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American Journal of Physics

Fermi’s golden rule and Bardeen’s tunneling theory

Hannu Reittu

Published Oct 1, 1995• 33 citations
Publisher

Abstract

A simple way to derive Bardeen’s tunneling theory is introduced. With a low rate of tunneling of, for example, electrons from one electrode to another through a wide vacuum gap, the appearance of the second electrode can be regarded as a perturbation. Then Bardeen’s formula for tunneling follows exactly from Fermi’s golden rule, supposing that this perturbation appears suddenly at some instant of time. Bardeen’s theory is illustrated by assuming a smoothly variable barrier shape, including the rectangular one as a limiting case. This exactly solvable example clarifies the sensitivity of the tunneling probability to the barrier shape and the energy of the tunneling particle.

DOI
10.1119/1.18037

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A simple way to derive Bardeen’s tunneling theory is introduced. With a low rate of tunneling of, for example, electrons from one electrode to another through a wide vacuum gap, the appearance of the second electrode can be regarded as a perturbation. Then Bardeen’s formula for tunneling follows exactly from Fermi’s golden rule, supposing that this perturbation appears suddenly at some instant of time. Bardeen’s theory is illustrated by assuming a smoothly variable barrier shape, including the rectangular one as a limiting case. This exactly solvable example clarifies the sensitivity of the tunneling probability to the barrier shape and the energy of the tunneling particle.
A novel and readily understandable derivation of the Golden Rule of time dependent perturbation theory is presented. The derivation is based on adiabatic turning on of the perturbation as used, for instance, in some formal developments of scattering theory. Energy conservation is expressed in terms of an intuitively and physically appealing Lorentzian line shape rather than the artificial, oscillatory sin(x)=x type line shape that appears in conventional derivations. The conditions for the derivation's validity are compactly and conveniently expressed in the frequency/energy domain rather than in the usual time domain. The derivation also highlights how, along with energy conservation, the transition rate faithfully and instantaneously follows the variations in the square of the perturbing potential as one may expect in the adiabatic limit. In the first instance, the adiabatic turning on is achieved, as usual, by a single exponential time variation. But we demonstrate that the instantaneous following of the square of the perturbing potential by the transition rate is more general and that one can derive the Golden Rule for a general slowly varying time dependent perturbation. This allows one to derive generalisations of the simple decay law, originally derived in the classic paper by Weisskopf and Wigner; a tutorial exposition of the essence of this classic work is provided. The Oppenheimer method for applying the Golden rule to problems, such as the electric field ionisation of atoms, in which the perturbing potential can also create the final states, is reviewed. No use of an energy gap condition is needed to derive our results on adiabatic behaviour in contrast to the origianl derivations of the adiabatic theorem in quantum mechanics.
In scanning tunneling microscopy (STM), the potential barriers are often close to or lower than the Fermi level, where both semiclassical tunneling theory and Bardeen’s tunneling theory are no longer valid. We present a new perturbation approach for general quantum transmission phenomena. For thick, positive potential barriers, it reduces to Bardeen’s tunneling theory. For potential barriers lower than the energy level, it is valid as long as the barrier thickness is smaller than one half of the de Broglie wavelength, a condition which is always satisfied in STM. An immediate application is shown.
Abstract Fermi’s golden rule is of great importance in quantum dynamics. However, in many textbooks on quantum mechanics, its contents and limitations are obscured by the approximations and arguments in the derivation, which are inevitable because of the generic setting considered. Here we propose to introduce it by an ideal model, in which the quasi-continuum band consists of equaldistant levels extending from − ∞ to + ∞ , and each of them couples to the discrete level with the same strength. For this model, the transition probability in the first order perturbation approximation can be calculated analytically by invoking the Poisson summation formula. It turns out to be a piecewise linear function of time, demonstrating on the one hand the key features of Fermi’s golden rule, and on the other hand that the rule breaks down beyond the Heisenberg time , even when the first order perturbation approximation itself is still valid.
A Brief History of Quantum Tunneling Some Basic Questions Concerning Quantum Tunneling Simple Solvable Problems Time-Dependence of the Wave Function in One-Dimensional Tunneling Semiclassical Approximations Generalization of the Bohr - Sommerfeld Quantization Rule and its Application to Quantum Tunneling Gamow's Theory, Complex Eigenvalues, and the Wave Function of a Decaying State Tunneling in Symmetric and Asymmetric Local Potentials and Tunneling in Nonlocal and Quasi-Solvable Barriers Classical Descriptions of Tunneling Tunneling in Time-Dependent Barriers Decay Width and Scattering Theory The Method of Variable Reflection Amplitude Applied to Solve Multichannel Tunneling Problems Path Integral and Its Semi-Classical Approximation in Quantum Tunneling Heisenberg's Equations of Motion for Tunneling Wigner Distribution Function in Quantum Tunneling Decay Widths of Siegert States, Complex Scaling and Dilatation Transformation Multidimensional Quantum Tunneling Group and Signal Velocities Time-Delay, Reflection Time Operator and Minimum Tunneling Time More about Tunneling Time Tunneling of a System with Internal Degrees of Freedom Motion of a Particle in a Waveguide with Variable Cross Section and in a Space Bounded by a Dumbbell-Shaped Object Relativistic Formulation of Quantum Tunneling Inverse Problems of Quantum Tunneling Some Examples of Quantum Tunneling in Atomic and Molecular Physics Some Examples from Condensed Matter Physics Alpha Decay.