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Physical Review

Energy Levels of a Bose-Einstein System of Particles with Attractive Interactions

Kerson Huang

Published Aug 15, 1959• 41 citations
Publisher

Abstract

An $N$-body Bose-Einstein system of particles with long-range attraction and hard-sphere repulsion between particles is considered. It is shown that if the constants of the interaction have values within a certain range it is possible to calculate the ground-state energy of the system as a function of $\frac{\ensuremath{\Omega}}{N}$, where $\ensuremath{\Omega}$ is the volume of the box containing the system, in the limit $N\ensuremath{\rightarrow}\ensuremath{\infty}$, $\ensuremath{\Omega}\ensuremath{\rightarrow}\ensuremath{\infty}$, with $\frac{N}{\ensuremath{\Omega}}=\ensuremath{\rho}$ fixed. The results show that the system can possess an $N$-body bound state, which has an equilibrium density and negative energy, and that the interactions can be saturating. Excited states are also considered. It is shown that low-lying excitations consist purely of phonons, whose velocity agrees with that computed from the macroscopic compressibility, furnished by the ground-state energy. The formula for the general excited energy levels suggests that thermodynamically the system may have a "gas" phase and two "liquid" phases, the transition between the two "liquid" phases being the analog of the Bose-Einstein condensation of the ideal gas. Thermodynamic considerations are, however, not contained in this paper.

