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Physical Chemistry Chemical Physics

Homogeneous Bose gas of dipolar molecules in the mean field approximation

Robert E. Zillich, K. Birgitta Whaley

Published Jan 1, 2011• 3 citations
Publisher

Abstract

We present a mean field analysis of the effects of molecular rotation on the excitation spectrum and stability of ultracold dipolar gases. For an unpolarized homogeneous gas interacting with a pure dipole-dipole interaction, we find that for the rotational state L = 1 the dipole-dipole interaction causes a splitting of the translation-rotation energy levels into a single M = 0 and a doubly degenerate M = ±1 excitation. For all other rotational states, the dipole-dipole interaction does not lead to coupling of translations and rotations and therefore has no effect on the rotational degeneracy of the excitations. The addition of arbitrarily small electric fields is found to introduce instabilities similar to those known to arise in the fully polarized dipolar gas. As in the case of a fully polarized gas, addition of a large enough short range repulsive potential is seen to stabilize the system, with the critical value of the repulsive interaction required for stabilization being larger when rotations are included.

DOI
10.1039/c1cp21331h

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We present a mean field analysis of the effects of molecular rotation on the excitation spectrum and stability of ultracold dipolar gases. For an unpolarized homogeneous gas interacting with a pure dipole-dipole interaction, we find that for the rotational state L = 1 the dipole-dipole interaction causes a splitting of the translation-rotation energy levels into a single M = 0 and a doubly degenerate M = ±1 excitation. For all other rotational states, the dipole-dipole interaction does not lead to coupling of translations and rotations and therefore has no effect on the rotational degeneracy of the excitations. The addition of arbitrarily small electric fields is found to introduce instabilities similar to those known to arise in the fully polarized dipolar gas. As in the case of a fully polarized gas, addition of a large enough short range repulsive potential is seen to stabilize the system, with the critical value of the repulsive interaction required for stabilization being larger when rotations are included.
Trapped degenerate dipolar Bose and Fermi gases of the cylindrical symmetry with the polarization vector along the symmetry axis are only stable for the strength of dipolar interaction below a critical value. In the case of bosons, the stability of such a dipolar Bose–Einstein condensate (BEC) is investigated for different strengths of contact and dipolar interactions using a variational approximation and a numerical solution of a mean-field model. In the disc shape, with the polarization vector perpendicular to the plane of the disc, the atoms experience an overall dipolar repulsion and this fact should contribute to the stability. However, a complete numerical solution of the dynamics leads to the collapse of a strongly disc-shaped dipolar BEC due to the long-range anisotropic dipolar interaction. In the case of fermions, the stability of a trapped single-component degenerate dipolar Fermi gas is studied including the Hartree–Fock exchange and Brueckner–Goldstone correlation energies in the local-density approximation valid for a large number of atoms. Estimates for the maximum allowed number of polar Bose and Fermi molecules in the BEC and degenerate Fermi gas are given.
Abstract. Trapped degenerate dipolar Bose and Fermi gases of cylindrical symmetry with the polarization vector along the symmetry axis are only stable for the strength of dipolar interaction below a critical value. In the case of bosons, the stability of such a dipolar Bose-Einstein condensate (BEC) is investigated for different strengths of contact and dipolar interactions using variational approximation and numerical solution of a mean-field model. In the disk shape, with the polarization vector perpendicular to the plane of the disk, the atoms experience an overall dipolar repulsion and this fact should contribute to the stability. However, a complete numerical solution of the dynamics leads to the collapse of a strongly disk-shaped dipolar BEC due to the long-range anisotropic dipolar interaction. In the case of fermions, the stability of a trapped single-component degenerate dipolar Fermi gas is studied including the Hartree-Fock exchange and Brueckner-Goldstone correlation energies in the local-density approximation valid for a large number of atoms. Estimates for the maximum allowed number of polar Bose and Fermi molecules in BEC and degenerate Fermi gas are given. PACS numbers: 03.75.Hh,03.75.Ss,03.75.Kk,05.30.Fk ar
We theoretically investigate various beyond mean-field effects on Bose gases at zero temperature featuring the anisotropic and long-range dipole-dipole interaction in addition to the isotropic and short-range contact interaction. Within the realm of the Bogoliubov--de Gennes theory, we consider static properties and low-lying excitations of both homogeneous and harmonically trapped dipolar bosonic gases. For the homogeneous system, the condensate depletion, the ground-state energy, the equation of state, and the speed of sound are discussed in detail. Making use of the local density approximation, we extend these results in order to study the properties of a dipolar Bose gas in a harmonic trap and in the regime of large particle numbers. After deriving the equations of motion for the general case of a triaxial trap, we analyze the influence of quantum fluctuations on important properties of the gas, such as the equilibrium configuration and the low-lying excitations in the case of a cylinder-symmetric trap. In addition to the monopole and quadrupole oscillation modes, we also discuss the radial quadrupole mode. We find that the latter acquires a quantum correction exclusively due to the dipole-dipole interaction. As a result, we identify the radial quadrupole as a reasonably accessible source for the signature of dipolar many-body effects and stress the enhancing character that dipolar interactions have for quantum fluctuations in the other oscillation modes.
