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Physical Review Letters

Superfluidity in a Dilute Bose Gas

Benjamin Colburn Crooker, Bernard HÉBRAL, E. N. Smith, Y. Takano, J. D. Reppy

Published Aug 22, 1983• 162 citations
Publisher

Abstract

Superfluid $^{4}\mathrm{He}$ films adsorbed on porous Vycor glass have been studied in the low-density limit where the superfluid interparticle spacing is more than an order of magnitude greater than the atomic hard-core diameter. For the lowest transition temperatures observed, the influence of critical fluctuations near ${T}_{c}$ is much reduced and a range of crossover to behavior more characteristic of the dilute Bose gas is observed.

DOI
10.1103/physrevlett.51.666

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Superfluid 4He^{4}\mathrm{He}4He films adsorbed on porous Vycor glass have been studied in the low-density limit where the superfluid interparticle spacing is more than an order of magnitude greater than the atomic hard-core diameter. For the lowest transition temperatures observed, the influence of critical fluctuations near Tc{T}_{c}Tc​ is much reduced and a range of crossover to behavior more characteristic of the dilute Bose gas is observed.
There is a growing interest in the relation between Bose-Einstein condensation (BEC) and the superfluidity. A Bose system confined in random media such as porous glass is suitable for studying this relation because BEC and superfluidity can be suppressed and controlled in such a disordered environment. However, it is not clear how this relation is affected by disorder and there are few theoretical studies that can be quantitatively tested by experiment. In this work we develop a dilute Bose gas model with a random potential that takes into account the pore-size dependence of porous glass. Then we compare our model with the measured low-temperature specific heat, condensate density, and superfluid density of 4He{}^{4}\mathrm{He}4He in Vycor glass. This comparison uses no free parameters. We predict phenomena at low temperatures: First, the random potential causes a T-linear specific heat instead of the T3{T}^{3}T3 dependence that is usually caused by phonons. Second, the BEC can remain even when the superfluidity disappears at low densities. Third, the system makes a reentrant transition at low densities; that is, the superfluid phase changes to the normal phase again as the temperature is reduced. This reentrant transition is more likely to be observed when the strength of the random potential is increased.
The crossover from ideal-Bose-gas behavior to nonclassical, XY-like criticality in a dilute, interacting Bose fluid is considered in detail with emphasis on the superfluid density, ${\ensuremath{\rho}}_{s}$(T), below the transition. A general discussion of crossover scaling in constrained systems shows that ${\ensuremath{\rho}}_{s}$ and other temperature-dependent thermodynamic functions at controlled overall density can be expressed in terms of universal scaling functions. The finite-temperature Green's function formalism is used to calculate the associated linear scaling fields and the crossover exponent exactly for all dimensionalities d>2, scaling predictions, including logarithmic singularities just at d=3, being checked via second-order computations. A mapping of the Bose problem onto the classical s4{s}^{4}s4 spin model is achieved which is asymptotically exact in the critical region. In this way, previously known renormalization-group results are used to calculate the scaling functions for ${\ensuremath{\rho}}_{s}$, for the off-diagonal susceptibility, etc., to first order in \ensuremath{\epsilon}=4-d. Good agreement is found with the experimental measurements by Reppy and co-workers of ${\ensuremath{\rho}}_{s}$(T) for helium absorbed at low coverages in Vycor glass (of pore size 50--80 A\r{}). An effective-mass ratio m∗{m}^{\mathrm{*}}m∗/m\ensuremath{\simeq}1.5, and an effective-scattering-length ratio a∗{a}^{\mathrm{*}}a∗/a\ensuremath{\simeq}1.3 are indicated for mobile helium in the Vycor (although the irregular character of Vycor has not, at this point, been fully allowed for in the theory). Other approaches in the literature to computing the critical behavior of quantum-mechanical systems are reviewed and related to the present analysis.
