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Physica B+C

The Schrödinger equation as the main quantization principle

E. E. Entralgo, V. V. Kuryshkin

Published Jul 1, 1988• 0 citations
Publisher
DOI
10.1016/0378-4363(88)90183-0

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In the first two chapters we have examined the basic principles – superposition (p. 18), complementarity (p. 19), quantization (p. 44), statistical algorithm (p. 57), and correspondence (p. 72) (see also Subsec. 2.3.4) – and the basic entities, observables and states, of quantum mechanics, as well as the main differences with respect to classical mechanics. While what we have discussed so far is rather a static picture of observables and states, in this chapter we shall deal with quantum dynamics, i.e. with the time evolution of quantum-mechanical systems. Historically, after Bohr had provided a quantized description of the atom (see Subsec. 1.5.4), Einstein showed the quantized nature of photons (see Subsec. 1.2.1), and de Broglie hypothized the wave-like nature of matter (see Subsec. 1.5.5), the first building block of quantum mechanics was provided by the commutation relations, proposed by Heisenberg in 1925, whose consequence is represented by the uncertainty relation (see Subsec. 2.2.7 and Sec. 2.3). This was the subject of the previous chapters. The dynamical part of the theory was proposed by Schrödinger in 1926, and is known as the Schrödinger equation. It is also known as wave mechanics (see Subsec. 1.5.7). In this chapter we shall show that Heisenberg's and Schrödinger's formulations are only two different aspects of the same theory. We shall also come back to this point in Sec. 8.1.1. Here, first we shall derive the fundamental equation which rules quantum dynamics (Sec. 3.1), and, in Sec. 3.2, we shall summarize the main properties of the Schrödinger equation.
We study the quantization of a classical system of interacting particles obeying a recently proposed kinetic interaction principle (KIP) [G. Kaniadakis, Physica A 296, 405 (2001)]. The KIP fixes the expression of the Fokker-Planck equation describing the kinetic evolution of the system and imposes the form of its entropy. In the framework of canonical quantization, we introduce a class of nonlinear Schrödinger equations (NSEs) with complex nonlinearities, describing, in the mean-field approximation, a system of collectively interacting particles whose underlying kinetics is governed by the KIP. We derive the Ehrenfest relations and discuss the main constants of motion arising in this model. By means of a nonlinear gauge transformation of the third kind, it is shown that in the case of constant diffusion and linear drift, the class of NSEs obeying the KIP is gauge-equivalent to another class of NSEs containing purely real nonlinearities depending only on the field rho=|psi|(2) .
This is the third in a series of papers which intends to develop a new microscopic theory capable by itself to determine the “maximaldecoupled” collective subspace in the many-particle Hilbert space as well as the collective Hamiltonian specifying the subspace. The fundamental principle to formulate the theory is called the invariance principle of the Schrödinger equation. The main purpose of this paper is to show that, when we positively utilize the invariance principle, we can directly obtain a quantum theory of collective motion going beyond the random phase approximation.