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European Journal of Physics

Removal of a degeneracy in the old quantum mechanics

Jean Sivardière

Published Jul 1, 1987• 0 citations
Publisher

Abstract

Various perturbations of the Kepler and harmonic elliptic motions are considered in the frame of the old quantum mechanics. It is shown that the degeneracy of the unperturbed levels is entirely removed by these perturbations.
DOI
10.1088/0143-0807/8/3/014

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The problem of degeneracy in quantum mechanics is related to the existence of groups of contact transformations under which the Hamiltonian is invariant. The correspondence between transformations in classical and quantum theories is developed. The Fock-Bargmann treatment of the symmetry group of the hydrogenic atom comes under this theory. The symmetry group of the 2-dimensional Kepler problem is found to be the 3-dimensional rotation group; that of the nnn-dimensional isotropic oscillator is isomorphic to the unimodular unitary group in nnn dimensions. The 2-dimensional anisotropic oscillator has the same symmetry as the isotropic oscillator in classical mechanics, but the quantum-mechanical problem presents complications which leave its symmetry group in doubt.
A quantum scar-an enhancement of a quantum probability density in the vicinity of a classical periodic orbit-is a fundamental phenomenon connecting quantum and classical mechanics. Here we demonstrate that some of the eigenstates of the perturbed two-dimensional anisotropic (elliptic) harmonic oscillator are strongly scarred by the Lissajous orbits of the unperturbed classical counterpart. In particular, we show that the occurrence and geometry of these quantum Lissajous scars are connected to the anisotropy of the harmonic confinement, but unlike the classical Lissajous orbits the scars survive under a small perturbation of the potential. This Lissajous scarring is caused by the combined effect of the quantum (near) degeneracies in the unperturbed system and the localized character of the perturbation. Furthermore, we discuss experimental schemes to observe this perturbation-induced scarring.
Abstract One of the great achievements of the Schrödinger wave-mechanics is the elegance of its perturbation theory, which has brought many problems, formerly considered intractable, within the range of a highly-developed mathematical technique. It is not necessary at this stage to review the numerous applications which have been made of this perturbation theory or to dwell upon its many advantages. The important advance towards an understanding of chemical forces which it has made possible is in itself a considerable achievement. There are, however, certain disadvantages in the perturbation theory in its present form, which limit the extent of its applications to complex problems of atomic and molecular structure. If the interaction of atoms, for instance, is to be calculated, as it most desirable, improved methods will have to be found.