The thermodynamics of a free Bose gas with effective temperature scale [Formula: see text] and hard-sphere Bose gas with the [Formula: see text] scale are studied. [Formula: see text] arises as the temperature experienced by a single particle in a quantum gas with 2-body harmonic oscillator interaction V osc , which at low temperatures is expected to simulate, almost correctly, the attractive part of the interatomic potential V He between 4 He atoms. The repulsive part of V He is simulated by a hard-sphere (HS) potential. The thermodynamics of this system of HS bosons, with the [Formula: see text] temperature scale (HSET), and particle mass and density equal to those of 4 He , is investigated, first, by the Bogoliubov–Huang method and next by an improved version of this method, which describes He II in terms of dressed bosons and takes approximate account of those terms of the 2-body repulsion which are linear in the zero-momentum Bose operators a0, [Formula: see text] (originally rejected by Bogoliubov). Theoretical heat capacity CV(T) exhibits good agreement, below 1.9 K, with the experimental heat capacity graph observed in 4 He at saturated vapour pressure. The phase transition to the He II phase, occurs in the HSET at Tλ = 2.17 K, and is accompanied, in the modified HSET version, by a singularity of CV(T). The fraction of atoms in the momentum condensate at 0 K equals 8.86% and agrees with other theoretical estimates for He II. The fraction of normal fluid falls to 8.37% at 0 K which exceeds the value 0% found in He II.
The thermodynamics of a free Bose gas with effective temperature scale
T~ and hard-sphere Bose gas with the
T~ scale are studied.
T~ arises as the temperature experienced by a single particle in a quantum gas with 2-body harmonic oscillator interaction
Vosc, which at low temperatures is expected to simulate, almost correctly, the attractive part of the interatomic potential
VHe between
4He atoms. The repulsive part of
VHe is simulated by a hard-sphere (HS) potential. The thermodynamics of this system of HS bosons, with the
T~ temperature scale (HSET), is investigated, first, by the Bogoliubov-Huang method and next by a modified version of this method, which takes approximate account of those terms of the 2-body repulsion which are linear in the zero-momentum Bose operators
a0,a0∗ (originally rejected by Bogoliubov). Theoretical heat capacity
CV(T) exhibits good agreement, below 2.1 K, with the experimental heat capacity graph observed in
4He at saturated vapour pressure. The phase transition to the low-temperature phase, with a Bose-Einstein condensate, occurs in the HSET at $T_λ=$2.17 K, and is accompanied, in the modified HSET version, by a singularity of
CV(T). Other thermal properties of HSET, such as the momentum distribution function, the fraction of atoms in the momentum condensate and normal fluid density, agree qualitatively with those of
4He, but improve those of the free Bose gas.
Using the energy-momentum relation derived by Brueckner and Sawada, the low-temperature thermodynamical properties of a Bose gas with hard-sphere interaction are investigated. The two cases, (1) when this energy spectrum is similar to that observed in liquid helium II and (2) when it becomes similar to that derived by Lee, Huang, and Yang, are investigated separately. In the first case (where the spectrum exhibits a nonmonotonic character), the analytical derivation of the expressions for the various thermodynamical properties is rendered possible by dividing the momentum range into three suitable intervals such that within each interval the epsilon -p relation can be approximated to a simple algebraic one. The numerical magnitudes of the various parameters characterizing the algebraic relations are calculated for the case of a gas with density equal to that of liquid helium(II) and for three plausible values of the hard-sphere diameter. The calculated results agree qualitatively with those obtained from the experimental study of this liquid. For the second case, expressions are derived for the various macroscopic properties of the assembly in terms of suitable mathematical functions and then are written down in the form of series expansions for the two particular cases of interest. (auth)