Chaos in Classical and Quantum Mechanics

Giulio Casati

Ilya Prigogine, Tomio Petrosky

Giulio Casati

James T. Cushing

The ubiquity of chaos in classical mechanics (CM), as opposed to the situation in standard quantum mechanics (QM), might be taken as speaking against QM being the fundamental theory of physical phenomena. Bohmian mechanics (BM), as a formulation of quantum theory, may clarify both the existence of chaos in the quantum domain and the nature of the classical limit. Two interesting possibilities are (i) that CM and classical chaos are included in and underwritten by quantum mechanics (BM) or (ii) that BM and CM simply possess a common region of (noninclusive) overlap. In the latter case, neither CM nor QM alone would be sufficient, even in principle, to account for all of the physical phenomena we encounter. In this talk I shall summarize and discuss the implications of some recent work on chaos and on the classical limit within the framework of BM.

Vladimir V. Egorov

Quantum–classical mechanics and the Franck–Condon principle related to quantum mechanics are discussed as two alternative theoretical approaches to molecular optical spectroscopy. The statement of the problem is connected with the singularity of quantum mechanics in describing the joint motion of electrons and nuclei in the transient state of “quantum” transitions. This singularity can be eliminated by introducing chaos into the transient state. Quantum mechanics itself, supplemented by chaos (dozy chaos), is called quantum–classical mechanics. Using the simplest example of quantum transitions, it is shown that the results of quantum–classical mechanics in the case of strong dozy chaos correspond to the physical picture based on quantum mechanics and the Franck–Condon principle. The same chaos can be strong for small molecules in standard molecular spectroscopy and simultaneously weak in the photochemistry and nanophotonics of large molecules, where quantum mechanics no longer works. To describe the chaotic dynamics of the transient state, it is necessary to apply quantum–classical mechanics. Thus, the erroneous Franck–Condon physical picture of molecular “quantum” transitions is workable from a practical point of view as long as we are dealing with sufficiently small molecules, just as the erroneous geocentric picture of the world was workable until we went out into outer space.

Robert C. Bishop