Control of molecular systems with very few phases

D. Blume

Few-body physics has played a prominent role in atomic, molecular and nuclear physics since the early days of quantum mechanics. It is now possible-thanks to tremendous progress in cooling, trapping and manipulating ultracold samples-to experimentally study few-body phenomena in trapped atomic and molecular systems with unprecedented control. This review summarizes recent studies of few-body phenomena in trapped atomic and molecular gases, with an emphasis on small trapped systems. We start by introducing the free-space scattering properties and then investigate what happens when two particles, bosons or fermions, are placed in an external confinement. Next, various three-body systems are treated analytically in limiting cases. Our current understanding of larger two-component Fermi systems and Bose systems is reviewed, and connections with the corresponding bulk systems are established. Lastly, future prospects and challenges are discussed. Throughout this review, commonalities with other systems such as nuclei or quantum dots are highlighted.

Fabien Gatti, Benjamin Lasorne, Hans‐Dieter Meyer +1 more

Wenxiang Hu, Bing Gu, Ignacio Franco

Controlling electronic decoherence in molecules is an outstanding challenge in chemistry. Recent advances in the theory of electronic decoherence [B. Gu and I. Franco, J. Phys. Chem. Lett. 9, 773 (2018)] have demonstrated that it is possible to manipulate the rate of electronic coherence loss via control of the relative phase in the initial electronic superposition state. This control emerges when there are both relaxation and pure-dephasing channels for decoherence and applies to initially separable electron-nuclear states. In this paper, we demonstrate that (1) such an initial superposition state and the subsequent quantum control of electronic decoherence can be created via weak-field one-photon photoexcitation with few-cycle laser pulses of definite carrier envelope phase (CEP), provided the system is initially prepared in a separable electron-nuclear state. However, we also demonstrate that (2) when stationary molecular states (which are generally not separable) are considered, such one-photon laser control disappears. Remarkably, this happens even in situations in which the initially factorizable state is an excellent approximation to the stationary state with fidelity above 98.5%. The laser control that emerges for initially separable states is shown to arise because these states are superpositions of molecular eigenstates that open up CEP-controllable interference routes at the one-photon limit. Using these insights, we demonstrate that (3) the laser control of electronic decoherence from stationary states can be recovered by using a two-pulse control scheme, with the first pulse creating a vibronic superposition state and the second one inducing interference. This contribution advances a viable scheme for the laser control of electronic decoherence and exposes a surprising artifact that is introduced by widely used initially factorizable system-bath states in the field of open quantum systems.

Paul W. Brumer, Moshe Shapiro

Ron R. Nissim, Ana Pejkic, Evgeny Myslivets +3 more

Fast control of a strong optical beam by a few photons is an outstanding challenge that limits the performance of quantum sensors and optical processing devices. We report that a fast and efficient optical gate can be realized in an optical fiber that has been engineered with molecular-scale accuracy. Highly efficient, distributed phase-matched photon-photon interaction was achieved in the fiber with locally controlled, nanometer-scale core variations. A three-photon input was used to manipulate a Watt-scale beam at a speed exceeding 500 gigahertz. In addition to very fast beam control, the results provide a path to developing a new class of sensitive receivers capable of operating at very high rates.