We investigate the ground state and low-lying excitations of a Bose-Einstein condensate (BEC) of dipolar molecules interacting via short-range contact and long-range dipole­ dipole interactions (ddi). We find the mean field ground state via the variational principle using a separable bosonic wave function as the variational state. This state can be refined to include small excitations in the form of plane waves, and the results of the variational calculation are a set of dispersion relations for the low-lying excitations. We analyze the polarization and stability of the ground state as a function of the strength of the external polarizing electric field, the strength of the ddi, and the strength of the contact interactions. In a certain parameter regime of strong contact interactions that oppose the dipole -dipole interactions, we identify a possible signature of a first -order phase transition: the polarization of the gas discontinuously flips as the electric field is continuously ramped through zero field. By examining the dispersion relations, we find that the ground state in this parameter regime is unstable.
Ultracold dilute atomic gases are highly controllable systems whose properties are fundamentally determined by the interatomic interactions.In typical experiments on ultra cold gases particles interact dominantly via a short-range isotropic potential.However, during the last years a new generation of experiments is starting to explore systems, where an additional interaction, the long-range and anisotropic dipole-dipole interaction plays a significant or possibly dominant role.The effects induced by the anisotropy of the dipole-dipole interaction are crucially enhanced if the dipolar gas is confined in a deep optical lattice.In this thesis we study novel phenomena in such systems of dipolar gases in deep optical lattices.The nonlocal nonlinearity introduced by the dipole-dipole interaction plays a crucial role in the physics of dipolar Bose-Einstein condensates.In particular, it may distort significantly the stability of straight vortex lines.Remarkably, in the presence of a periodic potential along the vortex line, the spectrum of transverse modes shows a roton-like minimum, which eventually destabilizes the straight vortex when the BEC as a whole is still stable, opening the possibility for new scenarios for vortex line configurations in dipolar gases.We have analyzed this instability, and showed that it leads to a second-order-like phase transition from a straight vortex line into novel helical or snake-like configurations, depending on the dipole orientation.Strong 1D lattices usually lead to unconnected two-dimensional gases.The long-range character of the dipole-dipole interactions leads to a novel scenario where non-overlapping gases at different sites may interact significantly.We show that the excitations of non-overlapping condensates in 1D optical lattices acquire a band-like character, being collectively shared by different sites.In particular, the hybridization of the modes significantly enhances the rotonization of the excitations, and may induce roton-instability.We discuss the observability of this effect in on-going experiments.Fermionic polar molecules in deep 1D optical lattices may form selfassembled filaments when the electric dipoles are oriented along the lattice axis.These composites are bosons or fermions depending on the number of molecules per chain, leading to a peculiar and complex Bose-Fermi mixture, vi which we discuss in detail for the simplest case of a three-well potential.We show that the interplay between filament binding energy, transverse filament modes, and trimer Fermi energy leads to a rich variety of possible scenarios ranging from a degenerate Fermi gas of trimers to a binary mixture of two different types of bosonic dimers.We study the intriguing zero temperature and finite temperature physics of these composites for the particular case of an ideal filament gas loaded in 1D sites, and discuss possible methods to probe these chain mixtures.
This thesis contains a study of ultracold paramagnetic atoms or polar molecules characterized by a long-range anisotropic dipolar interaction. We particularly focus on two aspects of ultracold dipolar gases. In the first problem the ground state properties of dipolar Bose-Einstein condensates (BEC) are investigated. This problem has gained importance due to recent experimental advances in achieving a condensate of Chromium atoms and ongoing research to produce quantum degenerate polar molecules. In the second problem, we consider possible applications of ultracold polar molecules to rotation sensing and interferometry. First, we concentrate on the interplay between the trapping geometry and dipole-dipole interaction for a polarized dipolar bosonic condensate. As the dipole-dipole interaction is attractive along the polarized direction, the lowest energy state of the BEC is always a collapsed state. However by applying a trapping potential along the polarization direction it is possible to achieve a metastable dipolar BEC. By numerically solving the Gross-Pitaevskii equation, we show that below a critical interaction strength, a metastable state exists depending on the trapping geometry. We also show that a novel feature of dipolar BEC is the appearance of different structural metastable ground states for certain combinations of trapping geometry and particle number. Next, by mixing in single component fermions we show that dipolar BEC can be stabilized against collapse in pancake shaped or cylindrical traps. We also show that the excitation spectrum of the BEC may have a minimum for non-zero momentum, termed a “roton minimum”. This minimum leads to a transition to stable or metastable density-wave states depending on the density of the bosons and boson-fermion interaction strength. In the second problem, we study a proposal for a large-angle coherent beam splitter for polar molecules. By taking into account the effect of a quasi-static external electric field on the rotational levels of the polarized molecules we show that it is possible to coherently split a stationary cloud of molecules into two counter-propagating components. We then investigate the effect of longitudinal acceleration on the transverse motion of the particles, assuming that the longitudinal motion of the molecules can be approximated classically by a wave packet with some mean velocity while the transverse motion is governed by quantum mechanics. We propose a particular time-dependent shape of acceleration to minimize the excitations in the transverse motion. Our theory is also applicable to the general case of particles moving along a circular guide with time-dependent longitudinal velocity. In addition, we include the effects of velocity fluctuations due to noise in the accelerating field.