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Theoretical and Mathematical Physics

Response to a mechanical perturbation and the Green's functions for nonequilibrium systems

В. П. Калашников

Published Oct 1, 1971• 19 citations
Publisher
DOI
10.1007/bf01036030

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In Chapter 3, we introduced a simple but reasonable approximation for the nonequilibrium dynamics of a Bose-condensed gas based on a generalized GP equation coupled to a kinetic equation. In Chapters 4–7, we turn to the question of how to derive such coupled equations for the condensate and noncondensate components in a way that gives a deeper understanding of the ZNG theory. Chapters 4–7 involve an introduction to Green's functions and field theoretic techniques for nonequilibrium problems. These provide the natural language and formalism to deal with the many subtle aspects of a Bose-condensed gas at finite temperatures. These four chapters are fairly technical. This chapter is mainly based on Kadanoff and Baym (1962) and Imamović-Tomasović (2001). Readers who are not interested in these questions can go straight to Chapter 8, which begins the discussion of applications of the ZNG coupled equations given in Chapter 3. Overview of Green's function approach To derive a microscopic theory of the nonequilibrium behaviour of a dilute weakly interacting Bose-condensed gas at finite temperatures, there are several different approaches available in the literature. We will use the wellknown Kadanoff–Baym (KB) nonequilibrium Green's function method. The generalization of this formalism to a Bose-condensed system was first considered by Kane and Kadanoff (1965), whose goal was to derive the Landau two-fluid hydrodynamic equations for a system with a Bose broken symmetry. The general problem consists of how to calculate the nonequilibrium response of a system induced by an external (space- and time-dependent) perturbation. In response to such an external perturbation, many interesting physical phenomena appear, including the excitation of collective modes and various transport processes.
In this article, we present a concise and self-contained introduction to nonequilibrium statistical mechanics with quantum field theory by considering an ensemble of interacting identical bosons or fermions as an example. Readers are assumed to be familiar with the Matsubara formalism of equilibrium statistical mechanics such as Feynman diagrams, the proper self-energy, and Dyson's equation. The aims are threefold: (i) to explain the fundamentals of nonequilibrium quantum field theory as simple as possible on the basis of the knowledge of the equilibrium counterpart; (ii) to elucidate the hierarchy in describing nonequilibrium systems from Dyson's equation on the Keldysh contour to the Navier-Stokes equation in fluid mechanics via quantum transport equations and the Boltzmann equation; (iii) to derive an expression of nonequilibrium entropy that evolves with time. In stage (i), we introduce nonequilibrium Green's function and the self-energy uniquely on the round-trip Keldysh contour, thereby avoiding possible confusions that may arise from defining multiple Green's functions at the very beginning. We try to present the Feynman rules for the perturbation expansion as simple as possible. In particular, we focus on the self-consistent perturbation expansion with the Luttinger-Ward thermodynamic functional, i.e., Baym's Phi-derivable approximation, which has a crucial property for nonequilibrium systems of obeying various conservation laws automatically. We also show how the two-particle correlations can be calculated within the Phi-derivable approximation, i.e., an issue of how to handle the "Bogoliubov-Born-Green-Kirkwood-Yvons (BBGKY) hierarchy".
The equation of motion for nonequilibrium Green functions is derived within the framework of the Schwinger and Keldysh formalism of perturbation expansion. For nonequilibrium distribution Green functions, the equation of motion derived from quantum mechanics contains undefined singularities, whose explicit form depends on the specific initial or boundary condition. In the present work, the exact expression of singular terms is found in the equation of motion from the time-looped perturbation theory in which the adiabatic initial condition is implied. Unlike the usual Dyson perturbation formalism or the well known Kadanoff-Baym equation of motion, our resulting equation can be adopted directly for calculations without the graphical analysis, which depends on the specific form of the Hamiltonian. On the basis of this equation of motion, the procedure of a nonperturbative solution is outlined and potential applications are briefly discussed.