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Physical review. B, Solid state

Critical properties of many-component systems

Victor J. Emery

Published Jan 1, 1975• 344 citations
Publisher

Abstract

Critical properties are discussed for systems with order parameters given by $n$ vectors ${\stackrel{\ensuremath{\rightarrow}}{\mathrm{S}}}_{\ensuremath{\alpha}}$, each with $m$ components. The Hamiltonian has an arbitrary symmetry for each vector separately, but there is a particular kind of coupling between them. It is shown that there is an integral representation for the partition function which reduces $n$ to an explicit parameter in an averaged partition function for the $m$-component model. This leads to a simple discussion of properties of the system as a function of $n$. In particular, it is possible to give a coherent derivation of several known and new results without the aid of perturbation theory or the renormalization-group method. It is shown that, in certain special cases, the exponents are Gaussian when $n$ is a negative even integer and that $n=0$ corresponds to the excluded-volume problem. The general case is shown to reduce to an arbitrary $m$-component model which is random when $n=0$ and constrained when $n\ensuremath{\rightarrow}\ensuremath{\infty}$. A direct derivation of the large-$n$ limit is given and leads to a variety of exactly solvable models. Expressions for the order ${n}^{\ensuremath{-}1}$ correction are obtained in terms of correlation functions. This expansion is valid at all temperatures and for any order of transition, so that it is particularly suitable for considering tricritical phenomena.

DOI
10.1103/physrevb.11.239

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Critical Exponents for Long-Range Interactions. I

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The critical exponents r and a are derived in powers of 1/n to first order for the n- vector model (or n-component system) with long-range interactions.The results show that the exponents have discontinuity with respect to the potential-range " at <T=2 for d>2 (d: dimensionality).It is also shown that they depend upon d and "• rather independently.The connection of the present results with the ones derived in E-expansion is briefly discussed.The 1/n-expansion of other critical exponents such as {J, iJ, "' and 71 are also discussed.§ 1. Introduction and summary Critical exponents characteristic of critical phenomena depend upon the dimensionality d, symmetry (or the degrees of freedom, n) and potential-range s (or effective potential-range rJ).Among these three parameters, the d-and n- dependences of critical exponents have been investigated 1 l-4 l mainly by using an expansion method combined with renormalization group techniques. 5> However, the potential-range s (or rJ) is also a very important parameter for critical phenomena, in particular for the purpose of discussing critical behavior in systems of restricted dimensionality, in which there would occur no phase transition otherwise.6>One of our main purposes in this paper is to investigate how the critical exponents depend upon the three parameters d, n and (J, particularly to clarify the mutual relationship between dimensionality d and potential-range s (or rJ).For this purpose, the critical exponents for general d and s (or rJ) are calculated, (I) by applying 1/n-expansion 7 > to n-vector model with potential-range s, and (II) by extending s-expansion 1 >• 2 > to a generalized effective Hamiltonian of Wilson-type 8 >• 6 l (essentially equivalent to the n-vector model with long-range interactions).Following Wilson 2 l and Fisher,ll for any real value d(>1), we make use of the formulae (2n)-a S d"-kf(k~) =Ka f"ka-~(k~)dk,Downloaded from https://academic.oup.com/ptp/article/49/2/424/1856924 by guest on 12 August 2023Critical Exponents for Long-Range Interactions.I with Ka = 2-<"-t>n-"12 [T(d/2) J-t.The effective potential-range (J is defined by rJ=s for O<s<2 and rJ=2 for s>2 through the interaction

