A new method for treating the most important eigenvalue problems in quantum mechanics is developed. The solutions can be found immediately once the equations are factorized by means of linear operators. These operators acting on a normalized eigenfunction change it into a new normalized eigenfunction and all solutions can be found once the basic eigenfunction is known. This basic eigenfunction is a solution of a simple differential equation of the first order. The underlying theory is explained more fully on a special case (Section 1) and then the rules of procedure are formulated explicitly (Section 2). The rest of the paper contains applications including the Kepler problem treated according to Dirac's theory.
A new method for treating the most important eigenvalue problems in quantum mechanics is developed. The solutions can be found immediately once the equations are factorized by means of linear operators. These operators acting on a normalized eigenfunction change it into a new normalized eigenfunction and all solutions can be found once the basic eigenfunction is known. This basic eigenfunction is a solution of a simple differential equation of the first order. The underlying theory is explained more fully on a special case (Section 1) and then the rules of procedure are formulated explicitly (Section 2). The rest of the paper contains applications including the Kepler problem treated according to Dirac's theory.
The Schrodinger-Infold factorization method for salrinz eigenralue problem in quantum mechanics is very simple for the determination of the sigenvalues and oigenfunctione, without usinx power series or polguomial developments. Howerer, no general theory underlying thie method has been depuloned. It is the parpose of tho preseat paper to formulate explicit conditiona (A, R, G) ander which the method applies, and to lay down formulas which will enable one to write ont at once the solution of ans eigenvalue problem eatisfying these conditions. As illastrationa tho spherical harmonics, the Kepler problem in ordinary space and in spherical epaco, and the harmonie oscillator, are re-troated here on the basis of the theory now developed.
The solution of the quantum-mechanical eigenvalue problem is discussed for cases when a series of approximate eigenfunctions is known. If these ``unperturbed'' states are divided into two classes, a perturbation formula is derived giving the influence of one class of states on the other in the final solution. The formula contains as special cases: (i) the Schrödinger-Brillouin formula for the eigenvalue of a nondegenerate state, (ii) a new simple formula for treating a class of degenerate states, and (iii) the splitting of the secular equation in cases where the system naturally consists of two independent parts in mutual interaction.
Abstract We present a simple algebraic procedure that can be applied to solve a range of quantum eigenvalue problems without the need to know the solution of the Schrödinger equation. The procedure, presented with a pedagogical purpose, is based on algebraic consistency conditions that must be satisfied by the eigenvalues of a couple of operators proper of the problem. These operators can be either bilinear forms of the raising and lowering operators appropriate to the problem, or else auxiliary operators constructed by resorting to the factorization of the Hamiltonian. Different examples of important quantum-mechanical textbook problems are worked out to exhibit the clarity and simplicity of the algebraic procedure for determining the spectrum of eigenvalues without knowing the eigenfunctions. For this reason the material presented may be particularly useful for undergraduate students or young physicists.
A new approach to the eigenvalue problem in quantum mechanics is proposed. This approach is based on three propositions: 1) a perturbation theory which does not require knowledge of the entire eigenvalue spectrum of the unperturbed problem and which uses a nonlinearization procedure (leaving some latitude in the choice of a zeroth order approximation); 2) a relationship between the perturbation theory and a variational principle, namely that any variational calculation is none other than the first two terms of some nontrivial perturbation theory which, when developed further, can reveal the accuracy of the variational calculations and can refine them by an iterative procedure; 3) Dyson's argument, which serves as a criterion for the reasonableness of the choice of a zeroth order approximation (the unperturbed problem). The realization of this perturbation theory in a k-dimensional space is equivalent to the solution of a k-dimensional electrostatic problem with a variable dielectric permittivity. In the one-dimensional case and in cases which reduce to the one-dimensional case, all the corrections are written in quadratures. It is shown that the construction of an ordinary perturbation theory (in which the zeroth order approximation is an exactly solvable problem) within the framework of this perturbation theory is a purely algebraic procedure, which reduces to the solution of some simple recurrence relations. An approximation analogous to the leading logarithmic approximation of quantum field theory is constructed. Some standard problems of quantum mechanics—the anharmonic oscillator, the Zeeman effect, and the Stark effect—are treated as examples. It is shown that this new approach makes it possible to develop systematically a theory for strong coupling and large perturbations.
A basic quantity in quantum mechanics is the wave function ψ. Given a quantum mechanical system we write the Schrödinger equation for it. Its solution is the wave function. When introducing the wave function we stated that the maximum information about the state of a system can be obtained only from ψ. How do we extract observable properties of the system from the wave function? In quantum mechanics for every classical dynamical variable there exists an operator. For example, the operator of momentum p is −i~∇ while the operator of energy variable H = p2/(2m)+V (X) is −(~2/2m)∇2+V (X). Operation of an operator on ψ gives another function. If the new function is λψ, then λ is the eigenvalue of the operator. For example, the energy of a particle in a particular state represented by ψ can be obtained by operating H on ψ. That is, we have Hψ = Eψ where E is the energy eigenvalue. The expectation value of A(X,p) can be obtained from the formula 〈A〉 = ∫ ∞ −∞ ψ∗Aψ dτ , (3.1) where ψ is the solution of the equation Hψ = Eψ. Operators in quantum mechanics which represent observables are of a spe- cial type: They are linear and Hermitian. Such operators not only form computation tools, but also form the most effective language in terms of which the theory can be formulated. The fascinating point is that using linear operators we can understand the quantum mechanics. Therefore, it is important to study the basic theory of linear operators. In this chapter, we present important properties of linear operators and their eigenfunctions. We discuss the features of various operators which are necessary for studying quantum and ematical structure of quantum mechanics is.
The basic equation of quantum mechanics is the Schrödinger equation which expresses the wave function Ψ of a quantum system as an eigenfunction of a quantized Hamiltonian operator H : HΨ = λΨ where the (real) eigenvalue λ is the quantum energy of the system in the state Ψ see equations (1.3.2), (1.3.4). Embodied already in this equation is the basic quantum mechanical principle that quantum energies cannot take on arbitrary values but are quantized : they are given by a discrete set of eigenvalues of a suitable second-order differential operator. This mathematical phenomenon of the discreteness of eigenvalues explains, for example, the observed discreteness of absorption and emission atomic spectral lines; compare remarks in Sections 1.2 and 1.3 of Chapter 1. The Schrödinger theory, and the equivalent theory of Heisenberg, Born and Jordan, represents a distinct advancement of the Bohr theory. Some early basic papers on quantum mechanics are compiled in the book [82], which includes a historic introduction by B. van der Waerden. Also see [6, 8, 9, 24, 75, 76]. These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.