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The European Physical Journal D

Laser cooling of molecules via single spontaneous emission

C. H. Raymond Ooi, Karl-Peter Marzlin, Jürgen Audretsch

Published Feb 1, 2003• 9 citations
Publisher
DOI
10.1140/epjd/e2002-00227-7

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arXiv:quant-ph/0107103•Jul 20, 2001•0 citations
We propose a laser cooling concept for the translational motion of molecules which does not require repeated spontaneous emission by each molecule. The cooling works by repetition of three main steps; velocity selection of a narrow momentum width, deceleration of velocity selected molecules by repeated STIRAP and accumulation of decelerated molecules via one time spontaneous emission. We use single spontaneous emission for irreversible accumulation of narrow velocity selected and decelerated populations. We develop an analytical model to describe the evolution of the molecular gas system, internal subsystem and external (center of mass) subsystem density matrices and entropies. Simulation results show cooling from an arbitrary momentum width towards final width of about hbark\\hbar khbark. The external entropy is reduced while the internal entropy is increased. The external entropy is shown to decrease during coherent laser interactions, a possibility of translational cooling via unitary evolution. The system entropy increases in consistency with the Araki-Lieb inequality.