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Physical Review

Angular Symmetry of the 2 - Matrix

Claude Garrod

Published Aug 5, 1968• 7 citations
Publisher

Abstract

For a system of $N$ spinless particles in a state of definite angular momentum $L$ with definite $z$ component $M$, the rotational symmetry properties of the two-particle density matrix are obtained in a completely explicit fashion. Also studied is the 2-matrix associated with an equally weighted (unpolarized) ensemble of the various $M$ states for a given $L$.

DOI
10.1103/physrev.172.173

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For a system of NNN spinless particles in a state of definite angular momentum LLL with definite zzz component MMM, the rotational symmetry properties of the two-particle density matrix are obtained in a completely explicit fashion. Also studied is the 2-matrix associated with an equally weighted (unpolarized) ensemble of the various MMM states for a given LLL.
Spin-s systems Angular momentum is one of the fundamental quantities of Newtonian physics, and in quantum physics its importance is at least as great. In quantum mechanics we often distinguish between two types of angular momentum: orbital angular momentum , which a system of particles possesses due to particle motion through space; and spin angular momentum , which is an intrinsic property of a particle. The distinction will be important later, but for now we will ignore it. We will here refer to angular momentum of any sort as “spin” and develop general-purpose mathematical tools for its description. We have already dealt with spin systems, particularly the example of a spin-½ particle. Our approach began with the empirical observation that a measurement of any spin component of a spin-½ particle could yield only the results +ħ/2 or −ħ/2. We introduced the basis states | z ±〉 for the two-dimensional Hilbert space ℋ. We also gave other basis states such as {| x ±〉} and {| y ±〉} in terms of the | z ±〉 states. From basis states and measurement values we constructed operators for the spin components S x , S y , and S z . With the operators in hand, we could then examine the algebraic relations between them (such as the commutation relation in Exercise 3.56). Our job here is to generalize our analysis to systems of arbitrary spin. To do this, we will reverse our chain of logic.
The global rotational degrees of freedom in the Schr\"odinger equation for an N-body system are completely separated from the internal ones. After removing the motion of the center of mass, we find a complete set of (2l+1)(2\mathcal{l}+1)(2l+1) independent base functions with angular momentum l.\mathcal{l}.l. These are homogeneous polynomials in the components of the coordinate vectors and the solutions of the Laplace equation, where the Euler angles do not appear explicitly. Any function with given angular momentum and given parity in the system can be expanded with respect to the base functions, where the coefficients are the functions of the internal variables. With the right choice of the base functions and the internal variables, we explicitly establish the equations for those functions. Only $(3N\ensuremath{-}6)$ internal variables are involved both in the functions and in the equations. The permutation symmetry of the wave functions for identical particles is discussed.
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Formulas are obtained which give the matrix representation, relative to a product basis, of the projection operator for the total angular momentum of a system. If the individual angular momenta are not too large, the matrix elements depend upon a small number of parameters, independent of the number of angular momenta coupled. Recurrence relations between elements and symmetry properties of elements are derived. These results enable one to perform the vector coupling of a large number of angular momenta in a relatively simple fashion. The connection between the matrix elements and vector coupling coefficients is discussed. Several important special cases are treated in detail.
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