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Journal of Luminescence

Magnetic field effect on ion-pair transfer in ruby. Cross relaxations and resonant transfer

M. Montagna, Lorenzo Gonzo A, Oreste Pilla, G. Viliani, Eugène Duval, André Monteil

Published Dec 1, 1984• 1 citation
Publisher
DOI
10.1016/0022-2313(84)90119-4

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The reversals of maser behaviour which occur in ruby at low fields on cooling from 80° to 4 oK are explained in terms of cross-relaxation transitions (resonant interchanges of energy between neighbouring paramagnetic ions). For an angle of 29° between the magnetic field and the crystal axis a cross-relaxation process has been demonstrated which involves groups of three ions and has a transition probability of 700± 100 per second in 0·013% ruby. The profile of the cross-relaxation resonance has a half-width of 190±30 Mcts at half-intensity, and has an approximately Gaussian shape. It should be possible to obtain useful low-field L-band maser action at 4 oK by pumping V41 with the magnetic field nearly perpendicular to the crystal axis, and also at 80 oK using a concentration ten times higher, i.e. 0·13%