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Journal of Low Temperature Physics

Matrix elements of a many-boson Hamiltonian in a representation of correlated basis functions

Fa Yueh Wu

Published Nov 1, 1972• 5 citations
Publisher
DOI
10.1007/bf00654841

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Absorption band shapes of an asymmetric dimer system constituted by monomers with different excitation energies and optical transition matrix elements are considered in the semiclassical parameter region. Optical transition matrix elements originating from arbitrary initial vibrational states are analyzed on the basis of a spin representation of the eigenstates of an associated symmetry broken spin-boson Hamiltonian. Correlations between the spin-down and spin-up coefficients of these eigenstates are shown to exist and investigated in detail. Using these correlations, an asymmetry interpolation of the intensity of absorption lines between dimer configurations with different optical monomer transition matrix elements is proposed.