It is difficult to incorporate the concept of interacting physical particles in the frame of conventional quantum mechanics. It comes from the fact that in this formalism the Hamiltonian plays a dual role as the generator of motion and as the observable associated with the energy. As a result it is easy to define either a representation in which particles interact but are not well defined (a representation in which the Hamiltonian is not diagonal) or a representation in which the units are well defined but do not interact. We expect that in the search for a representation in which we may speak of both well defined and still interacting particles, the distinction between reversible and irreversible processes should play a basic role. Certainly we do not want to eliminate irreversible processes such as scattering, production or decay which are basically related to the mechanisms through which we observe particles. To distinguish between reversible and irreversible processes we have to work in a representation such that a Liapounov function (the entropy) may be ascribed to the time evolution of the system. The introduction of such a representation through a specific class of non-unitary transforms is described. We then propose newmore » quantum rules directly applicable to dissipative systems with a Liapounov function. For systems with a discrete spectrum these new quantum rules reduce trivially to the usual quantum rules as formulated by Born, Jordan and Heisenberg. The theory is applied to a simple field theoretical model - the so-called Friedrichs model-for which all calculations can be performed exactly.« less
It is difficult to incorporate the concept of interacting physical particles in the frame of conventional quantum mechanics. It comes from the fact that in this formalism the Hamiltonian plays a dual role as the generator of motion and as the observable associated with the energy. As a result it is easy to define either a representation in which particles interact but are not well defined (a representation in which the Hamiltonian is not diagonal) or a representation in which the units are well defined but do not interact. We expect that in the search for a representation in which we may speak of both well defined and still interacting particles, the distinction between reversible and irreversible processes should play a basic role. Certainly we do not want to eliminate irreversible processes such as scattering, production or decay which are basically related to the mechanisms through which we observe particles. To distinguish between reversible and irreversible processes we have to work in a representation such that a Liapounov function (the entropy) may be ascribed to the time evolution of the system. The introduction of such a representation through a specific class of non-unitary transforms is described. We then propose newmore » quantum rules directly applicable to dissipative systems with a Liapounov function. For systems with a discrete spectrum these new quantum rules reduce trivially to the usual quantum rules as formulated by Born, Jordan and Heisenberg. The theory is applied to a simple field theoretical model - the so-called Friedrichs model-for which all calculations can be performed exactly.« less
The microscopic theory of irreversible processes that we developed is summarized and illustrated, using as a simple example the Friedrichs model. Our approach combines the Poincaré's point of view (dynamical interpretation of irreversibility) with the Gibbs-Einstein ensemble point of view. It essentially consists in a nonunitary transformation theory based on the symmetry properties of the Liouville equation and dealing with continuous spectrum. The second law acquires a microscopic content in terms of a Liapounov function which is a quadratic functional of the density operator. In our new representation of dynamics, which is defined for a restricted set of observables and states, this functional takes a universal form. We obtain, in this way, a semi-group description, the generator of which contains a part directly related to the microscopic entropy production. The Friedrichs model gives us a simple field theoretical example for which the entropy production can be evaluated. The thermodynamical meaning of life-times is explicitly displayed. The transition from pure states to mixtures, as well as the occurrence of long tails in thermodynamic systems, are also briefly discussed.
The investigation of the recently described generalized transformation theory which leads to a non-Hamiltonian description of dynamics is pursued. The concept of generalized unitary transformations of superoperators is introduced and a specific class of transformations studied. For nondissipative systems it is equivalent to the usual unitary transformations that diagonalize the Hamiltonian. The important point is that this class of transformations remains meaningful for dissipative systems, hence a new representation of dynamics that we shall call the "physical particle" representation. It has the following properties: (a) The energy (or an arbitrary function of the energy) is represented by a diagonal matrix. (b) In the ((0))II space (see these Proceedings, 65, 789 (1970)) corresponding to the coherent processes, the evolution can be described in terms of the changes in population of the physical particles. (c) At thermodynamic equilibrium, the physical particles are uncorrelated and behave as independent entities; the entropy has a purely combinatorial meaning.A full description of dynamics in this representation will be given in a forth-coming paper.
The second law of thermodynamics, for quantum systems, is formulated, on the microscopic level. As for classical systems, such a formulation is only possible when specific conditions are satisfied (continuous spectrum, nonvanishing of the collision operator, etc.). The unitary dynamical group can then be mapped into two contractive semigroups, reaching equilibrium either for t --> +infinity or for t --> -infinity. The second law appears as a symmetry-breaking selection principle, limiting the observables and density functions to the class that tends to thermodynamic equilibrium in the future (for t --> +infinity). The physical content of the dynamical structure is now displayed in terms of the appropriate semigroup, which is realized through a nonunitary transformation. The superposition principle of quantum mechanics has to be reconsidered as irreversible processes transform pure states into mixtures and unitary transformations are limited by the requirement that entropy remains invariant. In the semigroup representation, interacting fields lead to units that behave incoherently at equilibrium. Inversely, nonequilibrium constraints introduce correlations between these units.
The compatibility of irreversibility, as expressed by the second law of thermodynamics, with ordinary quantum mechanics requires an extension of the latter. Such an extension of a reversible formalism is made possible by the presence of self-energy processes (already found in quantum electrodynamics), which allows for the widening of the dynamics through the introduction of specific additional variables leading to the recognition of such processes. A projection technique modeled on that introduced long ago by the Brussels group defines a subdynamics that is shown to contain the starting formulation in its entirety. (It corresponds to a restricted class of initial conditions, namely the reversible ones.) A new kinetic description is obtained in which, e.g., collision processes for privileged components arise from the original interaction. This method is applied successively to various models, and we focus in this paper on the possible presence of temporal behaviour excluded in ordinary quantum mechanics. Among the differences between this framework and that of ordinary quantum mechanics, the possibility appears for the purely exponential decay of a particle, while ordinary quantum mechanics requires long time tails associated with the finite lower bound in the spectrum of the Hamiltonian.
The compatibility of irreversibility, as expressed by the second law of thermodynamics, with ordinary quantum mechanics is a challenging problem. Our solution requires an extension of the latter. Such an extension of a reversible formalism is made possible by the presence of self‐energy processes (already found in quantum electrodynamics) which enables the widening of the dynamics by the introduction of specific additionnal variables leading to the recognition of such processes. A projection technique modeled on the one introduced long ago by the Brussels group defines a subdynamics which is shown to contain entirely the starting formulation (it corresponds now to a restricted class of initial conditions, namely the reversible one). A new kinetic description is obtained in which e.g. collision processes for privileged components arise from the original interaction. This method is applied successively to various models and we focus in this paper on the possible presence of temporal behaviours excluded in ordinary quantum mechanics. Among those differences, the possibility appears of a purely exponential decay for a particle while ordinary quantum mechanics requires long time tails associated with the finite lower bound in the spectrum of the Hamiltonian.