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Journal of Mathematical Physics

Representations of the Canonical Commutation Relations Describing a Nonrelativistic Infinite Free Bose Gas

H. Araki, E. J. Woods

Published May 1, 1963• 398 citations
Publisher

Abstract

The existence of inequivalent representations of the canonical commutation relations which describe a nonrelativistic infinite free Bose gas of uniform density is investigated, with a view to possible applications to statistical mechanics. The functional E(f, g)=(Ψ, eiφ(f) eiπ(g)Ψ) is used to describe the inequivalent representations. This functional is calculated for the free Bose gas in a box of volume V, and the limit is then taken as V → ∞. In this way we construct cyclic representations describing an infinite system of particles with a density distribution ρ(k) in momentum space. For a given ρ(k) the operator algebra generated by the φ(f), π(g) is reducible. For the ground-state representation (all particles in the zero-momentum state), the representation is a direct integral of irreducible representations (analogous to BCS theory). For finite temperatures the situation is complicated by the occurrence of representations which are not type I. The physical significance of the reducibility of the representations is discussed. It is argued that the thermal ensemble for the infinite system is a pure state at zero temperature, although there is some ambiguity as to which operators should belong to the algebra of observables. For finite temperatures, the thermal ensemble seems to be a mixture. The case of an interacting Bose gas is considered briefly.

DOI
10.1063/1.1704002

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The existence of inequivalent representations of the canonical commutation relations which describe a nonrelativistic infinite free Bose gas of uniform density is investigated, with a view to possible applications to statistical mechanics. The functional E(f, g)=(Ψ, eiφ(f) eiπ(g)Ψ) is used to describe the inequivalent representations. This functional is calculated for the free Bose gas in a box of volume V, and the limit is then taken as V → ∞. In this way we construct cyclic representations describing an infinite system of particles with a density distribution ρ(k) in momentum space. For a given ρ(k) the operator algebra generated by the φ(f), π(g) is reducible. For the ground-state representation (all particles in the zero-momentum state), the representation is a direct integral of irreducible representations (analogous to BCS theory). For finite temperatures the situation is complicated by the occurrence of representations which are not type I. The physical significance of the reducibility of the representations is discussed. It is argued that the thermal ensemble for the infinite system is a pure state at zero temperature, although there is some ambiguity as to which operators should belong to the algebra of observables. For finite temperatures, the thermal ensemble seems to be a mixture. The case of an interacting Bose gas is considered briefly.
The existence of a Bose-Einstein condensation in an interacting many-boson system at T = 0°K is proved under certain conditions on the particle density and the interparticle potential. Starting with the tentative assumption that the condensation exists, we study the fluctuation in the occupation number of the condensate with due regard to its interactions (1) with particles outside the condensate as well as (2) with the fluctuation itself. If the condensate fluctuation has a normalizable ground state, then the assumed existence of the condensation is tenable. For the case of the pair-Hamiltonian model satisfying the conditions for condensation, the interactions of the second category are of no importance. In the limit of infinite volume, this Hamiltonian can be diagonalized in an irreducible representation of a Bose-field operatorφ(x), whereφ(x) has nonvanishing ground state expectation value, in accordance with the usual c-number replacement of creation and destruction operators for the condensate particles. The full Hamiltonian for a system of pairwise interacting bosons is studied only in a low-density limit. Bose-Einstein condensation exists when the over-all space integral of the interparticle potential is positive. In this case the interactions of the second category play an important role in ensuring a normalizable ground state for the condensate fluctuation. There is an indication that in the limit of infinite volume the Hamiltonian cannot be diagonalized in any irreducible representation of the field operatorφ. Yet the c-number replacement of the condensate operators is legitimate as far as states of particles outside the condensate are concerned. Some speculations are made as to what may happen for systems of moderate density.
This paper is a study of the representations of the current algebra for an infinite, free, Bose or Fermi system at finite temperature. The state of the algebra is calculated for a finite system by use of the grand canonical formalism of statistical physics, and the thermodynamic limit is used to get the representation of the infinite case. An expression of the states is given in terms of determinants of one particle operators. In a second part, the usual formulas for the occupation density, the condensation temperature for bosons, etc., are recovered. It is also found that the canonical and grand canonical formalisms are equivalent when used to study Fermi systems in the thermodynamic limit, but not so for the Bose systems. It is postulated that this has something to do with the phase transition of Bose systems. Finally, the problem of the Hamiltonian is discussed in some details. The states calculated previously are used to test a method for calculating expectation values of the Hamiltonian, given the states of the algebra; it yields the correct value for the case of the free system at finite temperature.
Abstract Berezin and Weyl quantization are renowned procedures for mapping commutative Poisson algebras of observables to their non-commutative, quantum counterparts. The latter is famous for its use on Weyl algebras, while the former is more appropriate for continuous functions decaying at infinity. In this work, we define a variant of the Berezin quantization map, which acts on the classical Weyl algebra W(E,0)\mathcal {W}(E,0)W(E,0) W ( E , 0 ) and constitutes a positive strict deformation quantization . This construction provides a natural framework to compare classical and quantum thermal equilibrium states of a Bose gas through the computation of their semi-classical limit. To this end, we first introduce a purely algebraic notion of KMS states for the classical Weyl algebra and establish that, in finite volume, there exists a unique such state, which can be interpreted as the Fourier transform of a Gibbs measure on a Hilbert space. We then construct a new class of classical KMS states that realize representations of the canonical commutation relations with infinite local density. These states arise as the semi-classical high-density limit of the quantum equilibrium states originally studied by Araki and Woods [5]. A key feature of our approach is that it preserves the macroscopic ground-state occupation of the Bose gas in the classical regime. Finally, we demonstrate that the infinite-volume classical states can be obtained as thermodynamic limits of finite-volume Gibbs states.
A presentation of the canonical commutation relation of Bose fields is given in a way which is independent of the choice of the bases of the test functions and covariant with respect to the Euclidean transformation of the coordinate system. It is shown that the representation is characterized by an integral on the conjugate space L* of the space L of the test functions and a real function on Σ⊗L* where Σ is the group of the transformations f→u-1f+φ; fεL*, φεL and u is a Euclidean transformation of L*. The conditions for the irreducibility of a representation and the unitary equivalence of the representations and the existence of unique vacuum state are given. An example of the inequivalent Euclidean covariant irreducible representations containing unique vacuum state is given.
The case of a noninteracting infinite Bose gas at zero temperature is studied in the formalism of local current algebras, using the representation theory of nuclear Lie groups. The class of representations describing such a system is obtained by taking an ``N / V limit'' of the finite case. These representations can also be determined uniquely from the solutions of a functional differential equation, which follows in turn from a condition on the ground state vector. Finally a system of functional differential equations is formulated for a theory with interactions, using a proposed definition of indefinite functional integration.
Considered is a family of irreducible Weyl representations of canonical commutation relations with infinite degrees of freedom on the abstract boson Fock space over a complex Hilbert space. Theorems on equivalence or inequivalence of the representations are reportedcdot. As a simple application, the well known inequivalence of the time-zero field and conjugate momentum of different masses in a quantum scalar field theory is rederived with space dimension dgeq 1 arbitrary. Also a generalization of representations of the time-zero field and conjugate momentum is presented. Comparison is made with a quantum scalar field on a bounded space of mathbb{R}^{d}. In the case of a bounded space with d=1, 2, 3, the representations of different masses turn out to be mutually equivalent.