DOI
10.1103/physrev.115.765

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An NNN-body Bose-Einstein system of particles with long-range attraction and hard-sphere repulsion between particles is considered. It is shown that if the constants of the interaction have values within a certain range it is possible to calculate the ground-state energy of the system as a function of \ensuremathΩN\frac{\ensuremath{\Omega}}{N}N\ensuremathΩ​, where \ensuremathΩ\ensuremath{\Omega}\ensuremathΩ is the volume of the box containing the system, in the limit N\ensuremath→\ensuremath∞N\ensuremath{\rightarrow}\ensuremath{\infty}N\ensuremath→\ensuremath∞, \ensuremathΩ\ensuremath→\ensuremath∞\ensuremath{\Omega}\ensuremath{\rightarrow}\ensuremath{\infty}\ensuremathΩ\ensuremath→\ensuremath∞, with N\ensuremathΩ=\ensuremathρ\frac{N}{\ensuremath{\Omega}}=\ensuremath{\rho}\ensuremathΩN​=\ensuremathρ fixed. The results show that the system can possess an NNN-body bound state, which has an equilibrium density and negative energy, and that the interactions can be saturating. Excited states are also considered. It is shown that low-lying excitations consist purely of phonons, whose velocity agrees with that computed from the macroscopic compressibility, furnished by the ground-state energy. The formula for the general excited energy levels suggests that thermodynamically the system may have a "gas" phase and two "liquid" phases, the transition between the two "liquid" phases being the analog of the Bose-Einstein condensation of the ideal gas. Thermodynamic considerations are, however, not contained in this paper.
The system under consideration is an NNN-particle quantum-mechanical system enclosed in a volume VVV, in which the particles interact via two-body hard-sphere potentials, with hard-sphere diameter aaa. The two-body hard-sphere problem is first discussed by a generalization of Fermi's pseudopotential by means of which the problem is formulated entirely in terms of the scattering phase shifts. It is then shown that a pseudopotential for the NNN-body problem can be introduced, and leads to an expansion of the energy levels of the system in powers of aaa. The first order energy levels of a Bose and a Fermi system are calculated. For the Bose system, the first order energy formula exhibits an "energy gap" above the ground state, leading to properties of the system not dissimilar to that of a superfluid. The ground state energy for a Bose system is calculated to order a3{a}^{3}a3 and that for the Fermi system, to order a2{a}^{2}a2. The physical interpretation and validity of these results are discussed.
The calculation of the thermodynamic properties in the Bose-Einstein distribution is presented.The behaviour of the Bose-gas in the Bose-Einstein distribution is analysed based on high and low temperature dependence.At > all particles are in the excited state and the ground state is essentially occupied.But at B T T < particles gradually falls to the ground state and eventually contains all the particles in the system as .0 → TThe analytical expressions for some important parameters such as Bose-Einstein condensation of an ideal Bose gas, the population density of the excited and ground state particles are also presented.Heart capacity of an ideal Bose gas and total internal energy are also calculated and the results presented graphically.The results obtained are consistent with those found in the literatures.
By a generalization of the method used in a previous paper the distribution of energy levels of a dilute Bose system of hard spheres is found. These energy levels are then used to compute the statistical properties for the system. A phase transition is found, and the transition point is calculated to the lowest order of aaa, the diameter of the hard spheres. Furthermore, the thermodynamical functions of the system in both the gas phase and the degenerate phase are obtained, provided $(\frac{a}{\ensuremath{\lambda}})\ensuremath{\ll}1$ and $\ensuremath{\rho}{a}^{3}\ensuremath{\ll}1$, where $\ensuremath{\lambda}$ is the thermal wavelength and $\ensuremath{\rho}$ is the particle density.
We prove the equivalence between the hard-sphere Bose gas and a system with momentum-dependent zero-range interactions in one spatial dimension, which we call extended hard-sphere Bose gas. The two-body interaction in the latter model has the advantage of being a regular pseudopotential. The most immediate consequence is the existence of its Fourier transform, permitting the formulation of the problem in momentum space, not possible with the original hard-core interaction. In addition, in the extended system, interactions are defined in terms of the scattering length, positive or negative, identified with the hard-sphere diameter only when it is positive. We are then able to obtain, directly in the thermodynamic limit, the ground-state energy of the strongly repulsive Lieb-Liniger gas and, more importantly, the energy of the lowest-lying super Tonks-Girardeau gas state with finite, strongly attractive interactions, in perturbation theory from the novel extended hard-sphere Bose gas.
The properties of a Bose-Einstein gas with repulsive interparticle interactions are determined at low temperature. It is shown that the contribution to the energy arising from particle excitation with small momentum transfers computed in conventional perturbation theory is divergent, but that this difficulty can be avoided by an alternative procedure. An exact method is developed for dealing with that part of the Hamiltonian which gives rise to the perturbation divergence and an exact solution is obtained. The treatment of the region of large momentum transfers is then carried out by introducing the concept of the scattering length of the interaction. The energy is given by the well-known result of the optical theorem corrected by a series in powers of ${(\ensuremath{\rho}{a}^{3})}^{\frac{1}{2}}$, where $\ensuremath{\rho}$ is the density and aaa the scattering length. Examination of the processes contributing to the energy shows that 95.8% of the correction of order ${(\ensuremath{\rho}{a}^{3})}^{\frac{1}{2}}$ results from a simple alteration of the perturbation energy denominators which takes into account the interaction energy of excited pairs with the unexcited pairs of the medium. The remaining 4.2% arises from multiple particle excitation. These methods also predict the existence of phonon excitation with phonon energies that are linear in the phonon momentum for small excitation and approach q22M\frac{{q}^{2}}{2M}2Mq2​ for large momentum. The detailed consideration of this spectrum forms part of the following paper.The results are compared with the theory of fermion systems with strong interactions, where again the largest correction to the first-order "optical" energy arises from alteration of the two-particle propagator which is required to take into account interactions with the many unexcited particles of the medium. The propagator corrections in the fermion and boson systems are similar except for a characteristic difference arising from the statistics. The theory for bosons is shown to be essentially identical with that given by Brueckner and Levinson in their general formulation of the theory of many-body systems with strong interactions.Systems with attractive but saturating interactions are also considered and some new difficulties are shown to arise which cannot be treated by a straightforward application of the methods of this paper.
The method developed in the previous paper for the treatment of the quantum-mechanical NNN-body hard-sphere problem is applied to a calculation of the grand partition function of an imperfect Bose gas with hard-sphere interactions. The grand partition function is calculated to second order in an expansion in powers of $\frac{a}{\ensuremath{\lambda}}$, where aaa is the hard-sphere diameter and $\ensuremath{\lambda}$ the thermal wavelength. The approximate equation of state for the gas phase is thereby obtained by calculating all the virial coefficients to order ${(\frac{a}{\ensuremath{\lambda}})}^{2}$.The first-order energy levels obtained in the previous paper embody some interesting physical properties. A fictitious system with exactly such energy levels is considered. The partition function for such a system can be calculated exactly and the exact equation of state obtained. It is shown that there is a phase transition, which more closely resembles an ordinary gas-liquid transition than the Bose-Einstein condensation.