The behavior of a dilute Bose superfluid at low temperatures, $T<<{T}_{\ensuremath{\lambda}}$, is considered with emphasis on the superfluid density, ${\ensuremath{\rho}}_{s}(T)$. Many of the predictions of the Bogoliubov model are exact in this regime and are shown to lead to a scaling description of the crossover from ideal to interacting Bose gas behavior as the density is reduced. Combined with previous work on scaling near criticality, $T\ensuremath{\simeq}{T}_{\ensuremath{\lambda}}$, these results complete the crossover description of the dilute superfluid over the full temperature range. Diagrammatic perturbation theory in the superfluid phase is outlined and previous results from the helium literature are summarized. The various divergences encountered have previously been shown to arise from nonanalyticities in the self-energy functions at zero momentum, and these are related to the spin-wave nature of the superfluid phase. A full renormalization-group fixed-point picture is presented summarizing the zero-temperature and finite-temperature regimes and the flows connecting them.
A concise and somewhat personal review of the problem of superfluidity and quantum criticality in regular and disordered interacting Bose systems is given, concentrating on general features and important symmetries that are exhibited in different parts of the phase diagram, and that govern the different possible types of critical behavior. A number of exact results for various insulating phase boundaries, which may be used to constrain the results of numerical simulations, can be derived using large rare region type arguments. The nature of the insulator-superfluid transition is explored through general scaling arguments, exact model calculations in one dimension, numerical results in two dimensions, and approximate renormalization group results in higher dimensions. Experiments on 4 He adsorbed in porous Vycor glass, on thin film superconductors, and magnetically trapped atomic vapors in a periodic optical potential are used to illustrate many of the concepts.
We review generally accepted definitions of Bose–Einstein condensation and superfluidity, emphasizing that they are independent concepts. These ideas are illustrated in a dilute hard-sphere Bose gas, which is relevant to experiments on excitons and spin-aligned atomic hydrogen. We then discuss superfluid He in porous media, as simulated by different models in different regimes. At low coverage, we model it by a dilute hard-sphere Bose gas in random potentials, and show that superfluidity is destroyed through the pinning of the Bose condensate by the external potentials. At full coverage, we model the random medium by an ohmic network of random resistors, and argue that the superfluid transition is a percolation transition in d = 3, with critical exponent 1.7. This book is devoted to the phenomenon of Bose–Einstein condensation [1, 2] and inevitably, its relevance to superfluidity [3]. To provide some background for other articles in this volume, I would like to summarize some commonly accepted views on these phenomena, and illustrate them in the context of a dilute hard-sphere Bose gas, a model in which we have some control over the approximations made. I will also describe some recent work on the effect of randomness on the Bose condensate, which shows that Bose–Einstein condensation does not automatically give rise to superfluidity.
The weakly interacting Bose gas in two dimensions is considered in the dilute limit n1/2{n}^{1/2}n1/2a\ensuremath{\ll}1, where n is the particle density and a is the range of the potential. The standard many-body perturbation theory for this system has two separate divergences: the first, associated with classical phase fluctuations, is responsible for the vanishing of the long-range order; the second is quantum mechanical and is connected with the vanishing of the scattering t matrix at long wavelengths and low energies. An earlier diagrammatic theory of Popov, which provides a consistent description of the system in the dilute limit, is rederived heuristically from a quasiparticle picture, and also using the renormalization group. It is shown that the superfluid transition temperature is Tc{T}_{c}Tc​\ensuremath{\approxeq}4\ensuremath{\pi}(${\ensuremath{\Elzxh}}^{2}$/2m)n/[ln ln(1/na2{\mathrm{na}}^{2}na2)], and the condition of validity of the dilute limit is ln ln(1/na2{\mathrm{na}}^{2}na2)\ensuremath{\gg}1. The connection to the dilute Bose gas in dimensions d>2 and the universal behavior beyond the extreme asymptotic low-density domain are also discussed.