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Physics Letters A

Non-existence of long-range order in a model of polyacetylene

Harald Grosse, Keiichi R. Ito

Published Apr 1, 1985• 2 citations
Publisher
DOI
10.1016/0375-9601(85)90108-2

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In this paper,we use the extended SSH Hamilton model plus Long-range electron correlation Hamiltonian to study change of long-range correlation energy with time in a finite length trans-polyacetylene chain with free boundaries under adiabatic condition in terms of dynamic method.We calculated the effect of the long-rang electron correlation on the polaron dynamics.It is found that the long-rang correlation shows a non-periodic damped oscillation with time when we add an electron or a hole in the trans-polyacetylene chain.After some time,the long-rang correlation energy approaches a constant and at the same time the stable configuration of the lattice is reached.The time that the long-rang correlation energy tends to a constant will decrease with increasing the lattice numbers.

Journal of Atomic and Molecular Physics•Jan 1, 2013•0 citations
In this paper,we use the extended SSH Hamilton model plus Long-range electron correlation Hamiltonian to study change of long-range correlation energy with time in a finite length trans-polyacetylene chain with free boundaries under adiabatic condition in terms of dynamic method.We calculated the effect of the long-rang electron correlation on the polaron dynamics.It is found that the long-rang correlation shows a non-periodic damped oscillation with time when we add an electron or a hole in the trans-polyacetylene chain.After some time,the long-rang correlation energy approaches a constant and at the same time the stable configuration of the lattice is reached.The time that the long-rang correlation energy tends to a constant will decrease with increasing the lattice numbers.