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Physical Review Letters

Necessary Conditions on Potential Functions for Nonrelativistic Bound States

Gerald Rosen

Published Dec 27, 1982• 14 citations
Publisher

Abstract

It is shown that $\ensuremath{\int}{|V(\stackrel{\ensuremath{\rightarrow}}{\mathrm{x}})|}^{\frac{3}{2}}{d}^{3}x>(\frac{{\ensuremath{\pi}}^{2}}{4}){(\frac{3{\ensuremath{\hbar}}^{2}}{2m})}^{\frac{3}{2}}$ is a necessary condition for one or more normalizable bound-state solutions to the nonrelativistic Schr\"odinger energy-eigenvalue equation for any potential function $V(\stackrel{\ensuremath{\rightarrow}}{\mathrm{x}})$ such that the integral is finite. Moreover, for potentials such that $\ensuremath{\int}{|V(\stackrel{\ensuremath{\rightarrow}}{\mathrm{x}})|}^{\frac{3\ensuremath{\gamma}}{2}}{d}^{3}x$ is finite for a value or values of $\ensuremath{\gamma}>1$, the magnitude of a negative energy eigenvalue is related to the latter integral by a general inequality derived here.

DOI
10.1103/physrevlett.49.1885

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The problem of determining the Schr\"odinger wave function of a nonrelativistic particle that is either scattered by a potential of a finite range or that is bound to it is reformulated in a novel way. It is shown that in either case the wave function must satisfy a certain boundary condition on the surface that delimits the effective range of the potential. For scattering states the boundary condition is analogous to the mathematical formulation of the Ewald-Oseen extinction theorem of classical electromagnetic theory. The new formulation is illustrated by determining the scattering states and the bound states for a central potential. It is also shown that a boundary condition that is used in band-structure calculations in solids is an immediate consequence of our quantum-mechanical extinction theorem for bound states.
We investigate the approximate bound state solutions of the Schr\"odinger equation for the PT-/non-PT-symmetric and non Hermitian Hellmann potential. Exact energy eigenvalues and corresponding normalized wave functions are obtained. Numerical values of energy eigenvalues for the bound states are compared with the ones obtained before. Scattering state solutions are also studied. Phase shifts of the potential are written in terms of the angular momentum quantum number ℓ\ellℓ.
We investigate the approximate bound state solutions of the Schrödinger equation for the PT-/non-PT-symmetric and non Hermitian Hellmann potential. Exact energy eigenvalues and corresponding normalized wave functions are obtained. Numerical values of energy eigenvalues for the bound states are compared with the ones obtained before. Scattering state solutions are also studied. Phase shifts of the potential are written in terms of the angular momentum quantum number ℓ\ellℓ.
It is shown that if the wave function of a nonrelativistic particle satisfies the Schr\"odinger equation with a velocity-independent potential, then its scattering amplitudes (and the SSS matrix in general) satisfy the same dispersion formulas as those derived for the scattering of light. In the present derivation, the validity of a perturbation expansion and certain integrability of the potential are assumed, and the requirement of the outgoing wave Green's function replaces the condition of strict causality for the scattering of light. The scattering amplitude for fixed momentum transfer is also shown to satisfy the dispersion relations. Together with the unitarity of the SSS matrix, the complete SSS matrix is determined by the Fourier transform of the potential through an iterative procedure using the dispersion relations. If the potential possesses bound states, then all the dispersion formulas are modified to include residue terms corresponding to singularities on the positive imaginary axis of the momentum plane. The necessity of these modifications is related to the divergence of the perturbation series for small wave numbers. Essential singularities of the SSS matrix due to exponentially damped potentials give no additional contribution to the dispersion formulas.
Considering energy eigenvalues E(m1{m}_{1}m1​,m2{m}_{2}m2​) with respect to two particles whose masses are m1{m}_{1}m1​ and m2{m}_{2}m2​, respectively, one would expect that if M>m then E(M,m2{m}_{2}m2​)>E(m,m2{m}_{2}m2​), but actually the opposite can happen if one solves the Schr\"odinger equation. In other words, the derivative \ensuremath{\partial}E/\ensuremath{\partial}m1{m}_{1}m1​ can be negative. In this paper a general condition of this problem is given.