Environment induced decoherence [1] has taught us that unitary evolution can be very fragile. Recent experiments with cavities [2], ion traps [3] and interference [4] confirm this expectation. All the experiments carried out so far do not help to answer a fundamental question: Can we maintain unitary evolution down to the Planck time? Different formulations of intrinsic decoherence [5-9] foresee that effects on smaller scales permit us to understand the breaking of the unitary evolution and in some way point out possible answers to our question. But, one can ask if some experiments in quantum optics can be devised to find an answer to the question with the present technology. Decoherence in the thermodynamic limit is a proposal to respond to these questions assuming that the Planck time should be a boundary between different physical theory, that is, we have a singular limit [10]. This singular limit is due to blurring in time and an experimental device will always introduce an average with its proper timescale. We show, with some examples recently presented in literature [11-15], how quantum optics can help to give a definite answer to the main question about unitary evolution, providing in this way direct hints for new physics. This approach to decoherence appears as a new understanding of the measurement problem in quantum mechanics.
Environment induced decoherence [1] has taught us that unitary evolution can be very fragile. Recent experiments with cavities [2], ion traps [3] and interference [4] confirm this expectation. All the experiments carried out so far do not help to answer a fundamental question: Can we maintain unitary evolution down to the Planck time? Different formulations of intrinsic decoherence [5-9] foresee that effects on smaller scales permit us to understand the breaking of the unitary evolution and in some way point out possible answers to our question. But, one can ask if some experiments in quantum optics can be devised to find an answer to the question with the present technology. Decoherence in the thermodynamic limit is a proposal to respond to these questions assuming that the Planck time should be a boundary between different physical theory, that is, we have a singular limit [10]. This singular limit is due to blurring in time and an experimental device will always introduce an average with its proper timescale. We show, with some examples recently presented in literature [11-15], how quantum optics can help to give a definite answer to the main question about unitary evolution, providing in this way direct hints for new physics. This approach to decoherence appears as a new understanding of the measurement problem in quantum mechanics.
We prove a very general theorem on decoherence in the thermodynamic limit, widely extending the scope of our preceding results [Phys. Lett. A 308, 135 (2003)]. The concept of a singular limit in time is used in the proof. Recent experimental findings [1, 2, 3, 4, 5] in NMR with organic molecular crystals have shown that an intrinsic decoherence effect is present in a many-body system in the thermodynamic limit. These experiments, that are known just in the NMR community, give a strong support to our understanding of decoherence as an effect arising from the thermodynamic limit applied to unitary evolution [6, 7, 8, 9, 10, 11, 12]. These theoretical results are based on a concept of singular limit in time. This concept seems to have been pioneered by Bohm [13, 14]. Indeed, the existence of such an effect would give a relevant answer both to the measurement problem and the question of the irreversibility: both are essential to the understanding of a classical world emerging from quantum mechanics. Besides, recent experiments with cavities realized by Haroche’s group [15, 16] have produced asymptotic states with a large number of photons as foreseen by Gea-Banacloche [17, 18] and further analyzed by Knight and Phoenix [19, 20]. As firstly pointed out by Gea-Banacloche, these states support a view of quantum measurement described by decoherence in the thermodynamic limit, in agreement with our view. In this case one has that
All real-world quantum systems interact with their surrounding environment to some extent. No matter how weak the coupling that prevents the system from being isolated, the evolution of an open quantum system is eventually plagued by non-unitary features, such as decoherence and dissipation. Decoherence is a quantum effect where the system loses its ability to exhibit coherent behavior. Nowadays, decoherence stands as a serious obstacle in quantum information processing. As the manipulation of quantum coherence in experiments has progressed, the need to better understand, control, and utilize dissipative non-equilibrium dynamics of quantum systems has grown in importance. This has ranged from fundamental questions associated with the quantum-to-classical transition and quantum thermodynamics innovation in quantum optics and cavity/circuit quantum electrodynamics. Current studies of many-body dynamics, ultracold atoms in optical lattices, trapped ions, superconducting systems, nanoelectro-mechanical systems, and quantum fields under the influence of external conditions offer new challenges to address questions regarding quantum systems far from equilibrium. On the theoretical side, quantum trajectory-based methods could be the key to both quantum nanodevice design and exploration of new regimes of quantum mechanics and quantum measurement, as well as applications to various quantum technologies.
