The shock to which students approaching quantum mechanics for the first time are exposed by the introduction of the postulates on which the mathematical framework of the theory is based, can be much smoothed by a discussion of a semiphilosophical nature about the connection between mathematical theories and the physical reality they are supposed to explain. The general outline of such a discussion is presented, with the purpose of making the introduction of operators to represent physical magnitudes more plausible to the students.
The shock to which students approaching quantum mechanics for the first time are exposed by the introduction of the postulates on which the mathematical framework of the theory is based, can be much smoothed by a discussion of a semiphilosophical nature about the connection between mathematical theories and the physical reality they are supposed to explain. The general outline of such a discussion is presented, with the purpose of making the introduction of operators to represent physical magnitudes more plausible to the students.
Abstract It can easily be argued that a fully mature and complete knowledge of quantum mechanics should include historical, axiomatic, formal mathematical, and even philosophical background to the subject. However, for a student approaching quantum theory for the first time in a serious way, it can be the case that an approach utilizing his or her existing knowledge of, and intuition for, classical physics (including mechanics, wave physics, and electricity and magnetism) as well as emphasizing connections to experimental results can be the most pro- ductive. That, at least, is the point of view adopted in this text and can be illustrated by a focus on the following general topics:
This article is a ‘‘sampler,’’ which shows how quantum mechanics may be presented to students in a way that makes apparent how natural quantum mechanics is as a description of the world. The mathematical machinery of Hilbert space, the idea of representing observables by operators, the Schrödinger equation, and the position-momentum uncertainty relation all follow from natural assumptions that students can readily accept. The basic ideas of quantum mechanics are developed from intuitive first principles to the point where one can connect with more traditional treatments of quantum mechanics.
Basic scientific theories usually start with a set of hypotheses or “postulates.” There is generally no logical reason, apart from internal consistency, that can be given to justify such postulates absolutely. They come from ‘revelations’ in the minds of ‘geniuses,’ most likely with hints from Nature based on extensive careful observations. Their general validity can only be established through experimental verification. If numerous rigorously derived logical consequences of a very small set of postulates all agree with experimental observations without exception, one is inclined to accept these postulates as correct descriptions of the laws of Nature and use them confidently to explain and predict other natural phenomena. Quantum mechanics is no exception. It is based on a few postulates. For the purpose of the present discussion, we begin with three basic postulates involving: the “state functions,” “operators,” and “equations of motion.” In this chapter, this set of basic postulates and some of the corollaries and related definitions of terms are introduced and discussed. We will first simply state these postulates and introduce some of the related mathematical tools and concepts that are needed to arrive at their logical consequences later. To those who have not been exposed to the subject of quantum mechanics before, each of these postulates taken by itself may appear puzzling and meaningless at first. It should be borne in mind, however, that it is the collection of these postulates as a whole that forms the foundations of quantum mechanics.
Many students find quantum mechanics conceptually difficult when they first encounter the subject. In this book, the postulates and key applications of quantum mechanics are well illustrated by means of a carefully chosen set of problems, complete with detailed, step-by-step solutions. Beginning with a chapter on orders of magnitude, a variety of topics are then covered, including the mathematical foundations of quantum mechanics, Schrödinger's equation, angular momentum, the hydrogen atom, the harmonic oscillator, spin, time-independent and time-dependent perturbation theory, the variational method, multielectron atoms, transitions and scattering. Throughout, the physical interpretation or application of certain results is highlighted, thereby providing useful insights into a wide range of systems and phenomena. This approach will make the book invaluable to anyone taking an undergraduate course in quantum mechanics.
Although, the main objective of this book has been to expose the facts that underpin formal description of quantum mechanics and to make quantum mechanics seem natural, in going about this process we have tried to provide the young student with a guideline on how to approach learning a new theory. Thus, somewhat unconventionally, we start the discourse with a discussion on the meaning of theory and its formal description. This allows us to demonstrate, in concrete terms, how quantum mechanics is just another theoretical framework that conforms to the standard definition of a theory in the natural sciences. In this first chapter, we start with a nontechnical discussion of what one means by a theoretical framework and its formal description. We clarify what qualifies as a theory, and list the questions whose answers one must seek in trying to learn it. A notion of what amounts to understanding a theory is thus conveyed. The meaning of law, axiom, postulate, theorem, falsifiability etc., are thus discussed. We try to draw out the purpose of constructing a formal description of a theory. We also outline the role of abstraction and generalization in its construction. Finally, we discuss the sense in which the terms “philosophy” and “fundamental theorem” are used in the construction of a theoretical framework.
Introduction to the Maths and Physics of Quantum Mechanics details the mathematics and physics that are needed to learn the principles of quantum mechanics. It provides an accessible treatment of how to use quantum mechanics and why it is so successful in explaining natural phenomena. This book clarifies various aspects of quantum physics such as ‘why quantum mechanics equations contain “I”, the imaginary number?’, ‘Is it possible to make a transition from classical mechanics to quantum physics without using postulates?’ and ‘What is the origin of the uncertainty principle?’. A significant proportion of discussion is dedicated to the issue of why the wave function must be complex to properly describe our “real” world. The book also addresses the different formulations of quantum mechanics. A relatively simple introductory treatment is given for the “standard” Heisenberg matrix formulation and Schrodinger wave-function formulation and Feynman path integrals and second quantization are then discussed. This book will appeal to first- and second-year university students in physics, mathematics, engineering and other sciences studying quantum mechanics who will find material and clarifications not easily found in other textbooks. It will also appeal to self-taught readers with a genuine interest in modern physics who are willing to examine the mathematics and physics in a simple but rigorous way. Key Features: Written in an engaging and approachable manner, with fully explained mathematics and physics concepts Suitable as a companion to all introductory quantum mechanics textbooks Accessible to a general audience