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Journal of Physics B Atomic and Molecular Physics

The Raman process in the case of multiphoton excitation of the hydrogen molecule in an intense laser beam

U. Devi, S Bhatnagar

Published Jul 11, 1974• 1 citation
Publisher

Abstract

The reduced transition amplitude for the multiphoton excitation with the emission of one Raman photon of the hydrogen molecule due to an intense EM field from the ground state 1s sigma 1 Sigma g + to the excited state B2p sigma 1 Sigma u + has been calculated using a method due to Reiss (1970). The intensity dependence of the transition probability has been numerically investigated. A major feature of the curve is the oscillatory behaviour for larger values of N where N is the number of photons absorbed in the process.

DOI
10.1088/0022-3700/7/10/006

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The reduced transition amplitude for the multiphoton excitation with the emission of one Raman photon of the hydrogen molecule due to an intense EM field from the ground state 1s sigma 1 Sigma g + to the excited state B2p sigma 1 Sigma u + has been calculated using a method due to Reiss (1970). The intensity dependence of the transition probability has been numerically investigated. A major feature of the curve is the oscillatory behaviour for larger values of N where N is the number of photons absorbed in the process.
Transition amplitudes corresponding to bound-bound multiphoton transitions with the emission or absorption of one and two Raman photons in the hydrogen atom have been evaluated following a recent method of Reiss. Results show that the transition probability varies smoothly for low values of NNN, where NNN is the number of intense photons absorbed or emitted during the transition. For larger values of NNN the amplitude, however, has oscillatory behavior. A particular feature of the present method of calculation is that we find the "reduced" transition amplitude for induced emission of two Raman photons is enhanced compared with single-Raman-photon emission. Another distinctive feature is the appearance of many more extrema in the transition amplitude for higher transitions for multiphoton processes at high intensity.
Using the hydrogenic model for the helium atom, the amplitude of transition from states He(ls) to He(ls, nl) by absorption of N photons of an intense field together with the emission of one Raman photon is evaluated. From the general expression for the transition amplitude, the particular case of transition from He(ls) to He(ls, 2p) is considered. The 'reduced' transition amplitude is plotted against the number of photons N involved and against the intensity parameter y st;parately. It is found that the s wave contributes maximaly to the transition amplitude. An important feature of the calculations is the appearance of nonlinear behaviour at high intensity. The dominance of higher order processes over lower ones at high intensity is also found.
The process of resonant multiphoton ionization of a hydrogen atom in the ground 1 s state is studied by direct numerical integration of the nonstationary Schrödinger equation for a quantum system in an electromagnetic field. The dependence of photoionization probability on the radiation intensity is found to be nonmonotonic. It is established that the minima of ionization correspond to multiphoton resonances between the ground state and one of the excited (Rydberg) atomic states perturbed by the laser field. It is shown that ionization is suppressed due to rearrangement of Rydberg states in a strong electromagnetic field and is accompanied by efficient Raman Λ transitions, which connect a set of closely lying Rydberg states via the continuum.
Analyses of the resonant multiphoton ionization of atoms require knowledge of ac Stark energy shifts and of multiphoton, bound-to-bound state, transition amplitudes. In this paper, we consider the three-photon photoionization of hydrogen atoms at frequencies that are at and surrounding the two-photon 1s to 2s resonance. AC energy shift sums of both the 1s and 2s states are calculated as a function of the laser frequency along with two-photon 1s ? 2s resonant transition amplitude sums. These quantities are calculated using an extended version of a method, which has often been employed in a variety of ways, of calculating these sums by expressing them in terms of solutions to a variety of differential equations that are derived from the different sums being evaluated. We demonstrate how exact solutions are obtained to these differential equations, which lead to exact evaluations of the corresponding sums. A variety of different cases are analysed, some involving analytic continuation, some involving real number analysis and some involving complex number analysis. A dc Stark sum calculation of the 2s state is carried out to illustrate the case where analytic continuation, pole isolation and pole subtraction are required and where the calculation can be carried out analytically; the 2s state, ac Stark shift sum calculations involve a case where no analytic continuation is required, but where the solution to the differential equation produces complex numbers owing to the finite photoionization lifetime of the 2s state. Results from these calculations are then used to calculate three-photon ionization probabilities of relevance to an analysis of the multiphoton ionization data published by Kyrala and Nichols (1991 Phys. Rev. A 44, R1450).