Progress of Theoretical Physics•Feb 1, 1973•40 citations
Critical properties are discussed for systems with order parameters given by nnn vectors S\ensuremath→\ensuremathα{\stackrel{\ensuremath{\rightarrow}}{\mathrm{S}}}_{\ensuremath{\alpha}}S\ensuremath→​\ensuremathα​, each with mmm components. The Hamiltonian has an arbitrary symmetry for each vector separately, but there is a particular kind of coupling between them. It is shown that there is an integral representation for the partition function which reduces nnn to an explicit parameter in an averaged partition function for the mmm-component model. This leads to a simple discussion of properties of the system as a function of nnn. In particular, it is possible to give a coherent derivation of several known and new results without the aid of perturbation theory or the renormalization-group method. It is shown that, in certain special cases, the exponents are Gaussian when nnn is a negative even integer and that n=0n=0n=0 corresponds to the excluded-volume problem. The general case is shown to reduce to an arbitrary mmm-component model which is random when n=0n=0n=0 and constrained when n\ensuremath→\ensuremath∞n\ensuremath{\rightarrow}\ensuremath{\infty}n\ensuremath→\ensuremath∞. A direct derivation of the large-nnn limit is given and leads to a variety of exactly solvable models. Expressions for the order n\ensuremath−1{n}^{\ensuremath{-}1}n\ensuremath−1 correction are obtained in terms of correlation functions. This expansion is valid at all temperatures and for any order of transition, so that it is particularly suitable for considering tricritical phenomena.
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The goal of this work is to provide an analysis of spaces of critical points for multicomponent systems. First, we propose the geometric concept of order O\mathcal{O}O for critical points; we distinguish it from a previous definition of a "multicritical" point. Specifically, we may define the intersection of spaces of critical points of order O\mathcal{O}O to be a space of critical points of order (O+1\mathcal{O}+1O+1). Ordinary critical points are defined to be of order O=2\mathcal{O}=2O=2, so that the tricritical points introduced by Griffiths are of order O=3\mathcal{O}=3O=3. We discuss more general examples of critical spaces of order O=3\mathcal{O}=3O=3 which are known for a wide variety of systems; we also propose several examples of models of magnetic systems showing critical points of order O=4\mathcal{O}=4O=4---i.e., systems having intersecting lines of tricritical points. The analysis of critical and coexistence spaces also provides a new form of the Gibbs phase rule suitable for complex magnetic models. Next we define---for the critical points of order O\mathcal{O}O of which examples have been given---special directions in terms of which to make a scaling hypothesis. We give the hypothesis for simple systems and then for tricritical points, and then, in a subsequent paper, part II, the special directions are used to make a scaling hypothesis at spaces of critical points of any order. Certain predictions (e.g., scaling laws and "single-power" scaling functions) follow in a simple and straightforward fashion. We consider the scaling hypothesis at a critical space of order O\mathcal{O}O in terms of a group of transformations. We can define a set of invariants of the group. It is possible, for $\mathcal{O}\ensuremath{\ge}3$, to make a second scaling hypothesis for the space of order $\mathcal{O}\ensuremath{-}1$ using certain of these invariants as independent variables. This is advantageous because certain "double-power" scaling functions then follow directly; these predict that for O=3\mathcal{O}=3O=3, experimental data collapse from a volume onto a line. This prediction is to be contrasted with ordinary scaling functions, which predict that data collapse by only a single dimension (e.g., from a volume onto a surface or from a surface onto a line).
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The critical behaviour of systems belonging to the three-dimensional Ising universality class is studied theoretically using the collective variables (CV) method.The partition function of a one-component spin system is calculated by the integration over the layers of the CV phase space in the approximation of the non-Gaussian sextic distribution of order-parameter fluctuations (the ρ 6 model).A specific feature of the proposed calculation consists in making allowance for the dependence of the Fourier transform of the interaction potential on the wave vector.The inclusion of the correction for the potential averaging leads to a nonzero critical exponent of the correlation function η and the renormalization of the values of other critical exponents.The contributions from this correction to the recurrence relations for the ρ 6 model, fixed-point coordinates and elements of the renormalization-group linear transformation matrix are singled out.The expression for a small critical exponent η is obtained in a higher non-Gaussian approximation.
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