All real-world quantum systems interact with their surrounding environment to some extent. No matter how weak the coupling that prevents the system from being isolated, the evolution of an open quantum system is eventually plagued by non-unitary features, such as decoherence and dissipation. Decoherence is a quantum effect where the system loses its ability to exhibit coherent behavior. Nowadays, decoherence stands as a serious obstacle in quantum information processing. As the manipulation of quantum coherence in experiments has progressed, the need to better understand, control, and utilize dissipative non-equilibrium dynamics of quantum systems has grown in importance. This has ranged from fundamental questions associated with the quantum-to-classical transition and quantum thermodynamics innovation in quantum optics and cavity/circuit quantum electrodynamics. Current studies of many-body dynamics, ultracold atoms in optical lattices, trapped ions, superconducting systems, nanoelectro-mechanical systems, and quantum fields under the influence of external conditions offer new challenges to address questions regarding quantum systems far from equilibrium. On the theoretical side, quantum trajectory-based methods could be the key to both quantum nanodevice design and exploration of new regimes of quantum mechanics and quantum measurement, as well as applications to various quantum technologies.
Decoherence is a relatively recent concept in the field of quantum mechanics. Although the pioneers of the field must have understood that loss of phase coherence in quantum superpositions is the reason underlying the appearance of definite outcomes in the quantum measurement problem, the latter was not treated in terms of decoherence until sixty years after the formulation of quantum mechanics as described in a report by Joos and Zeh in 1983 [1]. However, soon after, the theory was developed in further detail, and experiments to measure the actual decoherence rates in various systems commenced. Today, decoherence is the main concern for another reason, i.e., the fact that superposition states must be maintained undisturbed in the quantum communication systems and decoherence presents a strong limitation for their practical application. Decoherence appears in open quantum systems, where the basic system under consideration interacts relatively strongly with an environment. Decoherence times may be as long as seconds for small atomic systems in extreme vacua, although below what is presently measurable (i.e., less than a fraction of a femtosecond) in most liquids and solids, where coupling to the surrounding molecules or atomic arrangements is strong. The relatively slow decoherence in well-isolated particle systems has been described in several recent articles on quantum optics, while the rapid decoherence in liquids and solids has not received this kind of attention. It is the purpose of the present review to fill this gap.
To understand in detail the relation between unitary quantum theory that describes our world at the microscopic scale and thermodynamics, which was long believed only to apply to macroscopic objects, is one of the most interesting and long-standing problems in physics. Recently, this problem has received renewed attention, in particular from the community of quantum information theory, but also from the field of statistical mechanics, inspired from stochastic thermodynamics. These results suggest that thermodynamics is also relevant for individual quantum systems, provided that they can be brought into contact with thermal baths. In this thesis, I use recently developed tools to provide new results both on fundamental questions, but also on questions which are of practical relevance for potential miniaturized thermal machines. In terms of fundamental questions, the results in this thesis contribute to understanding how the basic laws of thermodynamics and statistical mechanics can be understood directly from unitary quantum mechanics. In particular, I discuss and answer the following questions: i) How can we quantify the third law of thermodynamics using information theoretic methods? ii) How can we quantify the "thermodynamic value" of a state-transition in quantum systems? iii) How can we axiomatically characterize the non-equilibrium free energy and relative entropy? iv) How can we justify statistical ensembles from an operational perspective, without having to introduce either some probability measures or an information theoretic entropy measure? v) How can we understand the equilibration of closed quantum systems, how long does it take and how difficult is it to avoid? In the second part of the thesis I discuss in detail how experimental restrictions, which become important at the quantum scale, influence the ultimate thermodynamic bounds for thermal machines. In particular, the results in this thesis provide thermodynamic bounds on work-extraction and efficiencies of thermal machines in situations where 1.) an experimenter only has limited field strengths available, 2.) an experimenter cannot control the interactions between particles, but external fields arbitrarily well, and 3.) situations in which a small quantum system can only be strongly coupled to heat baths. These bounds are tight and I provide explicit examples illustrating the different behaviours. Finally, I come back to a classic problem in statistical physics: The emergence of spontaneous symmetry breaking. Here, I provide general and rigorous new results that show how symmetry-breaking stationary states emerge from fluctuations in order parameters in dissipative lattice models.
Time evolution operator in quantum mechanics can be changed into a statistical operator by a Wick rotation. This strict relation between statistical mechanics and quantum evolution can reveal deep results when the thermodynamic limit is considered. These results translate in a set of theorems proving that these effects can be effectively at work producing an emerging classical world without recurring to any external entity that in some cases cannot be properly defined. In a many-body system has been recently shown that Gaussian decay of the coherence is the rule with a duration of recurrence more and more small as the number of particles increases. This effect has been observed experimentally. More generally, a theorem about coherence of bulk matter can be proved. All this takes us to the conclusion that a well definite boundary for the quantum to classical world does exist and that can be drawn by the thermodynamic limit, extending in this way the deep link between statistical mechanics and quantum evolution to a high degree.