial confinement reduces the probability for secondary collisions. At a trap depth of 10 mK, a radial dimension of $3\ensuremath{\mu}\mathrm{m},$ and a density of $2\ifmmode\times\else\texttimes\fi{}{10}^{13}{\mathrm{cm}}^{\ensuremath{-}3}$ the heating rate is $1.4\ensuremath{\mu}\mathrm{K}/\mathrm{s},$ which should be compared to the transition temperature to BEC of $0.6\ensuremath{\mu}\mathrm{K}.$ The collisional heating is dominated by ion---metastable-atom collisions, due to their long-range charge-induced dipole interaction. Keeping the evaporative cooling switched on at T=TC{T=T}_{C}T=TC​ reduces the heating a hundredfold. Using a bright beam of laser cooled neon atoms, an initial population of > 1010>~{10}^{10}> 1010 atoms can be loaded into a magneto-optical trap in one second. Tight magnetic traps are easy to achieve for metastable neon atoms, due to their magnetic moment of $3{\ensuremath{\mu}}_{B}.$ We conclude that achieving BEC is feasible for metastable neon. This also holds for triplet metastable helium, once the loading rate of traps has been improved. Finally, the semiclassical model used for calculating the heating rate is applicable to a wide range of inelastic collisions in trapped alkali gases and/or collisions with background gas.
Measurements of the temperature dependence of trap loss collisions of laser-cooled rubidium atoms are presented. A significant suppression of the rate of collisions between ground- and excited-state atoms is observed for temperatures below $\\sim$70 mu\\mumuK. In such inelastic collisions, the atomic excitation takes place at long range and must survive against spontaneous decay to short range. Our results are consistent with recent predictions for the low temperature suppression of these collisions due to reduced survival of atomic excitation at low collision velocities.^ We report on measurements of trap loss collisions between ultracold Rb atoms which are confined in a magneto-optical trap. Both isotopes sp85\\sp{85}sp85Rb and sp87\\sp{87}sp87Rb have been studied over wide range of trap laser intensities and detunings. The trap loss collision rates exhibit variations over 3 orders of magnitude. We observe significant differences between the isotopes. At large detunings the ability of the trap to recapture products of the hyperfine-changing collisions is significantly diminished. This finding is supported by our numerical simulations of the recapture process. The trap loss rates due to collisions with room temperature background gas have also been measured.^ Using laser light tuned to a repulsive molecular potential, we have been able to suppress inelastic ground-state hyperfine changing collisions between ultracold sp87\\sp{87}sp87Rb atoms. Adiabatic excitation to the repulsive curve alters the atomic trajectories and prevents the atoms from approaching close enough for the hyperfine change to occur. Experimental results show suppressions up to $\\sim$50% and are in reasonable agreement with a simple Landau-Zener model.^ Finally, we have observed a significant cooperative effect in ultracold trap loss collisions induced by two separate lasers. One laser, tuned close to the atomic resonance, excites the atom pair to an attractive potential at long range. The resulting acceleration and deflection give rise to an enhancement in the collisional flux of ground-state atoms reaching short range, as probed by a second laser. Enhancements up to a factor of $\\sim$3 have been observed. ^